Themed collection Liquid Crystals Science and Technology

31 items
Open Access Paper

Grafting of thermotropic fluorinated mesogens on polysiloxane to improve the processability of linear low-density polyethylene

A series of polysiloxane grafted with thermotropic fluorinated mesogens (TSCPFLCP) is designed and synthesized, which effectively improves the processability and toughness of LLDPE.

Graphical abstract: Grafting of thermotropic fluorinated mesogens on polysiloxane to improve the processability of linear low-density polyethylene
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Effects of liquid crystal polymer (LCP) on the structure and performance of PEEK/CF composites

Here a liquid crystal polymer (LCP) was introduced into a PEEK/CF system as a new solution to simultaneously promote processing and mechanical performance of PEEK/CF and other polymer-based composites.

Graphical abstract: Effects of liquid crystal polymer (LCP) on the structure and performance of PEEK/CF composites
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Influence of hydroquinone content on thermotropic liquid crystalline copolymers and nanocomposites: thermo-mechanical properties and morphology

Thermotropic liquid crystalline copolyesters (Co-TLCPs) were synthesized by varying the hydroquinone (HQ) molar ratio from 1–5 with respect to the 2,5-diethoxyterephthalic acid (ETA) monomer.

Graphical abstract: Influence of hydroquinone content on thermotropic liquid crystalline copolymers and nanocomposites: thermo-mechanical properties and morphology
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Preparation of substituted triphenylenes via nickel-mediated Yamamoto coupling

Nickel-mediated Yamamoto coupling provides a concise and efficient synthesis of triphenylene derivatives, including electron-deficient discotic mesogens.

Graphical abstract: Preparation of substituted triphenylenes via nickel-mediated Yamamoto coupling
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Multifunctional sensors based on liquid crystals scaffolded in nematic polymer networks

Naked-eye color change as a result of temperature change or VOC exposure was demonstrated in a nematic polymer network-stabilized liquid crystal (PNLC) system.

Graphical abstract: Multifunctional sensors based on liquid crystals scaffolded in nematic polymer networks
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Liquid crystal behavior, photoluminescence and gas sensing: A new series of ionic liquid crystal imidazole and benzoimidazole bearing chalcone groups, synthesis and characterization

Four new series of chalcones containing imidazole bromonium and benzimidazole bromonium salts with spacer alkyl chains (Cn, n = 2 and 4) were synthesized and their chemical structure, thermal behavior, photoluminescence and gas sensing ability were characterized.

Graphical abstract: Liquid crystal behavior, photoluminescence and gas sensing: A new series of ionic liquid crystal imidazole and benzoimidazole bearing chalcone groups, synthesis and characterization
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Optical anticounterfeiting photonic bilayer film based on handedness of solid-state helicoidal structure

Anticounterfeiting photonic bilayer DH-CLCsolid films were fabricated by sandwiching two CLCsolid films having different handedness. The encrypted information is only disclosed under right-handed circular polarized light.

Graphical abstract: Optical anticounterfeiting photonic bilayer film based on handedness of solid-state helicoidal structure
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Novel sulphonic acid liquid crystal derivatives: experimental, computational and optoelectrical characterizations

A novel liquid crystal homologous series based on the benzene sulphonic acid moiety, namely (E)-4-((4-((4-(alkoxy)benzoyl)oxy)benzylidene)amino)benzenesulfonic acid (Sn), was synthesized and examined via different experimental and theoretical measurements.

Graphical abstract: Novel sulphonic acid liquid crystal derivatives: experimental, computational and optoelectrical characterizations
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Ultraviolet light screen using cholesteric liquid crystal capsules on the basis of selective reflection

When the prepared cholesteric liquid crystal microcapsule is applied to the skin, it can protect the skin by selectively reflecting only ultraviolet rays in sunlight like sunscreen cosmetics.

Graphical abstract: Ultraviolet light screen using cholesteric liquid crystal capsules on the basis of selective reflection
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Preparation of graphene oxide liquid crystals with long-range highly-ordered flakes using a coat-hanger die

Graphene oxide liquid crystals with long-range highly ordered GO flakes were successfully prepared by a designed coat-hanger die.

Graphical abstract: Preparation of graphene oxide liquid crystals with long-range highly-ordered flakes using a coat-hanger die
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Cholesteric mesophase based 1D photonic materials from self-assembly of liquid crystalline block and random terpolymers containing chromonic molecules

We describe the influence of competing self-organizing phenomena on the formation of cholesteric mesophase in liquid crystalline brush block terpolymers (LCBBTs) and liquid crystalline random brush terpolymers (LCRBTs) containing chromonic molecules.

Graphical abstract: Cholesteric mesophase based 1D photonic materials from self-assembly of liquid crystalline block and random terpolymers containing chromonic molecules
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Gold nanoparticles grafted with chemically incompatible ligands

A Janus-type lamellar structure is formed from gold nanoparticles grafted with chemically incompatible mesogenic ligands. Metallic NP-rich sublayers are separated by ligand-rich sublayers of various composition due to the ligand segregation.

Graphical abstract: Gold nanoparticles grafted with chemically incompatible ligands
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

The role of intermolecular interactions in stabilizing the structure of the nematic twist-bend phase

Stabilization of the nematic twist-band phase by arrays of multiple nonspecific short-range intermolecular interactions.

Graphical abstract: The role of intermolecular interactions in stabilizing the structure of the nematic twist-bend phase
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Directional effect on the fusion of ellipsoidal morphologies into nanorods and nanotubes

Herein, a directional fusion of ellipsoidal morphologies into nanorods and nanotubes was demonstrated through the study of polymerization-induced self-assembly behaviors of semi-fluorinated liquid-crystalline block copolymers.

Graphical abstract: Directional effect on the fusion of ellipsoidal morphologies into nanorods and nanotubes
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Patterned waveguide liquid crystal displays

A polymer stabilized LC based light waveguide display is reported. Performance is improved by patterned photo-polymerization or electrode. It has high brightness, ultrafast switching time, high contrast ratio, and high transmittance for transparent and augmented displays.

Graphical abstract: Patterned waveguide liquid crystal displays
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Organic–inorganic hybrid liquid crystals of azopyridine-enabled halogen-bonding towards sensing in aquatic environment

Organic–inorganic hybrid liquid crystals of azopyridines enabled by halogen bonding with the triple functions of degree of orientation change, MEF, and SERS towards sensing silver in aquatic environment.

Graphical abstract: Organic–inorganic hybrid liquid crystals of azopyridine-enabled halogen-bonding towards sensing in aquatic environment
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Polymer-dispersed liquid-crystal-based switchable glazing fabricated via vacuum glass coupling

A vacuum-coupling technique is suggested to fabricate a glass-based PDLC, without using a roll-to-roll process, to improve the optical properties.

Graphical abstract: Polymer-dispersed liquid-crystal-based switchable glazing fabricated via vacuum glass coupling
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Synthesis of novel liquid crystalline and fire retardant molecules based on six-armed cyclotriphosphazene core containing Schiff base and amide linking units

The FTIR spectra overlay of compounds 5a–j with Schiff base and amide linking units.

Graphical abstract: Synthesis of novel liquid crystalline and fire retardant molecules based on six-armed cyclotriphosphazene core containing Schiff base and amide linking units
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Textile materials inspired by structural colour in nature

The concept of mimicking structural colour in nature as an alternative to traditional textile coloration techniques would reduce dependency on dyes, pigments and vast quantities of water in the textile supply chain.

Graphical abstract: Textile materials inspired by structural colour in nature
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Fluorenone imidazolium salts as novel de Vries materials

ILCs consisting of cationic head group–spacer–fluorenone central core–side chain show de Vries-like behaviour.

Graphical abstract: Fluorenone imidazolium salts as novel de Vries materials
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Difference in the interaction of nano-diameter rod and tubular particles with a disclination line in a nematic liquid crystal

The liquid crystal forces generated by nanowires and nanotubes are different due to their heterotopicity for the liquid crystal director.

Graphical abstract: Difference in the interaction of nano-diameter rod and tubular particles with a disclination line in a nematic liquid crystal
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Photo-controllable rotational motion of cholesteric liquid crystalline droplets in a dispersion system

A photo-controllable rotational motion was demonstrated for an isolated cholesteric liquid crystalline droplet in a surfactant solution.

Graphical abstract: Photo-controllable rotational motion of cholesteric liquid crystalline droplets in a dispersion system
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

One-pot synthesis of symmetric imidazolium ionic liquids N,N-disubstituted with long alkyl chains

The modified Debus–Radziszewski reaction was used as a one-pot on-water reaction to allow a greener synthesis of long-chain 1,3-dialkylimidazolium acetate ionic liquids in high yield from long-chain linear amines.

Graphical abstract: One-pot synthesis of symmetric imidazolium ionic liquids N,N-disubstituted with long alkyl chains
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Influence of inter- and intramolecular H-bonding on the mesomorphic and photoswitching behaviour of (E)-4-((4-(hexyloxy)phenyl)diazenyl)-N-phenyl benzamides

We report on the synthesis, phase behaviour and photoswitching studies of new azo linked rod-shaped molecules.

Graphical abstract: Influence of inter- and intramolecular H-bonding on the mesomorphic and photoswitching behaviour of (E)-4-((4-(hexyloxy)phenyl)diazenyl)-N-phenyl benzamides
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Facile control of surfactant lamellar phase transition and adsorption behavior

The presence of small water-soluble additives makes it possible to tune the surfactant gel-to-liquid crystalline (Lβ–Lα) phase transition temperature (Tm) for a bilayer-forming cationic surfactant system and its phase behavior on dilution.

Graphical abstract: Facile control of surfactant lamellar phase transition and adsorption behavior
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Hexahydrofarnesyl as an original bio-sourced alkyl chain for the preparation of glycosides surfactants with enhanced physicochemical properties

The novelty of this work lies in the valorization of an original by-product into new sugar-based surfactants presenting effective properties.

Graphical abstract: Hexahydrofarnesyl as an original bio-sourced alkyl chain for the preparation of glycosides surfactants with enhanced physicochemical properties
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

L-DOPA modulates the kinetics but not the thermodynamic equilibrium of TTA+ amphiphiles forming lyotropic nematic liquid crystals

L-DOPA modulates the dive in mechanism of bicelles with potential use as drug delivery systems.

Graphical abstract: l-DOPA modulates the kinetics but not the thermodynamic equilibrium of TTA+ amphiphiles forming lyotropic nematic liquid crystals
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Hybrid fluorescent liquid crystalline composites: directed assembly of quantum dots in liquid crystalline block copolymer matrices

Spatial distribution of QDs within hybrid composite films was programed by varying the molecular architecture of the host LC block copolymers.

Graphical abstract: Hybrid fluorescent liquid crystalline composites: directed assembly of quantum dots in liquid crystalline block copolymer matrices
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

New wide-stability four-ring azo/ester/Schiff base liquid crystals: synthesis, mesomorphic, photophysical, and DFT approaches

DSC thermograms of some prepared compounds: (a) recorded from second heating and (b) from cooling at a rate of ±10 °C min−1.

Graphical abstract: New wide-stability four-ring azo/ester/Schiff base liquid crystals: synthesis, mesomorphic, photophysical, and DFT approaches
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Reversible photo-responsive gel–sol transitions of robust organogels based on an azobenzene-containing main-chain liquid crystalline polymer

A robust and photo-responsive organogel has been constructed by introducing an azobenzene-containing main-chain liquid crystalline polymer gelator.

Graphical abstract: Reversible photo-responsive gel–sol transitions of robust organogels based on an azobenzene-containing main-chain liquid crystalline polymer
From the themed collection: Liquid Crystals Science and Technology
Open Access Paper

Defect-mediated colloidal interactions in a nematic-phase discotic solvent

Saturn ring dyads (left) mediate more stable colloidal interactions than Saturn ring triads (right) in nematic-phase discotic dispersions.

Graphical abstract: Defect-mediated colloidal interactions in a nematic-phase discotic solvent
From the themed collection: Liquid Crystals Science and Technology
31 items

About this collection

Welcome to this themed collection on “Liquid Crystals Science and Technology”, guest edited by Dr Giacomo Saielli (Italian National Research Council and University of Padova).

Liquid Crystals (LCs) have been discovered serendipitously in 1888 by the botanist Friedrich Reinitzer. Their discovery sparked a great deal of debate during the first half of 1900 concerning their structural and dynamic properties and even their relationship with living organisms. They remained, however, mostly an academic curiosity until the second half of the last century when their possible application as displays became clear. 

LC displays now represent a huge share of the display industry and many other applications based on LCs have been proposed and developed. At the same time, the LC science, mostly rooted in chemistry and physics but also touching mathematics, biology and engineering, has progressed significantly with new fields opening, e.g. ionic liquid crystals, polymeric liquid crystals, active matter systems, orienting phases for bio-NMR, LC-based membranes for separation. Moreover, new LC phases have been reported during the last recent decades renewing the scientific discussion on the fundamental properties and phase structure of these fascinating materials.   

This themed collection highlights a series of papers published in the last two years concerning basic scientific investigations on LCs, from the synthesis of novel materials to structure-property relationships as well as applications in opto-electronic devices, thus attesting the breadth and vitality of the present research on liquid crystals. 


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