Themed collection EES Catalysis Recent Review Articles
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Surpassing water-splitting potential in aqueous redox flow batteries: insights from kinetics and thermodynamics
Aqueous redox flow batteries (AQRFBs) employing non-flammable electrolytes are recognized for their inherent safety and eco-friendliness, making them promising candidates for large-scale energy storage systems.
EES. Catal., 2024,2, 522-544
https://doi.org/10.1039/D3EY00231D
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High-pressure electrochemistry: a new frontier in decarbonization
Higher pressures can positively impact electrochemical activity, selectivity, stability, and efficiency.
EES. Catal., 2024,2, 507-521
https://doi.org/10.1039/D3EY00284E
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Direction of oxygen evolution reaction electrocatalyst evaluation for an anion exchange membrane CO2 electrolyzer
The reference electrode-integrated MEA-type electrolyzer can be utilized to genuinely assess OER electrocatalyst performance for CO2 electrolysis.
EES. Catal., 2024, Advance Article
https://doi.org/10.1039/D3EY00314K
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Reaction microenvironment control in membrane electrode assemblies for CO2 electrolysis
This perspective discusses the latest achievements in activity and selectivity control in CO2 electrolysis by tuning reaction microenvironments.
EES. Catal., 2024,2, 220-230
https://doi.org/10.1039/D3EY00155E
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Advances and challenges in scalable carbon dioxide electrolysis
This perspective illustrates ways to achieve scalable CO2 electrolysis by designing efficient electrolyzers and regulating the catalytic reaction environments.
EES. Catal., 2023,1, 934-949
https://doi.org/10.1039/D3EY00159H
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Copper-based catalysts for CO2 hydrogenation: a perspective on active sites
This Perspective reviews the understanding of active sites on various Cu-based materials for the CO2 hydrogenation to high-value products from theoretical and experimental advances.
EES. Catal., 2023,1, 921-933
https://doi.org/10.1039/D3EY00152K
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A perspective of COx conversion to aromatics
The sustainable production of chemicals through COx hydrogenation is a growing area of interest, with thermal catalytic conversion showing the most promise.
EES. Catal., 2023,1, 677-686
https://doi.org/10.1039/D3EY00102D
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Advanced dual-atom catalysts for efficient oxygen evolution reaction
This perspective discusses the latest exciting advancements in dual-atom catalysts (DACs) for the oxygen evolution reaction and battery devices, highlighting the fundamental principles for the intelligent design and application of DACs.
EES. Catal., 2023,1, 665-676
https://doi.org/10.1039/D3EY00050H
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Revisiting group 4–7 transition metals for heterogeneous ammonia synthesis
Group 4–7 metals are usually inactive for NH3 synthesis catalysis and have gained far less attention as compared to Fe and Ru. This mini-review discusses potential strategies to activate these metals, aiming to find novel catalysts for NH3 synthesis.
EES. Catal., 2024,2, 780-788
https://doi.org/10.1039/D3EY00301A
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Zeolite catalysts for non-oxidative ethane dehydrogenation to ethylene
The conversion of ethane to ethylene is crucial for deriving platform chemicals from non-petroleum feedstock.
EES. Catal., 2024, Advance Article
https://doi.org/10.1039/D4EY00031E
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A minireview on electrochemical CO2 conversion based on carbonate/bicarbonate media
(Bi)Carbonate electrochemical conversion has emerged as a promising technology. Studies on mechanisms, along with latest progress in catalyst design and working electrode optimization. are summarized. Challenges and opportunities are also discussed.
EES. Catal., 2024,2, 564-572
https://doi.org/10.1039/D3EY00287J
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Effects of the delocalization state on electrocatalytic CO2 reduction: a mini-review
The delocalization state of catalysts has been found to promote the stability and selectivity of CO2RR. This mini-review was discussed how the delocalization state of catalysts affects catalytic properties.
EES. Catal., 2024,2, 556-563
https://doi.org/10.1039/D3EY00227F
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Unconventional intermetallic noble metal nanocrystals for energy-conversion electrocatalysis
The distinctive atomic distance and coordination environment endow the unconventional intermetallic noble metal nanocrystals with enhanced electrochemical performance.
EES. Catal., 2024,2, 545-555
https://doi.org/10.1039/D3EY00248A
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Selective catalytic reduction of NOx with NH3 over copper-based catalysts: recent advances and future prospects
This review presents the important progress of Cu-based catalysts for the NH3-SCR reaction. Special attention is given to elucidating the design of high-performance catalysts, as well as anti-inactivation measures in industrial applications.
EES. Catal., 2024,2, 231-252
https://doi.org/10.1039/D3EY00210A
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A review of II–VI semiconductor nanoclusters for photocatalytic CO2 conversion: synthesis, characterization, and mechanisms
In this review, we briefly overview the syntheses, compositions, growth mechanisms, and performance improvement strategies of typical II–VI MSCs. Recent advances on the application of II–VI MSCs in photocatalytic CO2 reduction are introduced.
EES. Catal., 2023,1, 687-694
https://doi.org/10.1039/D3EY00106G
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Advanced bifunctional catalyst design for rechargeable zinc–air batteries
This review provides an overview of advanced bifunctional catalysts that promotes both oxygen reduction reaction and oxygen evolution reaction in rechargeable zinc–air batteries, and analyses in detail their principles and future development.
EES. Catal., 2024,2, 696-726
https://doi.org/10.1039/D4EY00014E
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A comparative overview of the electrochemical valorization and incorporation of CO2 in industrially relevant compounds
This review covers the recent work on the electrochemical valorization of CO2 towards key industrial compounds like carboxylic acids, urea and dimethyl carbonate by combining the eCO2RR intermediates with other active (in)organic reagents.
EES. Catal., 2024,2, 753-779
https://doi.org/10.1039/D4EY00005F
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Cu-based catalysts for electrocatalytic nitrate reduction to ammonia: fundamentals and recent advances
This review provides an overview of Cu-based catalysts for electrocatalytic nitrate reduction to ammonia. It encompasses materials, reaction mechanisms, analysis methods and insights into the practical applications and economic prospects.
EES. Catal., 2024,2, 727-752
https://doi.org/10.1039/D4EY00002A
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Advancements and opportunities in piezo-(photo)catalytic synthesis of value-added chemicals
Achieving value-added transformation of chemicals through green catalytic technology can simultaneously meet the market and environmental protection. This article reviews the recent advances in synthesizing value-added chemicals using piezo-(photo)catalytic technologies.
EES. Catal., 2024, Advance Article
https://doi.org/10.1039/D3EY00313B
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Crystalline carbon nitrides for photocatalysis
This review comprehensively summarizes the recent advances on crystalline carbon nitrides, including their preparation, optimization strategies, photocatalytic applications, as well as challenges and prospects.
EES. Catal., 2024,2, 411-447
https://doi.org/10.1039/D3EY00302G
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Metal halide perovskites for CO2 photoreduction: recent advances and future perspectives
This review presents a comprehensive overview of state-of-the-art developments in metal halide perovskite-based catalysts for photocatalytic reduction of CO2.
EES. Catal., 2024,2, 448-474
https://doi.org/10.1039/D3EY00187C
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Nanostructured single-atom catalysts derived from natural building blocks
The emerging single-atom catalysts derived from biomass sources to date have been comprehensively summarized and discussed, including synthesis strategies, various biomass precursors, catalytic applications, existing challenges, and perspectives.
EES. Catal., 2024,2, 475-506
https://doi.org/10.1039/D3EY00265A
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Pt single crystal surfaces in electrochemistry and electrocatalysis
In this review, recent advances in the use of platinum single-crystal surfaces in electrochemistry are addressed.
EES. Catal., 2024,2, 399-410
https://doi.org/10.1039/D3EY00260H
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Recent progress in understanding the catalyst layer in anion exchange membrane electrolyzers – durability, utilization, and integration
This review discusses recent insights in catalyst layer design strategies for anion exchange membrane water electrolyzers, including electrode design, catalyst/ionomer integration, operational variables, in situ diagnostics, and cell durability.
EES. Catal., 2024,2, 109-137
https://doi.org/10.1039/D3EY00193H
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Multidisciplinary approaches for enzyme biocatalysis in pharmaceuticals: protein engineering, computational biology, and nanoarchitectonics
This article reviews the integration of multidisciplinary approaches, including protein engineering, computational biology, and nanoarchitectonics, to advance pharmaceutical enzyme biocatalysis.
EES. Catal., 2024,2, 14-48
https://doi.org/10.1039/D3EY00239J
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Research progress and perspectives on photocatalysts based on the lead-free double halide perovskite
Unlocking photocatalytic potential: this review explores the remarkable properties of lead-free double halide perovskites, their synthesis methods, and their role in photocatalytic H2 production and CO2 reduction.
EES. Catal., 2024,2, 94-108
https://doi.org/10.1039/D3EY00229B
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Harnessing single-atom catalysts for CO2 electroreduction: a review of recent advances
We use an alchemical furnace as the main concept, with three pillars representing the general synthesis strategies for SACs. The four “elixirs” within the furnace chamber represent the diverse regulation strategies for SACs in CO2RR applications.
EES. Catal., 2024,2, 71-93
https://doi.org/10.1039/D3EY00150D
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Single atom catalysts for water electrolysis: from catalyst-coated substrate to catalyst-coated membrane
This review summarizes the integration of single atom catalysts and catalyst-coated membrane architecture, exhibiting high utilization of SACs, facile ion transport, low interfacial resistance, and excellent scalability.
EES. Catal., 2024,2, 49-70
https://doi.org/10.1039/D3EY00165B
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Gas-phase errors in computational electrocatalysis: a review
In this review we show how DFT gas-phase errors affect computational models of electrocatalytic reactions.
EES. Catal., 2024,2, 157-179
https://doi.org/10.1039/D3EY00126A
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Structural engineering of catalysts for ammonia electrosynthesis from nitrate: recent advances and challenges
Electrocatalytic nitrate reduction to ammonia offers a sustainable approach for nitrogenous waste upcycling. This review outlines recent advances in the design of electrocatalysts through cross-scale structural engineering.
EES. Catal., 2024,2, 202-219
https://doi.org/10.1039/D3EY00184A
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Recent advances in tunable metal–support interactions for enhancing the photocatalytic nitrogen reduction reaction
Photocatalytic nitrogen reduction using inexhaustible solar energy has been considered as a promising strategy for NH3 synthesis. The design of heterogeneous photocatalysts with tunable MSIs is of great significance.
EES. Catal., 2024,2, 180-201
https://doi.org/10.1039/D3EY00191A
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Photocatalytic inactivation technologies for bioaerosols: advances and perspective
Photocatalytic bioaerosol control systems are urgently needed to inactivate airborne pathogenic microorganisms to prevent secondary contamination.
EES. Catal., 2024,2, 138-156
https://doi.org/10.1039/D3EY00179B
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A chemist's guide to photoelectrode development for water splitting – the importance of molecular precursor design
This review outlines the underexplored molecular chemistry bottom-up approach of bespoke precursor design in photoelectrode development for photoelectrochemical water splitting.
EES. Catal., 2023,1, 832-873
https://doi.org/10.1039/D3EY00176H
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Emerging on-chip microcells in electrocatalysis: functions of window and circuit
We discuss current achievements on two basic functions: window and circuit; the former focuses on the active sites, e.g., site identification and monitoring; the latter highlights circuit characteristics, e.g., electrical-field modulation, contact engineering, and in situ conductance.
EES. Catal., 2023,1, 874-891
https://doi.org/10.1039/D3EY00168G
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Atomically imaging single atom catalysts and their behaviors by scanning tunneling microscopy
STM is promising for atomically precise imaging of single-atom catalysts, including their geometric and electronic structures and their behaviors.
EES. Catal., 2023,1, 794-809
https://doi.org/10.1039/D3EY00174A
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Electroreforming injects a new life into solid waste
This review draws the similarities between electroreforming of biomass and plastic derivatives and highlights the pretreatment of raw solid waste, the innovation in catalyst design, and mechanism investigation of waste derivative conversion.
EES. Catal., 2023,1, 892-920
https://doi.org/10.1039/D3EY00147D
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Metal-doped carbon nitride: an all-in-one photocatalyst
Graphitic carbon nitride (CN) has received significant attention for energy conversion. Metal doped CNs, as all-in-one photocatalysts, integrate light absorption, charge separation, and reactive site by incorporating atomic metal into CN framework.
EES. Catal., 2023,1, 810-831
https://doi.org/10.1039/D3EY00123G
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Strategies for the design of ruthenium-based electrocatalysts toward acidic oxygen evolution reaction
This review provides a thorough discussion of fundamental mechanistic understanding, attempts at advanced Ru-based acidic OER catalysts, and future research opportunities.
EES. Catal., 2023,1, 619-644
https://doi.org/10.1039/D3EY00092C
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Recent advances in electrocatalytic NOx reduction into ammonia
Electrochemical ammonia synthesis from gaseous NOx pollutant enables the replacement of conventional Haber-Bosch process. This review summarizes the efforts toward electrocatalyst development for selective NH3 production from NOx.
EES. Catal., 2023,1, 645-664
https://doi.org/10.1039/D3EY00090G
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Microkinetic studies for mechanism interpretation in electrocatalytic CO and CO2 reduction: current and perspective
The accurate and reliable microkinetic modeling of electrochemical CO2 reduction requires a synergistic combination of experimental and computational approaches, alongside the use of operando spectroscopies as complementary techniques.
EES. Catal., 2023,1, 590-618
https://doi.org/10.1039/D3EY00079F
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Single-site catalysts for CO2 electroreduction
The emerging single-site catalysts for electrochemical CO2 reduction have been comprehensively summarized and discussed, including their catalytic mechanisms, synthesis, optimization strategies, remaining challenges and perspectives.
EES. Catal., 2023,1, 434-458
https://doi.org/10.1039/D3EY00063J
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Catalytic hydrogen storage in liquid hydrogen carriers
The storage and transportation of hydrogen remain significant hurdles for its commercialization and large-scale implementation. Liquid hydrogen carriers have emerged as promising solutions in hydrogen energy conversion systems.
EES. Catal., 2023,1, 459-494
https://doi.org/10.1039/D3EY00076A
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Strategies for reducing the overpotential of one-dimensional Si nanostructured photoelectrodes for solar hydrogen production
Strategies to reduce the overpotential of 1D silicon nanostructured photoelectrodes for solar hydrogen generation: co-catalysts to improve the reaction kinetics, hetero- and homo-junctions to improve carrier collection and enhance photovoltage.
EES. Catal., 2023,1, 392-412
https://doi.org/10.1039/D3EY00073G
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Electrocatalysts for value-added electrolysis coupled with hydrogen evolution
Recent progresses of value-added electrolysis that replace OER with value-added anodic reactions. Representation of the elements: hydrogen (white color), carbon (gray), oxygen (red), nitrogen (blue), and iodine (magenta).
EES. Catal., 2023,1, 413-433
https://doi.org/10.1039/D3EY00017F
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Layered double hydroxides and their composites as high-performance photocatalysts for CO2 reduction
The panorama of the latest developments of LDH-based photocatalysts for CO2 reduction is exhibited.
EES. Catal., 2023,1, 369-391
https://doi.org/10.1039/D3EY00080J
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A review of the recent progress on direct heterogeneous catalytic CO2 hydrogenation to gasoline-range hydrocarbons
This review presents important progress, main catalytic systems and critical scientific issues on direct heterogeneous catalytic CO2 hydrogenation to gasoline-range hydrocarbons.
EES. Catal., 2023,1, 353-368
https://doi.org/10.1039/D3EY00026E
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Advances in organic semiconductors for photocatalytic hydrogen evolution reaction
This article reviews organic photocatalyst hydrogen evolution reaction (HER), discussing the excitonic behaviour and improvement strategies. It also covers progress in organic photocatalysts, and assesses HER efficiency and stability.
EES. Catal., 2023,1, 333-352
https://doi.org/10.1039/D3EY00047H
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Recent advances in perovskite oxide electrocatalysts for Li–O2 batteries
This review provides a timely and comprehensive understanding of recent advances towards perovskite-based catalysts for lithium–oxygen batteries.
EES. Catal., 2023,1, 230-249
https://doi.org/10.1039/D3EY00028A
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Clarifying the local microenvironment of metal–organic frameworks and their derivatives for electrochemical CO2 reduction: advances and perspectives
Electrochemical CO2 reduction has been widely explored since 1970's, which could alleviate the current environmental and energy crisis caused by excessive CO2. Various strategies have been developed, including engineering and optimization of electrolytic cells and catalysts.
EES. Catal., 2023,1, 179-229
https://doi.org/10.1039/D3EY00018D
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Evolution of singlet oxygen in peroxymonosulfate activation: a review
Given that sulfate-radical-based advanced oxidation processes (SR-AOPs) have attracted great attention in recent years, PMS activation has been reckoned to be an alternative method to the Fenton process in environmental remediation.
EES. Catal., 2023,1, 103-116
https://doi.org/10.1039/D2EY00107A
About this collection
In addition to high quality research papers, EES Catalysis features topical review articles. Reviews will be added to this webpage as soon as possible after publication.