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Themed collection Celebrating the Chemical Sciences in India - Leaders in the Field Symposium 2020

38 items
Open Access Perspective

Diverse strategies for transition metal catalyzed distal C(sp3)–H functionalizations

Transition metal catalyzed C(sp3)–H functionalization is a rapidly growing field.

Graphical abstract: Diverse strategies for transition metal catalyzed distal C(sp3)–H functionalizations
Open Access Perspective

From CO2 activation to catalytic reduction: a metal-free approach

This review article documents the key developments in the metal-free catalytic reduction of CO2 into various energy intensive chemicals and fuels, and reductive functionalization of CO2 for the formation of new C–N bonds.

Graphical abstract: From CO2 activation to catalytic reduction: a metal-free approach
From the themed collection: Celebrating 10 years of Chemical Science
Open Access Perspective

Metal–organic framework gels and monoliths

This perspective links the synthesis of MOF Gels to the formation of MOF-monoliths and their resultant properties and application.

Graphical abstract: Metal–organic framework gels and monoliths
Open Access Edge Article

Switching between mono and doubly reduced odd alternant hydrocarbon: designing a redox catalyst

A doubly reduced redox non-innocent phenalenyl based transition metal free catalyst has been designed and utilized in the development of the C–C cross coupling reaction through the activation of aryl halides at room temperature.

Graphical abstract: Switching between mono and doubly reduced odd alternant hydrocarbon: designing a redox catalyst
Open Access Edge Article

Mechanistic insights into rhodium-catalyzed enantioselective allylic alkylation for quaternary stereogenic centers

The origin of high enantioselectivity in the formation of quaternary stereogenic carbon.

Graphical abstract: Mechanistic insights into rhodium-catalyzed enantioselective allylic alkylation for quaternary stereogenic centers
Open Access Edge Article

Controlled synthesis of organic two-dimensional nanostructures via reaction-driven, cooperative supramolecular polymerization

We report the kinetically controlled supramolecular polymerization of organic two-dimensional charge-transfer nanostructures via a chemical reaction (imine)-driven approach.

Graphical abstract: Controlled synthesis of organic two-dimensional nanostructures via reaction-driven, cooperative supramolecular polymerization
From the themed collection: Celebrating 10 years of Chemical Science
Open Access Edge Article

A new pentacyclic pyrylium fluorescent probe that responds to pH imbalance during apoptosis

A modified Vilsmeier–Haack reaction resulted in the synthesis of a pyrylium based turn-on fluorescent pH probe. The probe can monitor minute acidification and dynamic pH variation in cells during apoptosis with therapeutic chemo drugs.

Graphical abstract: A new pentacyclic pyrylium fluorescent probe that responds to pH imbalance during apoptosis
From the themed collection: Celebrating 10 years of Chemical Science
Open Access Edge Article

A new route to porous metal–organic framework crystal–glass composites

A lower temperature route to metal–organic framework crystal–glass composites is presented. Specifically, the annealing pre-formed ZIF-62 glass with a crystalline MOF above Tg will enable formation of a greatly expanded range of materials.

Graphical abstract: A new route to porous metal–organic framework crystal–glass composites
Open Access Edge Article

A direct route to six and seven membered lactones via γ-C(sp3)–H activation: a simple protocol to build molecular complexity

Six and seven membered lactones have been synthesized directly from readily available aliphatic acids.

Graphical abstract: A direct route to six and seven membered lactones via γ-C(sp3)–H activation: a simple protocol to build molecular complexity
Open Access Edge Article

Structure–activity relationships in well-defined conjugated oligomer photocatalysts for hydrogen production from water

Oligomer chain length and backbone twisting were found to have a strong effect on optoelectronic properties but a trimer of dibenzo[b,d]thiophene sulfone was found to have high photocatalytic activity approaching that of its polymer analogue.

Graphical abstract: Structure–activity relationships in well-defined conjugated oligomer photocatalysts for hydrogen production from water
From the themed collection: 2020 Chemical Science HOT Article Collection
Open Access Edge Article

Continuous and scalable synthesis of a porous organic cage by twin screw extrusion (TSE)

Twin screw extrusion (TSE) is demonstrated as an alternative synthetic method for preparing a prolific porous organic cage.

Graphical abstract: Continuous and scalable synthesis of a porous organic cage by twin screw extrusion (TSE)
From the themed collection: Celebrating 10 years of Chemical Science
Open Access Edge Article

Geometric landscapes for material discovery within energy–structure–function maps

We introduce a representation for the geometric features of the pores of porous molecular crystals. This representation provides a good basis for supervised (predict adsorption properties) and unsupervised (polymorph classification) tasks.

Graphical abstract: Geometric landscapes for material discovery within energy–structure–function maps
From the themed collection: 2020 Chemical Science HOT Article Collection
Open Access Edge Article

Exploring long-range proton conduction, the conduction mechanism and inner hydration state of protein biopolymers

Post formation modification of protein-based materials can attenuate the proton conduction efficiency resulting from change in conduction mechanism, charge carrier mobility, carrier concentrations and inner hydration layer.

Graphical abstract: Exploring long-range proton conduction, the conduction mechanism and inner hydration state of protein biopolymers
Open Access Edge Article

Transition metal-free catalytic reduction of primary amides using an abnormal NHC based potassium complex: integrating nucleophilicity with Lewis acidic activation

An abnormal N-heterocyclic carbene (aNHC) based potassium complex was used as a transition metal-free catalyst for reduction of primary amides to corresponding primary amines under ambient conditions.

Graphical abstract: Transition metal-free catalytic reduction of primary amides using an abnormal NHC based potassium complex: integrating nucleophilicity with Lewis acidic activation
Open Access Edge Article

A stable covalent organic framework for photocatalytic carbon dioxide reduction

A metal-decorated alkene-linked covalent organic framework is a robust, selective photocatalyst for CO2 reduction.

Graphical abstract: A stable covalent organic framework for photocatalytic carbon dioxide reduction
Open Access Edge Article

Is silver a mere terminal oxidant in palladium catalyzed C–H bond activation reactions?

We disclose an intriguing and a potentially general role for one of the most commonly used silver salt additives whose molecular understanding continues to remain rather vague in the contemporary practice of palladium catalysis.

Graphical abstract: Is silver a mere terminal oxidant in palladium catalyzed C–H bond activation reactions?
Open Access Edge Article

Mining predicted crystal structure landscapes with high throughput crystallisation: old molecules, new insights

New crystal forms of two well-studied organic molecules are identified in a computationally targeted way, by combining structure prediction with a robotic crystallisation screen, including a ‘hidden’ porous polymorph of trimesic acid.

Graphical abstract: Mining predicted crystal structure landscapes with high throughput crystallisation: old molecules, new insights
Open Access Edge Article

Freeze the dynamicity: charge transfer complexation assisted control over the reaction pathway

Aqueous CT complexes of donor and acceptor molecules with reactive thiol groups were frozen and lyophilized to get alternate D–A assemblies in the solid state. Oxidation of the thiols resulted in asymmetric disulfides exclusively.

Graphical abstract: Freeze the dynamicity: charge transfer complexation assisted control over the reaction pathway
Open Access Edge Article

Accelerated robotic discovery of type II porous liquids

High-throughput automation was used to streamline the synthesis, characterisation, and solubility testing, of new Type II porous liquids, accelerating their discovery.

Graphical abstract: Accelerated robotic discovery of type II porous liquids
Open Access Edge Article

Zinc ion interactions in a two-dimensional covalent organic framework based aqueous zinc ion battery

We have demonstrated a hydroquinone stitched β-ketoenamine COF acting as an efficient organic cathode in an aqueous rechargeable zinc ion battery.

Graphical abstract: Zinc ion interactions in a two-dimensional covalent organic framework based aqueous zinc ion battery
Open Access Edge Article

B(C6F5)3-catalyzed dehydrogenative cyclization of N-tosylhydrazones and anilines via a Lewis adduct: a combined experimental and computational investigation

Metal-free acceptorless-dehydrogenative cyclization of N-tosylhydrazones and aromatic amines produces both symmetrical and unsymmetrical 1,2,4-triazoles in high yields and selectivities.

Graphical abstract: B(C6F5)3-catalyzed dehydrogenative cyclization of N-tosylhydrazones and anilines via a Lewis adduct: a combined experimental and computational investigation
Open Access Edge Article

Organobase triggered controlled supramolecular ring opening polymerization and 2D assembly

Spontaneously aggregation of a carboxylic acid appended NDI can be retarted by intra-molecular H-bonding. With catalytic DMAP or DBU, the meta-stable monomer exhibits living supramolecular polymerization and generates ultra-thin 2D sheet.

Graphical abstract: Organobase triggered controlled supramolecular ring opening polymerization and 2D assembly
Open Access Edge Article

Rhodium catalyzed template-assisted distal para-C–H olefination

We report first example of template assisted rhodium catalyzed para-C–H alkenylation.

Graphical abstract: Rhodium catalyzed template-assisted distal para-C–H olefination
Open Access Edge Article

Storing redox equivalent in the phenalenyl backbone towards catalytic multi-electron reduction

Redox equivalent storage in the phenalenyl backbone towards catalytic multi-electron reduction.

Graphical abstract: Storing redox equivalent in the phenalenyl backbone towards catalytic multi-electron reduction
Open Access Edge Article

Hypercoordinate iodine for catalytic asymmetric diamination of styrene: insights into the mechanism, role of solvent, and stereoinduction

Stereoselectivity in the asymmetric diamination of styrene catalyzed by chiral hypercoordinate iodine originates from the prochiral face recognition when the substrate binds to the catalyst.

Graphical abstract: Hypercoordinate iodine for catalytic asymmetric diamination of styrene: insights into the mechanism, role of solvent, and stereoinduction
Open Access Edge Article

Plasmonic colloidosomes of black gold for solar energy harvesting and hotspots directed catalysis for CO2 to fuel conversion

Plasmonic black gold converts CO2 to methane using solar energy.

Graphical abstract: Plasmonic colloidosomes of black gold for solar energy harvesting and hotspots directed catalysis for CO2 to fuel conversion
Open Access Edge Article

Unusual confinement properties of a water insoluble small peptide hydrogel

A water insoluble peptide-hydrogel that shows unique compartmentalization by not allowing any exchange to and from the hydrogel and can protect enzymes from denaturation.

Graphical abstract: Unusual confinement properties of a water insoluble small peptide hydrogel
Open Access Edge Article

Insights into the role of noncovalent interactions in distal functionalization of the aryl C(sp2)–H bond

How a series of noncovalent interactions (NCIs) determine the regiochemical outcome in a distal sp2 C–H functionalization reaction is presented.

Graphical abstract: Insights into the role of noncovalent interactions in distal functionalization of the aryl C(sp2)–H bond
Open Access Edge Article

Flux melting of metal–organic frameworks

We show flux melting by using a liquid MOF as a solvent for a secondary, non-melting MOF component.

Graphical abstract: Flux melting of metal–organic frameworks
Open Access Edge Article

Transforming atmospheric CO2 into alternative fuels: a metal-free approach under ambient conditions

The present work established the metal-free approach to capture CO2 from air and its reduction into alternative fuel under ambient conditions.

Graphical abstract: Transforming atmospheric CO2 into alternative fuels: a metal-free approach under ambient conditions
Open Access Edge Article

Reduction of CO2 by a masked two-coordinate cobalt(I) complex and characterization of a proposed oxodicobalt(II) intermediate

The detailed mechanism of CO2 reduction by a cobalt(I) complex is investigated using computations and kinetics.

Graphical abstract: Reduction of CO2 by a masked two-coordinate cobalt(i) complex and characterization of a proposed oxodicobalt(ii) intermediate
Open Access Edge Article

Two chiral catalysts in action: insights into cooperativity and stereoselectivity in proline and cinchona-thiourea dual organocatalysis

Increasing use of two chiral catalysts in cooperative asymmetric catalysis in recent years raises some fundamental questions on chiral compatibility between the catalysts, modes of activation, and relative disposition of substrates within the chiral environment of the catalysts for effective asymmetric induction.

Graphical abstract: Two chiral catalysts in action: insights into cooperativity and stereoselectivity in proline and cinchona-thiourea dual organocatalysis
Open Access Edge Article

Selective C–H halogenation over hydroxylation by non-heme iron(IV)-oxo

Synthetic non-heme iron-oxo and iron-halide complexes promote selective halogenation of the sp3-C–H bonds via hydrogen atom abstraction and halide rebound phenomenon.

Graphical abstract: Selective C–H halogenation over hydroxylation by non-heme iron(iv)-oxo
Open Access Edge Article

Origin of stereoselectivity in the amination of alcohols using cooperative asymmetric dual catalysis involving chiral counter-ions

Transition state models are proposed for chiral counterion induced stereoselectivity in cooperative dual catalysis access to the amination of alcohols.

Graphical abstract: Origin of stereoselectivity in the amination of alcohols using cooperative asymmetric dual catalysis involving chiral counter-ions
Open Access Edge Article

Selective activation of organocatalysts by specific signals

Activation of the responsive organocatalyst proline by three different signals allows temporal control over chemical reaction kinetics.

Graphical abstract: Selective activation of organocatalysts by specific signals
Open Access Edge Article

Controlling destructive quantum interference in tunneling junctions comprising self-assembled monolayers via bond topology and functional groups

Three different benzodithiophene derivatives were designed to isolate the effects of bond topology from that of functional groups in quantum interference to examine the role of the quinone functionality separate from cross-conjugation.

Graphical abstract: Controlling destructive quantum interference in tunneling junctions comprising self-assembled monolayers via bond topology and functional groups
Open Access Edge Article

Linking defects, hierarchical porosity generation and desalination performance in metal–organic frameworks

The composite membranes with defective metal–organic frameworks (MOFs) show a significant increase in water flux, without compromising the high salt rejection.

Graphical abstract: Linking defects, hierarchical porosity generation and desalination performance in metal–organic frameworks
Open Access Edge Article

Tuning the redox non-innocence of a phenalenyl ligand toward efficient nickel-assisted catalytic hydrosilylation

The hydrosilylation of olefins by a nickel(II) catalyst assisted by a redox non-innocent phenalenyl (PLY) ligand is reported.

Graphical abstract: Tuning the redox non-innocence of a phenalenyl ligand toward efficient nickel-assisted catalytic hydrosilylation
38 items

About this collection

In December 2020, Chemical Science supported IISER Kolkata, India in hosting a Leaders in the Field Symposium, which showcased innovative chemistry research from both established and early career researchers in India. This specially curated collection includes recent Chemical Science articles authored by the presenters and organisers of the Leaders in the Field Symposium and as with all Chemical Science articles – they are all completely free to access and read. We hope you enjoy browsing through this collection.

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