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Themed collection CO2 Utilisation

27 items
Perspective

CO2 hydrogenation over heterogeneous catalysts at atmospheric pressure: from electronic properties to product selectivity

The fundamental insights into the relationships among the electronic properties of active metals, the binding strengths of key intermediates, and the CO2 hydrogenation selectivity are provided.

Graphical abstract: CO2 hydrogenation over heterogeneous catalysts at atmospheric pressure: from electronic properties to product selectivity
From the themed collection: Green Chemistry Reviews
Tutorial Review

Recent progress in the catalytic transformation of carbon dioxide into biosourced organic carbonates

The recent advances made in the catalytic preparation of biobased cyclic carbonates derived from sugars, glycerol, fatty acids/vegetable oils and terpenes are presented, together with a discussion surrounding their potential applications.

Graphical abstract: Recent progress in the catalytic transformation of carbon dioxide into biosourced organic carbonates
From the themed collection: Green Chemistry Reviews
Critical Review

Photochemical reduction of carbon dioxide to formic acid

This review presents an overview of the photoreduction of CO2 to formic acid using homogeneous catalysts.

Graphical abstract: Photochemical reduction of carbon dioxide to formic acid
From the themed collection: Green Chemistry Reviews
Critical Review

Biological carbon fixation: a thermodynamic perspective

Changes of Gibbs free energy made insights into the carbon fixation pathways from thermodynamic perspective.

Graphical abstract: Biological carbon fixation: a thermodynamic perspective
From the themed collection: 2021 Green Chemistry Hot Articles
Critical Review

Oxidative dehydrogenation of light alkanes with carbon dioxide

In this critical review, the recent advances of the CO2-assisted catalytic dehydrogenation of light alkanes are summarized.

Graphical abstract: Oxidative dehydrogenation of light alkanes with carbon dioxide
From the themed collection: Green Chemistry Reviews
Open Access Critical Review

Recent developments in organocatalysed transformations of epoxides and carbon dioxide into cyclic carbonates

The synthesis of cyclic carbonates from epoxides and carbon dioxide using metal-free catalyst systems is critically reviewed.

Graphical abstract: Recent developments in organocatalysed transformations of epoxides and carbon dioxide into cyclic carbonates
From the themed collection: Green Chemistry Reviews
Critical Review

From ‘Gift’ to gift: producing organic solvents from CO2

The latest advances in the field of production of commonly used organic solvents from CO2 are summarized and discussed.

Graphical abstract: From ‘Gift’ to gift: producing organic solvents from CO2
From the themed collection: CO2 Utilisation
Communication

One-step plasma-enabled catalytic carbon dioxide hydrogenation to higher hydrocarbons: significance of catalyst-bed configuration

C2+ hydrocarbons are selectively produced in one-step catalytic CO2 conversion via designing the catalyst-bed configuration under non-thermal DBD plasma operating at low temperature and atmospheric pressure.

Graphical abstract: One-step plasma-enabled catalytic carbon dioxide hydrogenation to higher hydrocarbons: significance of catalyst-bed configuration
From the themed collection: CO2 Utilisation
Communication

Transition-metal-free synthesis of thiazolidin-2-ones and 1,3-thiazinan-2-ones from arylamines, elemental sulfur and CO2

A multi-component reaction of arylamines, elemental sulfur and CO2 (1 atm) is reported to generate valuable thiazolidin-2-ones and 1,3-thiazinan-2-ones in moderate to good yields under transition-metal-free reaction conditions.

Graphical abstract: Transition-metal-free synthesis of thiazolidin-2-ones and 1,3-thiazinan-2-ones from arylamines, elemental sulfur and CO2
From the themed collection: 2021 Green Chemistry Hot Articles
Communication

Rh(I)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2

The first Rh(I)-catalyzed regioselective arylcarboxylation of electron-deficient acrylamides with arylboronic acids under atmospheric pressure of CO2 has been developed.

Graphical abstract: Rh(i)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2
From the themed collection: CO2 Utilisation
Communication

Photoredox-catalyzed dicarbofunctionalization of styrenes with amines and CO2: a convenient access to γ-amino acids

Visible-light-mediated regioselective carbocarboxylation of styrenes using CO2 and amines to generate important γ-amino acids has been realized by photocatalysis.

Graphical abstract: Photoredox-catalyzed dicarbofunctionalization of styrenes with amines and CO2: a convenient access to γ-amino acids
From the themed collection: CO2 Utilisation
Paper

Electrochemical CO2 reduction on graphdiyne: a DFT study

Graphdiyne exhibits high activity for CO2 electroreduction reaction and the unique sp–sp2 hybridization is crucial.

Graphical abstract: Electrochemical CO2 reduction on graphdiyne: a DFT study
From the themed collection: CO2 Utilisation
Paper

Highly efficient synthesis of alkylidene cyclic carbonates from low concentration CO2 using hydroxyl and azolate dual functionalized ionic liquids

A dual functionalized ionic liquid catalytic system was developed for the reaction between CO2 and propargylic alcohols, and exhibited excellent performance and good reusability, even under a low concentration of CO2 in a gram-scale reaction.

Graphical abstract: Highly efficient synthesis of alkylidene cyclic carbonates from low concentration CO2 using hydroxyl and azolate dual functionalized ionic liquids
From the themed collection: CO2 Utilisation
Paper

A self-healing and recyclable polyurethane-urea Diels–Alder adduct synthesized from carbon dioxide and furfuryl amine

A green route to synthesize a self-healing polyurethane-urea Diels–Alder adduct (PUUa-DA) using CO2 and furfuryl amine as renewable feedstocks is reported.

Graphical abstract: A self-healing and recyclable polyurethane-urea Diels–Alder adduct synthesized from carbon dioxide and furfuryl amine
From the themed collection: CO2 Utilisation
Paper

Molecular H2O promoted catalytic bicarbonate reduction with methanol into formate over Pd0.5Cu0.5/C under mild hydrothermal conditions

Molecular water promoted co-conversion of bicarbonate and methanol into formate over a Pd–Cu catalyst: a H2-free approach for bicarbonate reduction.

Graphical abstract: Molecular H2O promoted catalytic bicarbonate reduction with methanol into formate over Pd0.5Cu0.5/C under mild hydrothermal conditions
From the themed collection: CO2 Utilisation
Paper

Carbon dioxide derived carbonized polymer dots for multicolor light-emitting diodes

Immobilization of carbon dioxide into fluorescent CPDs is achieved, and multiple-color LEDs are fabricated using the CPDs as single phosphors.

Graphical abstract: Carbon dioxide derived carbonized polymer dots for multicolor light-emitting diodes
From the themed collection: CO2 Utilisation
Paper

A rhenium catalyst with bifunctional pyrene groups boosts natural light-driven CO2 reduction

A rhenium–pyrene catalyst that dramatically promotes sunlight-induced CO2RR efficiency was developed by enhancing intermolecular electron transfer efficiency and visible light-harvesting ability.

Graphical abstract: A rhenium catalyst with bifunctional pyrene groups boosts natural light-driven CO2 reduction
From the themed collection: CO2 Utilisation
Paper

Highly effective capture and subsequent catalytic transformation of low-concentration CO2 by superbasic guanidines

We have developed a novel N,N′-bis(imidazolyl)guanidine-based system, which shows high performance in low-concentration CO2 capture and subsequent catalytic transformation to functionalized (4E,5Z)-4-imino-5-benzylideneoxazolidine-2-ones.

Graphical abstract: Highly effective capture and subsequent catalytic transformation of low-concentration CO2 by superbasic guanidines
From the themed collection: CO2 Utilisation
Paper

Near neutral waterborne cationic polyurethane from CO2-polyol, a compatible binder to aqueous conducting polyaniline for eco-friendly anti-corrosion purposes

A near-neutral waterborne cationic polyurethane from CO2-polyol was synthesized using BDE as an internal emulsifier. Its compatibility with an aqueous cPANI dispersion and strong adhesion to CS plates mean it could be used for corrosion protection.

Graphical abstract: Near neutral waterborne cationic polyurethane from CO2-polyol, a compatible binder to aqueous conducting polyaniline for eco-friendly anti-corrosion purposes
From the themed collection: CO2 Utilisation
Paper

Integrating Z-scheme heterojunction of Co1-C3N4@α-Fe2O3 for efficient visible-light-driven photocatalytic CO2 reduction

A direct Z-scheme heterojunction of Co1-C3N4@α-Fe2O3 was constructed for efficient photocatalytic CO2 reduction coupled with water oxidation under visible-light irradiation, with a CO generation rate of 14.9 μmol g−1 h−1 and CO selectivity over 99%.

Graphical abstract: Integrating Z-scheme heterojunction of Co1-C3N4@α-Fe2O3 for efficient visible-light-driven photocatalytic CO2 reduction
From the themed collection: CO2 Utilisation
Paper

Electrodeposited Cu–Pd bimetallic catalysts for the selective electroreduction of CO2 to ethylene

Cu–Pd bimetallic catalysts were fabricated on carbon paper (CP) by the electrodeposition method via a dynamic hydrogen bubble template approach.

Graphical abstract: Electrodeposited Cu–Pd bimetallic catalysts for the selective electroreduction of CO2 to ethylene
From the themed collection: CO2 Utilisation
Paper

Tuning the coordination number of Fe single atoms for the efficient reduction of CO2

The coordination number of Fe single-atom catalysts (Fe–N5/Fe–N6) significantly affects the electrocatalytic performance during CO2-to-CO conversion.

Graphical abstract: Tuning the coordination number of Fe single atoms for the efficient reduction of CO2
From the themed collection: CO2 Utilisation
Paper

Tuning selectivity of CO2 hydrogenation by modulating the strong metal–support interaction over Ir/TiO2 catalysts

Modulating the strong metal-support interaction over Ir/TiO2 offers an opportunity for selective transformation of CO2 hydrogenation from CH4 to CO.

Graphical abstract: Tuning selectivity of CO2 hydrogenation by modulating the strong metal–support interaction over Ir/TiO2 catalysts
From the themed collection: CO2 Utilisation
Paper

Stabilization of Cu+ by tuning a CuO–CeO2 interface for selective electrochemical CO2 reduction to ethylene

By utilizing the synergistic interaction between CuO and CeO2, the stabilization of Cu+ species at a metal–oxide interface is realized. H2 production is considerably suppressed, resulting in enhanced ethylene production with a high FE of 50.0%.

Graphical abstract: Stabilization of Cu+ by tuning a CuO–CeO2 interface for selective electrochemical CO2 reduction to ethylene
From the themed collection: CO2 Utilisation
Paper

Calix[8]arene-constructed stable polyoxo-titanium clusters for efficient CO2 photoreduction

Self-assembly and CO2 photoreduction performance of two thermodynamically reversibly converted polyoxo-titanium clusters (PTCs), Ti4-C8A and Ti7-C8A, which were modified by calix[8]arene organic “functional armor”.

Graphical abstract: Calix[8]arene-constructed stable polyoxo-titanium clusters for efficient CO2 photoreduction
From the themed collection: CO2 Utilisation
Paper

Tetracoordinate borates as catalysts for reductive formylation of amines with carbon dioxide

The first example of borate-catalyzed N-formylation of amines using CO2 as the carbon source in the presence of hydrosilanes is demonstrated using sodium (trihydroxy)phenylborate as a transition metal-free catalyst.

Graphical abstract: Tetracoordinate borates as catalysts for reductive formylation of amines with carbon dioxide
From the themed collection: CO2 Utilisation
Paper

A highly active Pt/In2O3 catalyst for CO2 hydrogenation to methanol with enhanced stability

An In2O3 supported Pt catalyst shows a significantly improved activity towards CO2 hydrogenation with methanol selectivity of ca. 100% at temperatures below 225 °C, 73% at 275 °C and 54% at 300 °C.

Graphical abstract: A highly active Pt/In2O3 catalyst for CO2 hydrogenation to methanol with enhanced stability
From the themed collection: CO2 Utilisation
27 items

About this collection

As is well known, the massive consumption of fossil fuels, among other human activities, has released substantial amounts of CO2 into the atmosphere, provoking both global warming and dramatic climate changes. As such, carbon dioxide capture and utilisation continues to attract significant attention, and important advances. As an ideal C1 source, efficient transformation of CO2 enables the sustainable synthesis of high value-added chemicals and fuels. Moreover, CO2 can be utilised in a huge number of diverse areas, including as a green tuneable solvent, a working agent, a protective agent, a soft oxidant, and many others. Guest Edited by Professor Liang-Nian He (Nankai University, P. R. China) and Professor Da-Gang Yu (Sichuan University, P. R. China).

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