
Bioinspired double network hydrogels: from covalent double network hydrogels via hybrid double network hydrogels to physical double network hydrogels
This minireview discusses the advantages and challenges in constructing bioinspired double-network hydrogels mimicking the structure and/or properties of biological tissue.
Mater. Horiz., 2021,8, 1173-1188
https://doi.org/10.1039/D0MH01514H
Radiative heat transfer at the nanoscale: experimental trends and challenges
Beyond the usual surface-to-surface Planck's law of thermal radiation, nanoscale radiative heat transfer is experiencing a revolution.
Nanoscale Horiz., 2021,6, 201-208
https://doi.org/10.1039/D0NH00609B

Advanced technologies for the fabrication of MOF thin films
In this Minireview, we discuss several appealing approaches that have been developed in the last few years for the fabrication of MOF thin films, highlighting their assets and the challenges still faced.
Mater. Horiz., 2021,8, 168-178
https://doi.org/10.1039/D0MH00898B
Toward printable solar cells based on PbX colloidal quantum dot inks
This review summarizes the advances in solar cells based on PbX CQD inks, including both lab-scale and large-area photovoltaic devices.
Nanoscale Horiz., 2021,6, 8-23
https://doi.org/10.1039/D0NH00488J

Toward the Creation of High-performance Heterogeneous Catalysts by Controlled Ligand Desorption from Atomically Precise Metal Nanoclusters
Nanoscale Horiz., 2021, Accepted Manuscript
https://doi.org/10.1039/D1NH00046B
Catalytic methods for chemical recycling or upcycling of commercial polymers
A review covering catalytic method development to enable efficient chemical recycling and upcycling of the most abundant commercial polymers.
Mater. Horiz., 2021,8, 1084-1129
https://doi.org/10.1039/D0MH01286F

Artificial intelligence and machine learning in design of mechanical materials
This review revisits the state of the art of research efforts on the design of mechanical materials using machine learning.
Mater. Horiz., 2021,8, 1153-1172
https://doi.org/10.1039/D0MH01451F
Niobium pentoxide based materials for high rate rechargeable electrochemical energy storage
This review summarizes the crystalline features, electrochemical characteristics, ions intercalation charge storage mechanisms, and recent advances in niobium pentoxide related materials for high-rate electrochemical energy storage.
Mater. Horiz., 2021,8, 1130-1152
https://doi.org/10.1039/D0MH01481H
Rare-earth quantum cutting in metal halide perovskites – a review
Ytterbium-doped lead halide perovskite (Yb3+:CsPbX3 with x = Cl or Cl/Br) nanocrystals and thin films have shown surprisingly efficient downconversion by quantum cutting with PLQYs up to 193%.
Mater. Horiz., 2021,8, 1072-1083
https://doi.org/10.1039/D0MH01470B
Boolean logic gate based on DNA strand displacement for biosensing: current and emerging strategies
The integration of various materials and technologies enables the intelligent SDLG biosensor to detect the different types of targets with high sensitivity and generate diversified output signals.
Nanoscale Horiz., 2021,6, 298-310
https://doi.org/10.1039/D0NH00587H
Trust is good, control is better: a review on monitoring and characterization techniques for flow battery electrolytes
This review article summarizes the state-of-the-art techniques for the characterization and monitoring of flow battery electrolytes highlighting in particular the importance of the electrolyte state-of-charge and state-of-health assessment.
Mater. Horiz., 2021, Advance Article
https://doi.org/10.1039/D0MH01632B
SnSe, the rising star thermoelectric material: a new paradigm in atomic blocks, building intriguing physical properties
Thermoelectric materials, which enable direct energy conversion between waste heat and electricity, are witnessing exciting developments due to innovative breakthroughs both in materials and the synergistic optimization of structures and properties.
Mater. Horiz., 2021, Advance Article
https://doi.org/10.1039/D1MH00091H
Recent progress in field-assisted additive manufacturing: materials, methodologies, and applications
Recent developments and major advances in field-assisted additive manufacturing technologies from aspects of materials, methodologies, and applications.
Mater. Horiz., 2021,8, 885-911
https://doi.org/10.1039/D0MH01322F
Nitroxide radical polymers for emerging plastic energy storage and organic electronics: fundamentals, materials, and applications
We review the electrochemical theory, material design, and device fabrication for nitroxide radical polymers in emerging plastic energy storage and organic electronics.
Mater. Horiz., 2021,8, 803-829
https://doi.org/10.1039/D0MH01391A
Review on the growth, properties and applications of self-assembled oxide–metal vertically aligned nanocomposite thin films—current and future perspectives
This review summarizes the recent progress in self-assembled oxide-metal nanocomposites, their design criteria using the in-plane strain compensation model, functionalities, and the coupling between electrical, magnetic and optical properties
Mater. Horiz., 2021,8, 869-884
https://doi.org/10.1039/D0MH01111H
Magnetic skyrmions for unconventional computing
A rich variety of unconventional computing paradigms has been raised with the rapid development of nanoscale devices. Magnetic skyrmions, spin swirling quasiparticles, have been endowed with great expectations for unconventional computing.
Mater. Horiz., 2021,8, 854-868
https://doi.org/10.1039/D0MH01603A
Porous flexible frameworks: origins of flexibility and applications
All major classes of porous crystalline frameworks including zeolites, metal–organic frameworks, covalent organic frameworks and hydrogen-bonded organic frameworks exhibit structural flexibilities.
Mater. Horiz., 2021,8, 700-727
https://doi.org/10.1039/D0MH01710H
Revisiting staining of biological samples for electron microscopy: perspectives for recent research
This review revisits staining protocols for electron microscopy focussing on the visualization of active sites, i.e. enzymes, metabolites or proteins, in cells and tissues, which were never established as standard protocols in electron microscopy.
Mater. Horiz., 2021,8, 685-699
https://doi.org/10.1039/D0MH01579B

Highly selective gas sensing enabled by filters
Sorption, size-selective & catalytic film or particle-bed filters dramatically enhance gas sensor selectivity. We critically review 300+ articles and tutorially give guidelines for systematic filter design in air quality, health & food applications.
Mater. Horiz., 2021,8, 661-684
https://doi.org/10.1039/D0MH01453B
Material design strategies to improve the performance of rechargeable magnesium–sulfur batteries
This review encompasses the underlying working principles behind the most critical approaches to solve challenging issues in Mg–S batteries.
Mater. Horiz., 2021,8, 830-853
https://doi.org/10.1039/D0MH01403F
Engineered two-dimensional nanomaterials: an emerging paradigm for water purification and monitoring
This review aims to comprehensively summarize the significant developments in design strategies, processing approaches, and application-oriented techniques of 2D nanomaterials for water purification and monitoring.
Mater. Horiz., 2021,8, 758-802
https://doi.org/10.1039/D0MH01358G
Light-driven bimorph soft actuators: design, fabrication, and properties
This review provides an account of the state-of-the-art light-driven bimorph soft actuators from their fundamentals to emerging applications, as well as new perspectives on the future scope, opportunities, and challenges.
Mater. Horiz., 2021,8, 728-757
https://doi.org/10.1039/D0MH01406K
Electrocatalysis of gold-based nanoparticles and nanoclusters
Gold-based nanomaterials can be used in various electrocatalytic reactions. The rational tuning of their composition, architecture, and particle size can achieve enhanced electrocatalytic activity.
Mater. Horiz., 2021, Advance Article
https://doi.org/10.1039/D0MH01947J
Recent advances in printed flexible heaters for portable and wearable thermal management
This review presents the recent progress of printed flexible heaters for portable and wearable thermal management.
Mater. Horiz., 2021, Advance Article
https://doi.org/10.1039/D0MH01950J
Polydopamine antibacterial materials
This review focuses on the recent progress in polydopamine antibacterial materials, including their structural and functional features, preparation strategies, antibacterial mechanisms, and their biomedical applications.
Mater. Horiz., 2021, Advance Article
https://doi.org/10.1039/D0MH01985B
Porous bioactive glass micro- and nanospheres with controlled morphology: developments, properties and emerging biomedical applications
Porous bioactive glass micro- and nanospheres are attractive biomaterials for biomedical applications: bone regeneration, wound healing, drug delivery and theranostics.
Mater. Horiz., 2021,8, 300-335
https://doi.org/10.1039/D0MH01498B
Recent advances in dioxaborine-based fluorescent materials for bioimaging applications
Dioxaborine-based materials, including molecules and nanoparticles, possess various interesting photophysical properties allowing advanced bioimaging from cells to in vivo.
Mater. Horiz., 2021,8, 501-514
https://doi.org/10.1039/D0MH01186J
Solution-processed electronics for artificial synapses
Solution-processed artificial synapses are expected to develop the synaptic electronics towards flexible and highly integrated three-dimensional neural networks to break through the von Neumann computing architecture in the post-Moore era.
Mater. Horiz., 2021,8, 447-470
https://doi.org/10.1039/D0MH01520B
Nanozyme's catching up: activity, specificity, reaction conditions and reaction types
The gaps and catching up strategies between nanozymes and enzymes in terms of their activity, specificity, physiological reaction conditions and biologically relevant reactions are critically reviewed.
Mater. Horiz., 2021,8, 336-350
https://doi.org/10.1039/D0MH01393E
Review on organosulfur materials for rechargeable lithium batteries
Lithium storage properties of organosulfur electrodes including organodisulfide, thioethers, organosulfide polymers and sulfurized polyacrylonitrile have been comprehensively reviewed.
Mater. Horiz., 2021,8, 471-500
https://doi.org/10.1039/D0MH01364A
Recent progress and challenges in solution blow spinning
In the past 30 years, researchers have worked towards reducing the size of ordinary three-dimensional (3D) materials into 1D or 2D materials in order to obtain new properties and applications of these low-dimensional systems.
Mater. Horiz., 2021,8, 426-446
https://doi.org/10.1039/D0MH01096K
Material innovation and mechanics design for substrates and encapsulation of flexible electronics: a review
Advances in materials and mechanics designs have led to the development of flexible electronics, which have important applications to human healthcare due to their good biocompatibility and conformal integration with biological tissue.
Mater. Horiz., 2021,8, 383-400
https://doi.org/10.1039/D0MH00483A
Thermally activated delayed fluorescence exciplex emitters for high-performance organic light-emitting diodes
Owing to their natural thermally activated delayed fluorescence (TADF) characteristics, the development of exciplex emitters for organic light-emitting diodes (OLEDs) has witnessed booming progress in recent years.
Mater. Horiz., 2021,8, 401-425
https://doi.org/10.1039/D0MH01245A
Metal–semiconductor heterostructures for surface-enhanced Raman scattering: synergistic contribution of plasmons and charge transfer
SERS on metal–semiconductor heterostructures including their building blocks, enhancement mechanisms and applications was reviewed. The synergistic contribution of plasmons and charge transfer is highlighted.
Mater. Horiz., 2021,8, 370-382
https://doi.org/10.1039/D0MH01356K
Biomimetic anti-freezing polymeric hydrogels: keeping soft-wet materials active in cold environments
The bio-inspired general synthesis strategies of anti-freezing hydrogels and their potential application fields.
Mater. Horiz., 2021,8, 351-369
https://doi.org/10.1039/D0MH01029D
In vitro and in vivo models for anti-amyloidosis nanomedicines
Impactful research in nanomedicine depends upon the adequate use of cellular and animal models. Here we systematically review and evaluate the in vitro and in vivo models which have enabled the development of anti-amyloidosis nanomedicines.
Nanoscale Horiz., 2021,6, 95-119
https://doi.org/10.1039/D0NH00548G
Targeted liposomal drug delivery: a nanoscience and biophysical perspective
By varying biophysical properties of drug-loaded liposomes such as size, head-group chemistry and polarity, fluidity, rigidity, and PEGylation, their effects on both passive and active targeting are reviewed with cancer therapy as the main example.
Nanoscale Horiz., 2021,6, 78-94
https://doi.org/10.1039/D0NH00605J
Energy-efficient transistors: suppressing the subthreshold swing below the physical limit
We review the physics, design, and optimization of four steep-slope transistors and demonstrate their potential and drawbacks.
Mater. Horiz., 2021, Advance Article
https://doi.org/10.1039/D0MH02029J
Liquid–liquid interfaces: a unique and advantageous environment to prepare and process thin films of complex materials
This review summarizes the recent progress in a novel route to both synthesize and process complex and multi-component materials as thin films, based on interfaces between immiscible liquids, highlighting different materials and applications.
Mater. Horiz., 2021, Advance Article
https://doi.org/10.1039/D0MH01676D
Nanopores in two-dimensional materials: accurate fabrication
This comprehensive and critical review covers the recent important progress of the fabrication of nanopores in two-dimensional materials.
Mater. Horiz., 2021, Advance Article
https://doi.org/10.1039/D0MH01412E
Recent advances toward environment-friendly photodetectors based on lead-free metal halide perovskites and perovskite derivatives
We present a review of the recent advances in environment-friendly photodetectors based on lead-free metal halide perovskites and perovskite derivatives.
Mater. Horiz., 2021, Advance Article
https://doi.org/10.1039/D0MH01567A
Design strategies for ceria nanomaterials: untangling key mechanistic concepts
The present work provides a comprehensive array of design parameters for the fabrication of the principal morphologies of nanoceria.
Mater. Horiz., 2021,8, 102-123
https://doi.org/10.1039/D0MH00654H
Functional separators towards the suppression of lithium dendrites for rechargeable high-energy batteries
This review summarizes the recent advances of functional separators towards the suppression of lithium dendrites in lithium metal batteries.
Mater. Horiz., 2021,8, 12-32
https://doi.org/10.1039/D0MH01167C

Dual emission in purely organic materials for optoelectronic applications
In this review, types and mechanisms of dual emission, as well as recent new insights for the design and applications of efficient novel dual emissive organic materials are presented.
Mater. Horiz., 2021,8, 33-55
https://doi.org/10.1039/D0MH01316A
Polyphenol scaffolds in tissue engineering
This review focuses on the recent advances in polyphenol-based scaffolds including their structural and functional features, fabrication strategies, and various applications in tissue engineering.
Mater. Horiz., 2021,8, 145-167
https://doi.org/10.1039/D0MH01317J
Bio-inspired wettability patterns for biomedical applications
This article reviews the recent progress of the bio-inspired wettability patterns and their biomedical applications.
Mater. Horiz., 2021,8, 124-144
https://doi.org/10.1039/D0MH01293A
Synthesis and application of core–shell liquid metal particles: a perspective of surface engineering
This review answers how to manipulate the surface/interface chemistry of liquid metal micro/nanomaterials for improved applications.
Mater. Horiz., 2021,8, 56-77
https://doi.org/10.1039/D0MH01117G
Chemotherapeutic drug–DNA hybrid nanostructures for anti-tumor therapy
Design, constructions, drug loading strategies and the latest applications of chemotherapeutic drug–DNA hybrid nanostructures.
Mater. Horiz., 2021,8, 78-101
https://doi.org/10.1039/D0MH00715C
Biomaterial-mediated internal radioisotope therapy
Radiation therapy (RT), including external beam radiotherapy (EBRT) and internal radioisotope therapy (RIT), has been an indispensable strategy for cancer therapy in clinical practice in recent years.
Mater. Horiz., 2021, Advance Article
https://doi.org/10.1039/D0MH01761B
About this collection
In addition to first reports of new concepts, Materials Horizons and Nanoscale Horizons publish topical review and minireview articles. Reviews will be added to this webpage as soon as possible after publication.