Themed collection Most popular 2022 catalysis articles

Unsymmetrical ligand scaffolds bridging two or more different metals in a site-selective manner offer a convenient approach to utilize metal–metal cooperation for bond activation.

The controlled functionalization of a single fluorine in a CF₃ group is difficult and rare. Photochemical C–F bond functionalization is achieved using catalysts made from a range of earth-abundant lanthanides by using a ligand that enables M–L cooperativity.

Ylide-substituted phosphines form monomer, air-stable PdCl₂ complexes which feature a unique bonding situation between the metal and the phosphine and ylide donor and exhibit high efficiencies as precatalysts in C–C and C–X cross-coupling reactions.

Two MOF molecular catalyst hybrids with differing topologies show mass and light transport governed photocatalysis. MOF-specific, irradiation wavelength-dependent product control is unlocked by switching between two energy/electron transfer channels.

This study elucidates the role of each class of nanopore by in-depth electrochemical analysis of three types of ZIF-8-derived carbons. Also, engineered co-doping of Fe and N is found essential to selectively form Fe–N_x sites in the carbon matrix.

The electric fields created at solid–liquid interfaces are important in heterogeneous catalysis.

A novel hemilabile MIC^N ligand-based Au(I)-catalytic procedure for the synthesis of γ-substituted γ-butyrolactones through the arylation-lactonization reaction of the corresponding γ-alkenoic acid is presented.

An iron complex with N-heterocyclic carbene ligands engages in efficient photoredox catalysis via excited state electron transfer reactions of its Fe(II) and Fe(III) oxidation states.

An earth-abundant Co-based catalyst, Co@C–N(800), could efficiently catalyze the reductive amination of carbonyl compounds into primary amines at 35 °C owing to the synergistic effect of Co nanoparticles and atomically dispersed Co–N_x sites.

A heterodinuclear Al(III)/K(I) organometallic ring-opening copolymerization catalyst shows exceptional rates, end-group selectivity and good loading tolerance to deliver monodisperse polyesters with molar masses up to 91 kg mol⁻¹.

The hexameric resorcinarene capsule is able to promote carbocation catalysis inside its cavity.

In this work, the first demonstration of heterogeneous photoredox C–N coupling is reported using Ni atoms on C₃N₄. Due to metal–support interactions, high activity and stability were observed during visible-light-driven C–N functionalization.

A robotic workflow for directed evolution of new enzymatic activities via high-throughput library creation and label-free MS screening.

Dynamic dimerization of GOx-loaded microcapsules with β-gal//hemin/G-quadruplex-bridged T₁/T₂-loaded microcapsules guides the bi-directional intercommunication of the three catalysts cascade.

We present the use of gold sensitizers [Au(SIPr)(Cbz)] (PhotAu 1) and [Au(IPr)(Cbz)] (PhotAu 2) as attractive alternatives to state-of-the-art iridium-based systems.

A Ti-based MOF with long-lived Ti³⁺ can achieve dark photocatalysis. The different groups on the organic linker modulate electron storage ability and the lifetime of Ti³⁺, significantly regulating dark photocatalytic activity in H₂ production.

General photoactivation of EDA complexes between arylsulfonium salts and 1,4-diazabicyclo[2.2.2]octane was discovered. This practical mode enables the generation of aryl radicals for C–H functionalization of arenes.

A dual catalytic system based on earth-abundant elements reduces aryl olefins to alkanes in aqueous media under visible light. Mechanistic studies allow for rational tunning of the system for the selective reduction of aryl olefins vs ketones and vice versa.

Rhenium–PNP complexes split N₂ to nitrides, but the nitrides do not give ammonia. Here, the thermodynamics of the hypothetical N–H bond forming steps are evaluated through the reverse reaction, showing that the first H addition is the bottleneck.

Two calix[4]resorcinarene-based chiral POCs with different self-assembly forms were constructed. The difference in the spatial distribution of chiral organocatalytic sites leads to the two chiral POCs exhibiting distinct stereoselectivities.

An efficient spatial separation of photoexcited carriers is demonstrated in a layered-oxyhalide nanoplate by controlling the direction of carrier flows upon Rh cocatalyst loading, which leads to drastic photocatalytic H₂ evolution activity.

A synthetic strategy to prepare 2D heterostructures from ultrathin CeO₂ surface-coordinated metal–organic framework was proposed, proving multiple effects of metal-coordinated interactions in 2D heterostructures.

Indium-containing chabazite zeolites show better stability and C₃H₆ selectivity for propane dehydrogenation than In₂O₃, In/SiO₂ and In/Al₂O₃. Extra-framework In⁺ is identified as the stable active site upon reduction of an impregnated sample.

Simple boranes with the optimal fluoride ion affinity are effective as catalysts for phase transfer nucleophilic fluorination with CsF.

We report a new synthetic approach for the intermolecular α-alkylation of aldehydes with alkyl halides based on a BINOL-phosphate and Cu(II)-porphyrin derived multifunctional CCOF catalyst via visible-light induced photothermal conversion.

The excellent reactivity toward C–H direct arylation, water wettability and O–C p–π conjugation endow EDOT to be an attractive electron donor unit for CP photocatalysts, yielding an unprecedented hydrogen evolution rate up to 0.95 mmol h⁻¹/6 mg catalyst.

A water-stable CsPbBr₃ catalyst is designed using core–shell encapsulation of the perovskite nanoparticle by 2D-C₃N₄ for photo-assisted thermocatalytic CO₂ reduction by H₂O. The m-CN@CsPbBr₃ heterojunction shows surprisingly high CO₂-to-CO yield.