Themed collection Lithium ion batteries – Topic Highlight

30 items
Open Access Perspective

Interfacial engineering of lithium metal anodes: what is left to uncover?

Interfacial engineering plays a key role in solving the reactivity puzzle of lithium metal batteries. Here, we discuss the interfacial engineering pieces that are in place and the ones that still need to be fitted.

Graphical abstract: Interfacial engineering of lithium metal anodes: what is left to uncover?
Open Access Review Article

Organic ionic plastic crystals: flexible solid electrolytes for lithium secondary batteries

This review introduces organic ionic plastic crystals (OIPCs) as Li-ion conductors and recent progress in the development of Li secondary batteries with OIPC-based solid electrolytes.

Graphical abstract: Organic ionic plastic crystals: flexible solid electrolytes for lithium secondary batteries
From the themed collection: Energy Advances Recent Review Articles
Open Access Review Article

Progress in electrode and electrolyte materials: path to all-solid-state Li-ion batteries

This review presents a brief scenario regarding the development of cathodes, anodes, and electrolytes for next-generation Li-ion batteries (LIBs) and supercapacitors for future energy technologies.

Graphical abstract: Progress in electrode and electrolyte materials: path to all-solid-state Li-ion batteries
From the themed collection: Energy Advances Recent Review Articles
Open Access Communication

Realizing a high voltage lithium metal battery in ether-based electrolyte by regulating the cathode electrolyte interphase

The tetrahydrofuran electrolyte with addition of LiNO3 enables the operation of Li||LiNi0.80Co0.10Mn0.10O2 batteries by regulating the cathode electrolyte interphase.

Graphical abstract: Realizing a high voltage lithium metal battery in ether-based electrolyte by regulating the cathode electrolyte interphase
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Communication

Single crystal Ni-rich NMC cathode materials for lithium-ion batteries with ultra-high volumetric energy density

Ultra-high tap density of single crystal Ni-rich NMC cathode materials with the spherical-like particles coupled with high discharge capacity result in up to 40% enhancement in volumetric energy density.

Graphical abstract: Single crystal Ni-rich NMC cathode materials for lithium-ion batteries with ultra-high volumetric energy density
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

Electrospun polar-nanofiber PVDF separator for lithium–sulfur batteries with enhanced charge storage capacity and cycling durability

A designer, polar and nanofibrous PVDF separator for lithium–sulfur battery cells mitigates the polysulfide-shuttling effect that currently limits their potential for commercialisation.

Graphical abstract: Electrospun polar-nanofiber PVDF separator for lithium–sulfur batteries with enhanced charge storage capacity and cycling durability
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

Preparation of carbon–sulphur composite electrodes by solution impregnation and application to all-solid-state lithium–sulphur batteries

Composite electrodes were prepared by impregnating both sulphur and solid electrolyte solutions into the interior of the porous carbon and drying them, and the composites were applied to all solid-state lithium-sulphur batteries.

Graphical abstract: Preparation of carbon–sulphur composite electrodes by solution impregnation and application to all-solid-state lithium–sulphur batteries
Open Access Paper

Solid–liquid–solid mediated artificial SEI coated stable lithium and high-sulfur percentage SPAN for high performance Li–S batteries

Comparison of Li-SPAN pouch cells with and without lithium treatment. The Li-SPAN pouch cell with the PVDF-HFP : DMF lithium treatment shows a LiF rich SEI.

Graphical abstract: Solid–liquid–solid mediated artificial SEI coated stable lithium and high-sulfur percentage SPAN for high performance Li–S batteries
Open Access Paper

A redox acceptor–acceptor nitro functionalized naphthalene diimide/rGO anode for sustainable lithium-ion batteries

This work demonstrates the development of organic material and reduced graphene oxide composites for environment-friendly, stable, and recyclable lithium-ion batteries.

Graphical abstract: A redox acceptor–acceptor nitro functionalized naphthalene diimide/rGO anode for sustainable lithium-ion batteries
Open Access Paper

Carbons derived from resole-type phenolic resins for use in lithium–sulfur batteries: templating the resins with sulfur leads to enhanced cell performance

Pyrolysed resole-type phenol-formaldehyde resins were used as carbonaceous sulfur-hosts in the cathodes of lithium–sulfur batteries.

Graphical abstract: Carbons derived from resole-type phenolic resins for use in lithium–sulfur batteries: templating the resins with sulfur leads to enhanced cell performance
Open Access Paper

Performance evaluation of lithium metal rechargeable batteries with a lithium excess cation-disordered rocksalt based positive electrode under high mass loading and lean electrolyte conditions

Operation of 500 W h kg−1 class rechargeable batteries was demonstrated. Non-destructive XCT analysis revealed volume expansion of the lithium metal electrode as the primary reason for the capacity fading.

Graphical abstract: Performance evaluation of lithium metal rechargeable batteries with a lithium excess cation-disordered rocksalt based positive electrode under high mass loading and lean electrolyte conditions
Open Access Paper

Carbon spheres with catalytic silver centres as selenium hosts for stable lithium–selenium batteries

A silver-centred carbon host for a Li–Se battery cathode is developed by a simple microwave-assisted approach. The successful immobilization of polyselenides by silver catalyst within the pores of the carbon spheres offers improved cycling stability.

Graphical abstract: Carbon spheres with catalytic silver centres as selenium hosts for stable lithium–selenium batteries
Open Access Paper

A rapid lithium-ion cathode discovery pipeline and its exemplary application

A new computational screening pipeline accelerates the process of identifying potential Li-ion cathodes, with a demonstration case upon its preliminary application.

Graphical abstract: A rapid lithium-ion cathode discovery pipeline and its exemplary application
Open Access Paper

SnO2/h-BN nanocomposite modified separator as a high-efficiency polysulfide trap in lithium–sulfur batteries

The illustration shows that the SnO2/10%-h-BN composite coated on the separator interlayer decreases the migration of soluble polysulfides compared to the SnO2/5%-h-BN and SnO2/25%-h-BN composite coated on the separator.

Graphical abstract: SnO2/h-BN nanocomposite modified separator as a high-efficiency polysulfide trap in lithium–sulfur batteries
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

A comparison of the impact of cation chemistry in ionic liquid-based lithium battery electrolytes

Two high-salt-content ionic liquid electrolytes with distinct cationic chemistries were compared. The one with a phosphonium cation showed superior characteristics, particularly in terms of its enhanced capacity when used in lithium metal batteries.

Graphical abstract: A comparison of the impact of cation chemistry in ionic liquid-based lithium battery electrolytes
Open Access Paper

Understanding the lithiation mechanism of Li2O-doped spinel high-entropy oxides as anode materials for Li-ion batteries

This work proposes an Li2O-doping strategy for improving the lithium storage ability of a high-entropy oxide, and its lithiation process is investigated in detail, which may promote the further development of high-entropy oxide anodes.

Graphical abstract: Understanding the lithiation mechanism of Li2O-doped spinel high-entropy oxides as anode materials for Li-ion batteries
From the themed collection: Energy Advances: Highlight China
Open Access Paper

Effect of a Ti layer on the growth of binder-free carbon nanotubes on Cu foil and their performance as lithium ion battery anodes

We report a unique approach to fabricate lithium ion battery anodes based on multiwalled carbon nanotubes (MWCNTs) grown directly on copper foils via chemical vapor deposition.

Graphical abstract: Effect of a Ti layer on the growth of binder-free carbon nanotubes on Cu foil and their performance as lithium ion battery anodes
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

Capacity-prediction models for organic anode-active materials of lithium-ion batteries: advances in predictors using small data

A capacity prediction model for organic anode active materials was constructed using sparse modeling for small data. The new model was validated in terms of the prediction accuracy, validity of the descriptors, and amount of the training data.

Graphical abstract: Capacity-prediction models for organic anode-active materials of lithium-ion batteries: advances in predictors using small data
Open Access Paper

An in situ LiF-enriched solid electrolyte interphase from CoF2-decorated N-doped carbon for dendrite-free Li metal anodes

We have prepared CoF2 decorated N-doped carbon via a convenient fluoridation treatment after the carbonation of ZIF-67 precursor, which was employed as a lithiophilic host for enabling homogeneous Li electrodeposition.

Graphical abstract: An in situ LiF-enriched solid electrolyte interphase from CoF2-decorated N-doped carbon for dendrite-free Li metal anodes
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

One-pot synthesis of LiAlO2-coated LiNi0.6Mn0.2Co0.2O2 cathode material

This work presents a scalable and efficient one-pot synthesis combining the co-precipitation of LiNi0.6Mn0.2Co0.2O2 (NMC622) and its surface modification by a LiAlO2 coating enhancing the active materials properties.

Graphical abstract: One-pot synthesis of LiAlO2-coated LiNi0.6Mn0.2Co0.2O2 cathode material
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

Fast rate lithium metal batteries with long lifespan enabled by graphene oxide confinement

Dendritic growth of lithium (Li) is hindering potential applications of Li-metal batteries, and new approaches are needed to address this challenge.

Graphical abstract: Fast rate lithium metal batteries with long lifespan enabled by graphene oxide confinement
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

Structure and interactions of novel ether-functionalised morpholinium and piperidinium ionic liquids with lithium salts

Investigation of the thermodynamic and transport properties of four novel ether-functionalised piperidinium and morpholinium ionic liquids with LiFSI and LiTFSI salts, and Li-ion coordination in ionic liquids.

Graphical abstract: Structure and interactions of novel ether-functionalised morpholinium and piperidinium ionic liquids with lithium salts
Open Access Paper

The role of anionic processes in Li1−xNi0.44Mn1.56O4 studied by resonant inelastic X-ray scattering

We investigated the first lithiation cycle of the positive electrode material Li1−xNi0.44Mn1.56O4 (LNMO) using soft X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS) at the transition metal L- and oxygen K-edges.

Graphical abstract: The role of anionic processes in Li1−xNi0.44Mn1.56O4 studied by resonant inelastic X-ray scattering
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

A Li-rich strategy towards advanced Mn-doped triphylite cathodes for Li-ion batteries

Introduction of additional Li ions into the LiFe0.5Mn0.5PO4 crystal structure results in an extended solid solution region of the Li+ de/intercalation process.

Graphical abstract: A Li-rich strategy towards advanced Mn-doped triphylite cathodes for Li-ion batteries
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

Enhancing low electronic conductivity materials in all active material electrodes through multicomponent architecture

Percolated electroactive material as electronically conductive network enables the high energy electroactive material with low intrinsic electronic conductivity at extremely high loading over 100 mg cm−2.

Graphical abstract: Enhancing low electronic conductivity materials in all active material electrodes through multicomponent architecture
From the themed collection: Energy Advances: Highlight USA & Canada
Open Access Paper

Experimental determination of metals generated during the thermal failure of lithium ion batteries

This work describes the deliberate failure of lithium-ion cells, and subsequent analysis of both the smoke and near field residue for the metals commonly found in battery cathodes.

Graphical abstract: Experimental determination of metals generated during the thermal failure of lithium ion batteries
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

Atomic-scale insight into the lattice volume plunge of LixCoO2 upon deep delithiation

The O ↔ O interlayer distance across Li layer and Co layer are responsible for the volume increase and decrease in LixCoO2, while the delithiation paths have an impact on the volume shrinkage points, corresponding to different capacity utilization.

Graphical abstract: Atomic-scale insight into the lattice volume plunge of LixCoO2 upon deep delithiation
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

Submerged comminution of lithium-ion batteries in water in inert atmosphere for safe recycling

Lithium-ion batteries are crushed in lime water in an inert N2 atmosphere to inactivate them. N2 flow reduces the risk of hydrogen explosion, and water absorbs the reaction heat.

Graphical abstract: Submerged comminution of lithium-ion batteries in water in inert atmosphere for safe recycling
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

A metal-free reduced graphene oxide coupled covalent imine network as an anode material for lithium-ion batteries

A crystalline and porous covalent imine network material, Tp-THzT-CIN, has been synthesized and when it is coupled with reduced graphene oxide, it yields a 2D/2D composite, which is an excellent anode material in lithium-ion batteries.

Graphical abstract: A metal-free reduced graphene oxide coupled covalent imine network as an anode material for lithium-ion batteries
From the themed collection: Lithium ion batteries – Topic Highlight
Open Access Paper

Dual modification of LiNi0.6Co0.2Mn0.2O2 with MgHPO4 as a high-performance cathode material for Li-ion batteries

The surface lithium-ion conductive Li3PO4 coating and bulk Mg2+ gradient doping were detected for the modified NCM622 cathode materials. The interfacial instability and bulk structure degradation were suppressed by the simple dual modification.

Graphical abstract: Dual modification of LiNi0.6Co0.2Mn0.2O2 with MgHPO4 as a high-performance cathode material for Li-ion batteries
From the themed collection: Lithium ion batteries – Topic Highlight
30 items

About this collection

Energy Advances  features cutting-edge science at the forefront of energy technology with a particular focus on emerging materials and methods. This collection highlights some of our recent publications on lithium-ion batteries.

Our multidisciplinary journal seeks further contributions in this area, including those reporting new and improved electrode materials and electrolyte formulations, understanding electrode – electrolyte interface phenomena, and battery recycling and sustainability. 

To contribute your research, please visit our submission platform.

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