Insights into acid dissociation of HCl and HBr with internal electric fields
A critical electric field exerted by the solvent on the ionizable group leads to acid dissociation.
Dioxygen bound cobalt corroles
Two cobalt–dioxygen adducts, [CoH8]–O2 and [CoCl8]–O2, chelated by electron-rich and electron-poor corroles, respectively, were isolated in solution and characterized by resonance Raman.
Organogel-assisted topochemical synthesis of multivalent glyco-polymer for high-affinity lectin binding
Gel-assisted topochemical synthesis of a PDA-based galactocluster having 1000-fold binding affinity, compared to monomers, for various galactose binding lectins is reported.
Proton conduction through oxygen functionalized few-layer graphene
The first demonstration of solid state proton conduction (8.7 × 10−3 S cm−1 at 80 °C, 95% relative humidity) of oxygen functionalized few-layer graphene.
The origin of low thermal conductivity in Sn1−xSbxTe: phonon scattering via layered intergrowth nanostructures
The spontaneous formation of nanodomains of the Sb-rich layered intergrowth SnmSb2nTe3n+m compounds in a SnTe matrix resulted in ultralow lattice thermal conductivity.
Cu2+ selective chelators relieve copper-induced oxidative stress in vivo
We report highly selective, novel Cu2+ chelators that relieve copper induced oxidative stress in vivo indicating applicability toward assuaging copper-overload disorders.
Conductance in a bis-terpyridine based single molecular breadboard circuit
We study conductance in a molecular breadboard junction accommodating up to 61 circuits and demonstrate switching between 4 conductance states.
Solvation and hydrogen bonding aided efficient non-radiative deactivation of polar excited state of 5-aminoquinoline
The mechanism of efficient fluorescence quenching of 5-aminoquinoline in alcoholic solvents.
Hydrogen bond induced enhancement of Fermi resonances in N–H⋯N hydrogen bonded complexes of anilines
Enhancement of Fermi resonance intensities due to the formation of N–H⋯N hydrogen bonding of anilines with alkyl amines is analyzed using a two-state deperturbation model.
Selective synthesis of mono- and di-methylated amines using methanol and sodium azide as C1 and N1 sources
The selective synthesis of various N,N-dimethylated and N-monomethylated amines from organic azides using methanol as a methylating agent is reported.
The role of electronegativity on the extent of nitridation of group 5 metals as revealed by reactions of tantalum cluster cations with ammonia molecules
The electronegativity of the metal (V > Ta) plays a key role in determining the composition of the metal nitrides.
Optically sensing phospholipid induced coil–helix transitions in the phosphoinositide-binding motif of gelsolin
A FRET-based probe reveals that coil–helix transitions in the phospholipid binding sequence of gelsolin occur at physiological phosphatidylinositol-4,5-bisphosphate concentrations.
Optical backbone-sidechain charge transfer transitions in proteins sensitive to secondary structure and modifications
We report the UV-vis absorption originating from protein backbone-sidechain charge transfer transitions in charged amino acids with anionic and cationic sidechains.
Controlling anticancer drug mediated G-quadruplex formation and stabilization by a molecular container
G-quadruplex DNA (GQ-DNA) formation has been controlled using a molecular container, cucurbituril (CB7), by means of translocating a potential anticancer drug, topotecan, from GQ-DNA to the CB7 nanocavity. Interestingly, this whole cycle can be easily monitored through the change in the emission color of the stabilizing ligand, i.e., topotecan.
Enhanced fluorescence with nanosecond dynamics in the solid state of metal ion complexes of alkoxy salophens
Incorporation of an alkoxy moiety dramatically alters the photophysics and molecular packing of aluminum complexes of salophen leading to enhanced emission in the solid state.
Conformational and hydration properties modulate ice recognition by type I antifreeze protein and its mutants
Mutation of wfAFP changes the intrinsic dynamics in such a way that it significantly influences water mediated AFP adsorption on ice.
Packing energetics determine the folding routes of the RNase-H proteins
The RNase-H proteins show a diverse range of folding routes with structurally distinct folding nuclei.
Can an ammonium-based room temperature ionic liquid counteract the urea-induced denaturation of a small peptide?
The folding/unfolding equilibrium of proteins in aqueous medium can be altered by adding small organic molecules generally termed as co-solvents.
Bifunctional Ru(II) complex catalysed carbon–carbon bond formation: an eco-friendly hydrogen borrowing strategy
Bifunctional Ru(II) complex (0.1 mol%) catalysed one-pot β-alkylation of secondary alcohols with primary alcohols and double alkylation of cyclopentanol were carried out successfully following the atom economical borrowing hydrogen methodology.
Tracer diffusion in a sea of polymers with binding zones: mobile vs. frozen traps
We simulate tracer dynamics in a sea of polymers with binding zones and address the issue of non-Gaussianity.
Exploration of the presence of bulk-like water in AOT reverse micelles and water-in-oil nanodroplets: the role of charged interfaces, confinement size and properties of water
We show that the distance from the interface at which bulk-like properties are recovered strongly depends on the choice of order parameter being probed: translational < tetrahedral ≪ dipolar orientation.
Localized delivery and enhanced osteogenic differentiation with biodegradable galactitol polyester elastomers
Cytocompatible galactitol based polyesters showed variations in physical properties, degradation, dye release and ability to direct cells towards bone lineage.
PIDA–I2 mediated direct vicinal difunctionalization of olefins: iodoazidation, iodoetherification and iodoacyloxylation
I+ (IOAc) was produced from the combination of phenyliodine diacetate (PIDA) and iodine.
Photoinduced charge generation rates in soluble P3HT : PCBM nano-aggregates predict the solvent-dependent film morphology
Spectroscopic evidence for the intermediate polymer : fullerene : solvent ternary phase which seeds the eventual film nano-morphology is determined by evaluation of the photoinduced polaron generation rates in solution.
Ultrathin few layer oxychalcogenide BiCuSeO nanosheets
Large scale ultrathin (∼3–4 nm thick and ∼1 μm long) few layered (4–5 layers) BiCuSeO nanosheets were synthesised by a facile soft chemical synthesis. BiCuSeO nanosheets exhibit lower lattice thermal conductivity and higher electrical conductivity than that of their bulk counterpart.
About this collection
This issue aims to highlight the top research from emerging investigators in India. All the authors are in the early stages of their independent careers and have contributed to topics including organic synthesis, physical organic chemistry, supramolecular chemistry, chemical biology, materials and many more. Find out more about the different authors here.
New articles will be added to this collection as they are published.