RSC Advances
Heterogeneous articles published in the last
6 months
Ni-based catalysts supported on Hbeta zeolite for the hydrocracking of waste polyolefins
High efficiency hydrocracking degradation of mixed polyolefin polymers is achieved under mild circumstances by Ni-based catalysts supported on Hbeta.
RSC Adv., 2024,14, 15856-15861
https://doi.org/10.1039/D4RA02809K
Catalytic performance of modified carbon black on methane decomposition for hydrogen production
Heat treatment changes the carbon structure, increasing the degree of graphitization and defects. Methane molecules gradually decompose at the graphitized edges of the carbon material (BAY clusters) to form ordered carbon and hydrogen.
RSC Adv., 2024,14, 15656-15663
https://doi.org/10.1039/D4RA01486C
Characteristics of Fe/C catalysts based on pyrolysis of ferric citrate and its peroxymonosulfate activation performance to degrade sulfadiazine in water
Advanced oxidation techniques based on peroxysulfate activation have been paid much attention owing to their excellent performance in degrading stubborn pollutants in water.
RSC Adv., 2024,14, 15582-15590
https://doi.org/10.1039/D4RA00768A
Synthesis and characterization of a green and recyclable arginine-based palladium/CoFe2O4 nanomagnetic catalyst for efficient cyanation of aryl halides
The utilization of magnetic nanoparticles in the fields of science and technology has gained considerable popularity.
RSC Adv., 2024,14, 14139-14151
https://doi.org/10.1039/D4RA01200C
A lost piece of the puzzle of the alkane cracking mechanism: a carbanion pathway on a solid base catalyst
The cracking of propane molecules via a thermal cracking process, a base-catalyzed process, and a strong-base-catalyzed process was studied by means of catalyst characterization and evaluation of catalyst performance.
RSC Adv., 2024,14, 15071-15084
https://doi.org/10.1039/D4RA00878B
Synergistic effect between In2O3 and ZrO2 in the reverse water gas shift reaction
The 75In2O3–25ZrO2 forms a solid solution structure, and can achieve 28% CO2 conversion and 96% CO selectivity during a 200 h-test.
RSC Adv., 2024,14, 14868-14874
https://doi.org/10.1039/D4RA01372G
Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran with high yield over bimetallic Ru–Co/AC catalysts
Catalytic hydrogenolysis of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) has become a hot topic in the bioenergy field in recent years.
RSC Adv., 2024,14, 14982-14991
https://doi.org/10.1039/D4RA02054E
An in situ phase transformation induced mesoporous heterointerface for the alkaline hydrogen evolution reaction
In situ phase transformation is achieved from single-phase Co3O4 to CoO/CoP hybrid phases, which acts as a highly efficient electrocatalyst for the hydrogen evolution reaction.
RSC Adv., 2024,14, 14886-14893
https://doi.org/10.1039/D4RA02063D
Tailoring MIL-100(Fe)-derived catalyst for controlled carbon dioxide conversion and product selectivity
The impact of the active catalyst particle size on the CO2 hydrogenation and product selectivity is presented using MOF-derived Fe-based catalytic system.
RSC Adv., 2024,14, 13946-13956
https://doi.org/10.1039/D4RA01772B
An efficient catalysis for the synthesis of pyrimido[1,2-a]benzimidazoles and 1-(benzothiazolylamino)methyl-2-naphthols using ZnO@SO3H@Tropine
An efficient, green method for one-pot three-component synthesis of pyrimido[1,2-a]benzimidazole and 1-(benzothiazolylamino)methyl-2-naphthol derivatives using a new nanoporous catalyst ZnO@SO3H@Tropine is reported. Advantages include, but are not limited to, simple work-up and high yields.
RSC Adv., 2024,14, 13452-13462
https://doi.org/10.1039/D3RA08960F
Retraction: High-performance sono/nano-catalytic system: CTSN/Fe3O4–Cu nanocomposite, a promising heterogeneous catalyst for the synthesis of N-arylimidazoles
RSC Adv., 2024,14, 12977-12977
https://doi.org/10.1039/D4RA90044H
Regulating oxygen vacancies by Zn atom doping to anchor and disperse promoter Ba on MgO support to improve Ru-based catalysts activity for ammonia synthesis
Zn doping promotes the formation of oxygen vacancy, which anchors and disperses Ba.
RSC Adv., 2024,14, 13157-13167
https://doi.org/10.1039/D4RA01517G
The influence of hydrogen bonding on the structure of organic–inorganic hybrid catalysts and its application in the solvent-free epoxidation of α-olefins
Different reaction routes with the influence of hydrogen bonding and without hydrogen bonding.
RSC Adv., 2024,14, 12853-12863
https://doi.org/10.1039/D4RA01399A
Effect of defect-healing treatment on layered silicate precursors toward well-defined crosslinked frameworks
A defect-healed layered precursor of FER-type zeolite exhibited enhanced iron atom insertion in more homogeneous environments.
RSC Adv., 2024,14, 12634-12638
https://doi.org/10.1039/D4RA01626B
Significantly enhanced catalytic performance of Pd nanocatalyst on AlOOH featuring abundant solid surface frustrated Lewis pair for improved hydrogen activation
The superior catalytic performance of Pd nanocatalysts in AlOOH-80 is attributed to solid surface frustrated Lewis pairs (ssFLP), which enhance hydrogen gas dissociation, improve Pd nanocatalyst hydrogenation, and result in high catalytic activity of Pd/AlOOH-80.
RSC Adv., 2024,14, 12593-12599
https://doi.org/10.1039/D4RA01852D
Optimizing methanol synthesis from CO2 using graphene-based heterogeneous photocatalyst under RSM and ANN-driven parametric optimization for achieving better suitability
Assessment of the performance of linear and nonlinear regression-based methods for estimating in situ catalytic CO2 transformations employing TiO2/Cu coupled with hydrogen exfoliation graphene (HEG) has been investigated.
RSC Adv., 2024,14, 12496-12512
https://doi.org/10.1039/D4RA00578C
Synergistic effects of the bimetallic Ni–Fe systems and their application in the reductive amination of polyether polyols
We report the synthesis of xNi–yFe/γ-Al2O3 catalysts which were applied to the reductive amination of polypropylene glycol (PPG) for the preparation of polyether amine (PEA).
RSC Adv., 2024,14, 11885-11890
https://doi.org/10.1039/D4RA00944D
Investigation into the impact of CeO2 morphology regulation on the oxidation process of dichloromethane
Four distinct CeO2 catalysts featuring varied morphologies (nanorods, nanocubes, nanoparticles, and nano spindle-shaped) were synthesized through a hydrothermal process and subsequently employed in the oxidation of dichloromethane (DCM).
RSC Adv., 2024,14, 12265-12277
https://doi.org/10.1039/D4RA01326C
Influences of Ru and ZrO2 interaction on the hydroesterification of styrene
Interfacial Lewis acid–base pairs are commonly found in ZrO2-supported metal catalysts due to the facile generation of oxygen vacancies of ZrO2.
RSC Adv., 2024,14, 11914-11920
https://doi.org/10.1039/D4RA00054D
Alkaline earth modified activated carbon supported Cu catalysts with enhanced selectivity in the hydrogenation of dimethyl oxalate to methyl glycolate
In this work, the effect of alkaline earth metal modification on the catalytic performance of activated carbon supported Cu was investigated.
RSC Adv., 2024,14, 11849-11861
https://doi.org/10.1039/D4RA01049C
Sulfur-doped activated carbon for the efficient degradation of tetracycline with persulfate: Insight into the effect of pore structure on catalytic performance
Sulfur-doped activated carbon has proved to be a promising metal-free catalyst for persulfate (PDS) catalytic activation for the oxidation of aqueous refractory organics.
RSC Adv., 2024,14, 11470-11481
https://doi.org/10.1039/D3RA08958D
Fe3O4@SiO2 core/shell functionalized by gallic acid: a novel, robust, and water-compatible heterogeneous magnetic nanocatalyst for environmentally friendly synthesis of acridine-1,8-diones
An efficient route for the construction of acridine-1,8-diones using Fe3O4@SiO2 core/shell functionalized by sulfonated gallic acid as a robust heterogeneous catalyst.
RSC Adv., 2024,14, 10842-10857
https://doi.org/10.1039/D4RA00629A
Multicomponent synthesis via acceptorless alcohol dehydrogenation: an easy access to tri-substituted pyridines
The multicomponent synthesis of 2,4,6-trisubstituted pyridine via acceptorless alcohol dehydrogenation using ammonium acetate as a nitrogen source catalyzed by hydroxyapatite-supported palladium nanoparticles as a heterogeneous catalyst.
RSC Adv., 2024,14, 10761-10767
https://doi.org/10.1039/D4RA00439F
Hydrogenation of cyclohexene over single-atom Pt or Pd incorporated porous ceria nanoparticles under solvent-free conditions
Single-atom Pt or Pd incorporated porous CeO2 nanoparticles was prepared through one-step flash-combustion technique. The prepared catalysts exhibited high activity in the hydrogenation of cyclohexene under solvent-free conditions.
RSC Adv., 2024,14, 10644-10652
https://doi.org/10.1039/D4RA01432D
Synthesis of some derivatives of 1,8-dioxo-octa-hydro xanthene and 9-aryl-hexahydro acridine-1,8-dione using metal ion-exchanged NaY zeolite as heterogeneous catalyst
This is a process for producing xanthene and acridine derivatives. It uses copper metal catalysts supported by de-alumination zeolite-NaY. The process is conducted in a single pot and solvent-free conditions and does not require toxic reagents.
RSC Adv., 2024,14, 10322-10330
https://doi.org/10.1039/D3RA03020B
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