RSC Advances  

Subject area
Solid state articles published in the last 6 months

18 items
Open Access Review Article

A review on MOFs synthesis and effect of their structural characteristics for hydrogen adsorption

Climate change is causing a rise in the need to transition from fossil fuels to renewable and clean energy such as hydrogen as a sustainable energy source.

Graphical abstract: A review on MOFs synthesis and effect of their structural characteristics for hydrogen adsorption
From the themed collection: 2024 Reviews in RSC Advances
Open Access Paper

The crucial role of hydrogen bonding in shaping the structures of zinc-based coordination polymers using tridentate N, N, O donor reduced Schiff base ligands and bridging acetates

In this article synthesis, characterization and DFT study of two polynuclear zinc(II) complexes with reduced Schiff base have been reported.

Graphical abstract: The crucial role of hydrogen bonding in shaping the structures of zinc-based coordination polymers using tridentate N, N, O donor reduced Schiff base ligands and bridging acetates
Open Access Paper

The effect of the gelation temperature on the structural, magnetic and magnetocaloric properties of perovskite nanoparticles manufactured using the sol–gel method

This study underscores the significant impact of gelation temperature variation in the sol–gel synthesis process on the physical properties of La0.8Sr0.2Mn0.8Co0.2O3 compounds.

Graphical abstract: The effect of the gelation temperature on the structural, magnetic and magnetocaloric properties of perovskite nanoparticles manufactured using the sol–gel method
Open Access Paper

In situ growth of Bi-MOF on cotton fabrics via ultrasonic synthesis strategy for recyclable photocatalytic textiles

CAU-17 was in situ grown on carboxymethylated cotton fabric by ultrasonication and exhibited favorable photocatalytic degradation ability.

Graphical abstract: In situ growth of Bi-MOF on cotton fabrics via ultrasonic synthesis strategy for recyclable photocatalytic textiles
Open Access Review Article

Design and application of metal organic frameworks for heavy metals adsorption in water: a review

The growing apprehension surrounding heavy metal pollution in both environmental and industrial contexts has spurred extensive research into adsorption materials aimed at efficient remediation.

Graphical abstract: Design and application of metal organic frameworks for heavy metals adsorption in water: a review
From the themed collection: 2024 Reviews in RSC Advances
Open Access Paper

Antibacterial, antibiofilm, and antioxidant activities of two novel metal–organic frameworks (MOFs) based on 4,6-diamino-2-pyrimidinethiol with Zn and Co metal ions as coordination polymers

Two novel metal–organic frameworks (MOFs), synthesized from 4,6-diamino-2-pyrimidinethiol with Zn and Co metal ions, display antibacterial, antibiofilm, and antioxidant properties, serving multifunctionality in biological and environmental domains.

Graphical abstract: Antibacterial, antibiofilm, and antioxidant activities of two novel metal–organic frameworks (MOFs) based on 4,6-diamino-2-pyrimidinethiol with Zn and Co metal ions as coordination polymers
Open Access Paper

Machine learning guided tuning charge distribution by composition in MOFs for oxygen evolution reaction

We utilize machine learning (ML) to accelerate the synthesis of MOFs, starting by building a library of over 900 MOFs with different metal salts, solvent ratios and reaction tine, and then utilizing zeta potentials as target variables for ML training.

Graphical abstract: Machine learning guided tuning charge distribution by composition in MOFs for oxygen evolution reaction
Open Access Paper

Crystal structure, Hirshfeld surface analysis, conduction mechanism and electrical modulus study of the new organic–inorganic compound [C8H10NO]2HgBr4

There has been a lot of interest in the development of a novel hybrid material based on mercury that has fascinating structural properties.

Graphical abstract: Crystal structure, Hirshfeld surface analysis, conduction mechanism and electrical modulus study of the new organic–inorganic compound [C8H10NO]2HgBr4
Open Access Correction

Correction: Advances in metal–organic frameworks for water remediation applications

Open Access Paper

Coordination-induced and tunable layered rare-earth hydroxide-complex intercalated nanohybrid phosphorescent photosensitizer and therapy

Hydrotalcite intercalated nanohybrids have served as a vital phosphorescent photosensitizer owing to remarkable 1O2 quantum yield and high cell mortality performance.

Graphical abstract: Coordination-induced and tunable layered rare-earth hydroxide-complex intercalated nanohybrid phosphorescent photosensitizer and therapy
Open Access Paper

Two new rare-earth oxyborates Ba4BiTbO(BO3)4 and Ba1.54Sr2.46BiTbO(BO3)4 and luminescence properties of the Ba4BiTb1−xEuxO(BO3)4 phosphors

Two new oxyborates Ba4BiTbO(BO3)4 and Ba1.54Sr2.46BiTbO(BO3)4 were synthesized and structurally characterized and luminescence properties of Ba4BiTb1−xEuxO(BO3)4 (0 ≤ x ≤ 0.2) were investigated.

Graphical abstract: Two new rare-earth oxyborates Ba4BiTbO(BO3)4 and Ba1.54Sr2.46BiTbO(BO3)4 and luminescence properties of the Ba4BiTb1−xEuxO(BO3)4 phosphors
Open Access Paper

The antibacterial activity of three zeolitic-imidazolate frameworks and zinc oxide nanoparticles derived from them

ZIF-4, ZIF-7 and ZIF-8 were synthesized and their antibacterial activity was evaluated. ZIF-8 showed the highest antibacterial property among the three types of MOFs and zinc oxide materials derived from them.

Graphical abstract: The antibacterial activity of three zeolitic-imidazolate frameworks and zinc oxide nanoparticles derived from them
Open Access Paper

Utilizing EPR spectroscopy to investigate the liquid adsorption properties of bimetallic MIL-53(Al/Cr) MOF

The flexibility of the MIL-53(M) metal–organic framework (MOF) has been elucidated through EPR spectroscopy, in liquid adsorption processes.

Graphical abstract: Utilizing EPR spectroscopy to investigate the liquid adsorption properties of bimetallic MIL-53(Al/Cr) MOF
Open Access Paper

Crystal structure, optical characterization, conduction and relaxation mechanisms of a new hybrid compound (C6H9N2)2[Sb2Cl8]

Hybrid materials play a crucial role in the construction of flexible electronic devices due to the advantages of both organic and inorganic components.

Graphical abstract: Crystal structure, optical characterization, conduction and relaxation mechanisms of a new hybrid compound (C6H9N2)2[Sb2Cl8]
Open Access Review Article

Advances in metal–organic frameworks for water remediation applications

Metal–organic frameworks have advanced adsorption, photocatalysis and sensing of water contaminants.

Graphical abstract: Advances in metal–organic frameworks for water remediation applications
From the themed collection: 2024 Reviews in RSC Advances
Open Access Paper

Pyridine 3,5-dicarboxylate-based metal–organic frameworks as an active electrode material for battery-supercapacitor hybrid energy storage devices

Battery–supercapacitor hybrid: merging of battery and supercapacitor electrodes for hybrid energy storage devices.

Graphical abstract: Pyridine 3,5-dicarboxylate-based metal–organic frameworks as an active electrode material for battery-supercapacitor hybrid energy storage devices
Open Access Paper

Hydrothermal synthesis of dittmarite-group NH4(Co1−xMnx)PO4·H2O particles as inorganic violet pigments

Dittmarite-group NH4(Co1−xMnx)PO4·H2O particles were prepared via a hydrothermal route. The violet colour of the particles was maintained upon substitution of Co2+ with Mn2+ ions up to x = 0.8, thus achieving an 80% saving of cobalt.

Graphical abstract: Hydrothermal synthesis of dittmarite-group NH4(Co1−xMnx)PO4·H2O particles as inorganic violet pigments
Open Access Paper

Facile construction of an anthracene-decorated highly luminescent coordination polymer for the selective detection of explosive nitroaromatics and the mutagenic pollutant TNP

This work highlights the fabrication of a luminescent 1D coordination polymer based on an anthracene-derived ligand, which has significant impact on the detection of explosive nitroaromatics and mutagenic pollutant TNP.

Graphical abstract: Facile construction of an anthracene-decorated highly luminescent coordination polymer for the selective detection of explosive nitroaromatics and the mutagenic pollutant TNP
18 items

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