RSC Advances  

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Crystallography articles published in the last 6 months

162 items - Showing page 1 of 7
Open Access Paper

Microstructure and physical properties of black-aluminum antireflective films

The microstructure and physical properties of reflective and black aluminum were compared for layers of different thicknesses deposited by magnetron sputtering on fused silica substrates.

Graphical abstract: Microstructure and physical properties of black-aluminum antireflective films
Open Access Paper

Humidity-tolerant and highly sensitive gas sensor for hydrogen sulfide based on WO3 nanocubes modified with CeO2

CeO2 nanoparticles modified WO3 nanocube materials were prepared. CeO2 nanoparticles endowed the WO3 with good hydrophobic properties and dissociative oxygen adsorption. The response and moisture resistance were synchronized.

Graphical abstract: Humidity-tolerant and highly sensitive gas sensor for hydrogen sulfide based on WO3 nanocubes modified with CeO2
Open Access Paper

Synthesis, characterization, crystal structure, and fabrication of photosensitive Schottky device of a binuclear Cu(II)-Salen complex: a DFT investigations

This work explores one centrosymmetric binuclear Cu(II)-Salen complex synthesis, characterization, photosensitive Schottky barrier diode (PSBD) function, and DFT spectrum.

Graphical abstract: Synthesis, characterization, crystal structure, and fabrication of photosensitive Schottky device of a binuclear Cu(ii)-Salen complex: a DFT investigations
Open Access Paper

Sodium halide solid state electrolyte of Na3YBr6 with low activation energy

Vibration of Br during the Na+ ion migration can significantly reduce ion migration activation energy. Therefore, compared to chlorides, bromide should be able to achieve lower migration activation energy and higher Na+ ion conduction.

Graphical abstract: Sodium halide solid state electrolyte of Na3YBr6 with low activation energy
Open Access Paper

Synthesis of cobalt phosphide hybrid for simultaneous electrochemical detection of ascorbic acid, dopamine, and uric acid

A Co2P hybrid, containing Co2P nanoparticles anchored on a P, N-doped porous carbon matrix, was synthesized and modified on a screen-printed electrode (SPE) as Co2P hybrid-SPE for the simultaneous detection of ascorbic acid, dopamine and uric acid.

Graphical abstract: Synthesis of cobalt phosphide hybrid for simultaneous electrochemical detection of ascorbic acid, dopamine, and uric acid
Open Access Paper

Photocatalytic degradation of methyl blue dye with H2O2 sensing

ZnO nanoparticles impregnated polymer for the degradation of methyl blue dye with H2O2 sensing colorimetrically and fluorometrically.

Graphical abstract: Photocatalytic degradation of methyl blue dye with H2O2 sensing
Open Access Paper

Effective separation of dyes/salts by sulfonated covalent organic framework membranes based on phenolamine network conditioning

This study developed a modified polyacrylonitrile (PAN) membrane controlled by a phenol–amine network and enhanced with a sulfonated covalent organic framework (SCOF), aimed at improving the efficiency of textile wastewater treatment.

Graphical abstract: Effective separation of dyes/salts by sulfonated covalent organic framework membranes based on phenolamine network conditioning
Open Access Paper

Electrochemical sensing performance of two CuO nanomaterial-modified dual-working electrodes

Systematic comparison of electrochemical sensing performance between CuO nanospheres and CuO nanochains with similar diameter using a dual-working electrode system.

Graphical abstract: Electrochemical sensing performance of two CuO nanomaterial-modified dual-working electrodes
Open Access Paper

Aluminium phosphide (Al12P12) nanocage as a potential sensor for volatile organic compounds: A DFT study

The potentiality of the aluminium phosphide (Al12P12) nanocage as a prospective sensor material towards methanol (MeOH) and ethanol (EtOH) molecules was investigated using density functional theory computations.

Graphical abstract: Aluminium phosphide (Al12P12) nanocage as a potential sensor for volatile organic compounds: A DFT study
Open Access Paper

Flexible tactile sensors with interlocking serrated structures based on stretchable multiwalled carbon nanotube/silver nanowire/silicone rubber composites

A patterned, stretchable, and fully elastomeric multiwalled carbon nanotube (MWCNT)/silver nanowire (Ag NW)/silicone rubber (SR) composite have been developed.

Graphical abstract: Flexible tactile sensors with interlocking serrated structures based on stretchable multiwalled carbon nanotube/silver nanowire/silicone rubber composites
Open Access Paper

The crucial role of hydrogen bonding in shaping the structures of zinc-based coordination polymers using tridentate N, N, O donor reduced Schiff base ligands and bridging acetates

In this article synthesis, characterization and DFT study of two polynuclear zinc(II) complexes with reduced Schiff base have been reported.

Graphical abstract: The crucial role of hydrogen bonding in shaping the structures of zinc-based coordination polymers using tridentate N, N, O donor reduced Schiff base ligands and bridging acetates
Open Access Paper

Detection of intracellular microRNA-21 for cancer diagnosis by a nanosystem containing a ZnO@polydopamine and DNAzyme probe

The novel nanosystem composed of ZnO@polydopamine nanomaterial and deoxyribozyme probe can be applied for ratiometric fluorescence assay for microRNA-21, which is helpful for cancer diagnosis and prognosis.

Graphical abstract: Detection of intracellular microRNA-21 for cancer diagnosis by a nanosystem containing a ZnO@polydopamine and DNAzyme probe
Open Access Paper

Colorimetric detection of Hg2+ based on the enhanced oxidase-mimic activity of CuO/Au@Cu3(BTC)2 triggered by Hg2+

A colorimetric method was designed for Hg2+ detection based on the enhanced oxidase-mimic activity of CuO/Au@Cu3(BTC)2.

Graphical abstract: Colorimetric detection of Hg2+ based on the enhanced oxidase-mimic activity of CuO/Au@Cu3(BTC)2 triggered by Hg2+
Open Access Paper

Selection, characterization, and biosensing applications of DNA aptamers targeting cyanotoxin BMAA

Scientists have established a connection between environmental exposure to toxins like β-N-methylamino-L-alanine (BMAA) and a heightened risk of neurodegenerative disorders.

Graphical abstract: Selection, characterization, and biosensing applications of DNA aptamers targeting cyanotoxin BMAA
Open Access Paper

Ultra-high Q-factor and amplitude-tunable Fano resonance in vanadium dioxide–silicon hybrid metamaterials

We present a VO2-silicon metamaterial with Q factor up to 165 198 that can be used for terahertz sensing. By adjusting the conductivity of VO2, an optical switching function with a modulation depth of 98.9% can be realized.

Graphical abstract: Ultra-high Q-factor and amplitude-tunable Fano resonance in vanadium dioxide–silicon hybrid metamaterials
Open Access Paper

Improved isoprene detection performance of Si-doped WO3 films deposited by sputtering and post-annealing

Sputtered films of Si-doped WO3 showed a good selective sensing for isoprene with rapid response/recovery times, which were less than 1.5 and 3.0 seconds, respectively.

Graphical abstract: Improved isoprene detection performance of Si-doped WO3 films deposited by sputtering and post-annealing
Open Access Paper

Determination of moxifloxacin in milk using a ratiometric fluorescent sensor based on Ag-MOF@curcumin

Moxifloxacin (MFX) has attracted increasing public concern recently, and the development of a simple and effective analysis method has become a research focus.

Graphical abstract: Determination of moxifloxacin in milk using a ratiometric fluorescent sensor based on Ag-MOF@curcumin
Open Access Paper

Rapid and quantitative detection of DNA hybridization using a simplified Fabry–Perot interferometric biosensor

The simple-structured Fabry–Perot interferometric biosensor is capable of rapid and quantitative detection of DNA hybridization.

Graphical abstract: Rapid and quantitative detection of DNA hybridization using a simplified Fabry–Perot interferometric biosensor
Open Access Paper

Syntheses, structural, photophysical and theoretical studies of heteroleptic cycloplatinated guanidinate(1−) complexes bearing acetylacetonate and picolinate ancillary ligands

[Pt(TAG-κCN)(acac)] (TAG = triarylguanidinate(1−) ligands) were isolated and fully characterized. These complexes are bluish green light emitters and the origin of absorption/emission in selected complexes were studied by TD-DFT calculations.

Graphical abstract: Syntheses, structural, photophysical and theoretical studies of heteroleptic cycloplatinated guanidinate(1−) complexes bearing acetylacetonate and picolinate ancillary ligands
Open Access Paper

Formation of H-bonding networks in the solid state structure of a trinuclear cobalt(III/II/III) complex with N2O2 donor Schiff base ligand and glutaric acid as bridging co-ligand: synthesis, structure and DFT study

Formation of hydrogen bonding network in a trinuclear linear mixed-valence centrosymmetric cobalt(III)–cobalt(II)–cobalt(III) complex has been analyzed using DFT calculations.

Graphical abstract: Formation of H-bonding networks in the solid state structure of a trinuclear cobalt(iii/ii/iii) complex with N2O2 donor Schiff base ligand and glutaric acid as bridging co-ligand: synthesis, structure and DFT study
Open Access Paper

Grind, shine and detect: mechanochemical synthesis of AIE-active polyaromatic amide and its application as molecular receptor of monovalent anions or nucleotides

The mechanochemical synthesis of AIE-active amide, as well as the application of the title compound as molecular receptor of monovalent anions and nucleotides, are described.

Graphical abstract: Grind, shine and detect: mechanochemical synthesis of AIE-active polyaromatic amide and its application as molecular receptor of monovalent anions or nucleotides
Open Access Paper

Rational design of a lysosome-targeted fluorescent probe for monitoring the generation of hydroxyl radicals in ferroptosis pathways

A novel hydrocyanine-based turn-on fluorescence probe HCy-Lyso, with excellent lysosome-targeting ability and ˙OH-responsive efficiency, has been applied for monitoring the variation in lysosomal ˙OH levels during ferroptosis.

Graphical abstract: Rational design of a lysosome-targeted fluorescent probe for monitoring the generation of hydroxyl radicals in ferroptosis pathways
Open Access Paper

Carbon dots–cadmium sulfide quantum dots nanocomposite for ‘on–off’ fluorescence sensing of chromium(VI) ions

This work involves fluorescent probe which is composed of carbon dots (CD) and cadmium sulfide quantum dots (CdS QD) for the sensitive and selective fluorescence detection of chromium(VI) ions.

Graphical abstract: Carbon dots–cadmium sulfide quantum dots nanocomposite for ‘on–off’ fluorescence sensing of chromium(vi) ions
Open Access Paper

Synthesis and characterization of a nanostructure conductive copolymer based on polyaniline and polylactic acid as an effective substrate in proteins impedimetric biosensing

Despite of all the developments in DNA microarray technology, there is not sufficient knowledge about protein abundance or their function in processes such as proteolysis, phosphorylation.

Graphical abstract: Synthesis and characterization of a nanostructure conductive copolymer based on polyaniline and polylactic acid as an effective substrate in proteins impedimetric biosensing
Open Access Paper

Enhanced acetone gas-sensing characteristics of Pd–NiO nanorods/SnO2 nanowires sensors

The ternary component consisting of SnO2 nanowires/Pd–NiO nanorods is employed to enhance the acetone gas sensor performance utilizing the synergistic effects of the p–n heterojunction between the p-type NiO and the n-type SnO2, as well as the catalytic spillover effect of Pd nanoparticles.

Graphical abstract: Enhanced acetone gas-sensing characteristics of Pd–NiO nanorods/SnO2 nanowires sensors
162 items - Showing page 1 of 7

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