Themed collection 2025 Green Chemistry Hot Articles

Highly efficient synthesis of tert-butyl esters using (Boc)2O under solvent/base-free electromagnetic milling conditions: a new reaction model
A novel and efficient method has been developed for the synthesis of tert-butyl esters using (Boc)2O as the tert-butyl source, facilitated by electromagnetic milling.
Green Chem., 2025,27, 1348-1355
https://doi.org/10.1039/D4GC05617E

Bio-oil derived polyesteramides as water-degradable replacements for polyethylene
Polyesteramides derived from Ethiopian mustard seed bio-oil possess commercially relevant thermomechanical properties and are chemically recyclable and water-degradable.
Green Chem., 2025,27, 4152-4164
https://doi.org/10.1039/D4GC05490C

Recovery and reuse of homogeneous palladium catalysts via organic solvent nanofiltration: application in the synthesis of AZD4625
Using OSN, a homogeneous Pd catalyst in AZD4625 synthesis is separated and reused for five cycles, maintaining over 90% conversion.
Green Chem., 2025,27, 3186-3196
https://doi.org/10.1039/D4GC06334A

Toward industrial C8 production: oxygen intrusion drives renewable n-caprylate production from ethanol and acetate via intermediate metabolite production
A simplified open culture chain elongation process with ethanol and acetate to produce renewable n-caprylate without adding yeast extract showed a trophic hierarchy between aerobic, facultative anaerobic, and fully anaerobic microbial species.
Green Chem., 2025,27, 2931-2949
https://doi.org/10.1039/D5GC00411J
Tensile-strain-driven interstitial Ru doping structure on an FeCoP/FF electrode accelerates the reaction kinetics of water electrolysis
This work creatively developed a strain-driven interstitial Ru doping strategy to synthesize an interstitially Ru doped-FeCoP/FF electrode with 2.32% tensile strain.
Green Chem., 2025,27, 2417-2426
https://doi.org/10.1039/D4GC06286H

Thermodynamically leveraged solventless aerobic deconstruction of polyethylene-terephthalate plastics over a single-site molybdenum-dioxo catalyst
This study reports the ambient catalytic depolymerization of PET under solvent-free conditions, using a carbon-supported single-site molybdenum-dioxo catalyst.
Green Chem., 2025,27, 2427-2438
https://doi.org/10.1039/D4GC05916F

Carbon dioxide-negative composite materials: an economically viable solution for CO2 sequestration
Carboxylating lignin and lignite fillers to sequester CO2 in composite materials.
Green Chem., 2025,27, 2392-2403
https://doi.org/10.1039/D4GC05692B
Anion doping promotes electrocatalyst reconfiguration for efficient C–C bond cleavage of 4-methylcyclohexanol
P doping promotes structural reconfiguration in nickel-based catalysts, forming an NiOOH/Ni2P interface that facilitates electrooxidation of 4-methylcyclohexanol.
Green Chem., 2025,27, 2008-2018
https://doi.org/10.1039/D4GC05682E
Natural wood as a lithium metal host
Natural wood with an exquisite 3D interconnected hierarchical porous structure is employed as a Li host. The wood host is conducive to regulating Li plating/stripping behavior, leading to reduced polarization and prolonged lifespan.
Green Chem., 2025,27, 1696-1702
https://doi.org/10.1039/D4GC05507A
The sustainable and catalytic synthesis of N,N-alkylated fatty amines from fatty acids and esters
The reductive amination of fatty acids (FAs) and fatty acid methyl esters (FAMEs) has been identified as a green and effective method to produce N,N-dimethylalkylamines (ADMAs).
Green Chem., 2025,27, 1410-1422
https://doi.org/10.1039/D4GC05740F

A waste-minimized protocol for electrochemical reductive amination and its environmental assessment
We report an efficient protocol for electrochemical reductive amination. A careful combination of reaction medium and electrolyte has allowed waste minimization and improved sustainability, as detailed by the environmental assessment of the process.
Green Chem., 2025,27, 633-641
https://doi.org/10.1039/D4GC04847D
“One-for-all” on-demand multifunctional fluorescent amphoteric polymers achieving breakthrough leather eco-manufacturing evolution
The proposed “all-in-one” strategy enables the creation of multifunctional materials for tanning, retanning, fatliquoring, and dyeing, simplifying leather manufacturing to meet market demands while delivering significant environmental benefits.
Green Chem., 2025,27, 498-516
https://doi.org/10.1039/D4GC04416A
About this collection
Welcome to our online rolling collection of the hottest work published in Green Chemistry. Here we feature all of the 2025 articles highlighted as HOT by our Editors and Referees. Congratulations to all those featured!