Themed collection Reaction Chemistry & Engineering Open Access Spotlight 2026

18 items
Open Access Review Article

Homogeneous catalysis in liquid organic hydrogen carriers: advances, challenges, and future directions

Recent advances in homogeneous LOHC (de)hydrogenation catalysis, key challenges, and the way forward in LOHC technology.

Graphical abstract: Homogeneous catalysis in liquid organic hydrogen carriers: advances, challenges, and future directions
Open Access Paper

Continuous microreactor synthesis of size-controlled Ru nanoparticles to probe support and size effects in ammonia cracking

This work reveals size–activity relationships in structurally sensitive reactions such as ammonia cracking by decoupling support and size effects through post-synthesis support of size-controlled flow synthesis nanoparticles.

Graphical abstract: Continuous microreactor synthesis of size-controlled Ru nanoparticles to probe support and size effects in ammonia cracking
Open Access Paper

Water and methanol cofeeding modulates kinetics in crude-to-chemical cracking

Co-processing crude oil with green methanol can integrate renewable carbon into refining, but water and other hydrophilic compounds like methanol can strongly affect catalyst behavior, product selectivity, and overall process efficiency.

Graphical abstract: Water and methanol cofeeding modulates kinetics in crude-to-chemical cracking
Open Access Paper

Photocatalytic butanol reforming for hydrogen production using Ag2O/TiO2 composite catalysts: effects of Ag2O loading, calcination temperature, and reaction parameters

Over recent years, photocatalytic biomass reforming for hydrogen production has gained research attention as an alternative to the inefficient water-splitting reaction, which requires a standard Gibbs free energy of 237 kJ mol−1.

Graphical abstract: Photocatalytic butanol reforming for hydrogen production using Ag2O/TiO2 composite catalysts: effects of Ag2O loading, calcination temperature, and reaction parameters
Open Access Paper

Kinetic insights into soybean peroxidase-catalyzed degradation of persistent organic pollutants

Enzymatic degradation of organic pollutants by means of peroxidase extracted from soybean hulls. A multi-substrate kinetic model allows to understand the interactions between different molecules and simulate the reaction mechanism well.

Graphical abstract: Kinetic insights into soybean peroxidase-catalyzed degradation of persistent organic pollutants
Open Access Paper

Studying deactivation pathways of molecular catalysts ex situ: an accessible method using standard analytical equipment

The catalyst stability was monitored using a new ex situ approach based on standard analytical techniques, enabling the identification of ligand degradation pathways and providing a basis for real-time optimization of reaction conditions.

Graphical abstract: Studying deactivation pathways of molecular catalysts ex situ: an accessible method using standard analytical equipment
Open Access Paper

ProcedureT5: adaptive experimental procedure prediction with data-augmented pre-training and multi-source data integration

Integrating chemistry-oriented pre-trained models with augmented multi-source datasets to develop ProceduerT5 and enhance experimental procedure prediction across broader scenarios.

Graphical abstract: ProcedureT5: adaptive experimental procedure prediction with data-augmented pre-training and multi-source data integration
Open Access Paper

Low-temperature standard-SCR over Cu-SSZ-13: selective inhibition of the oxidation half-cycle by mild hydrothermal aging

Mild hydrothermal aging selectively inhibits the oxidation half-cycle in low-temperature SCR; activity is fully restored by proportionally increasing oxygen pressure.

Graphical abstract: Low-temperature standard-SCR over Cu-SSZ-13: selective inhibition of the oxidation half-cycle by mild hydrothermal aging
Open Access Paper

Indirect hard modeling of low resolution benchtop NMR data for the kinetic fitting of a complex organic reaction

A benchtop NMR instrument in combination with spectral hard modeling enabled monitoring and subsequent kinetic fitting of a chlorination reaction. Different modes were investigated, an NMR tube, re-circulating batch and single pass continuous flow.

Graphical abstract: Indirect hard modeling of low resolution benchtop NMR data for the kinetic fitting of a complex organic reaction
Open Access Paper

Improving the univariate calibration approach with Bayesian modeling for IR reaction monitoring

A workflow based on Bayesian methods for improving the univariate calibration approach for reaction monitoring using Infrared (IR) spectroscopy.

Graphical abstract: Improving the univariate calibration approach with Bayesian modeling for IR reaction monitoring
Open Access Paper

Anion size-dependent carbon dioxide adsorption capacity in high-purity diallyldimethylammonium-based poly(ionic liquid)s

High-purity poly(ionic liquid)s with different anion sizes were prepared for the first time via careful dialysis. This work truly demonstrated that CO2 adsorption capacity could be enhanced by designing counter anions.

Graphical abstract: Anion size-dependent carbon dioxide adsorption capacity in high-purity diallyldimethylammonium-based poly(ionic liquid)s
From the themed collection: Emerging Investigator Series
Open Access Paper

Emulsion droplet-enabled selective electrochemical oxidation of alcohols at industrially relevant current densities

An electrochemical emulsion microenvironment enables TEMPO-mediated selective oxidation of alcohols to aldehydes with high selectivity and broad substrate scope.

Graphical abstract: Emulsion droplet-enabled selective electrochemical oxidation of alcohols at industrially relevant current densities
Open Access Paper

Oxidation of dibenzyl ether with nitric acid to benzaldehyde in continuous-flow microreactors

Accompanied by the generation of in situ gas, the rapid and highly exothermic gas–liquid–liquid three-phase reaction and kinetic study platform.

Graphical abstract: Oxidation of dibenzyl ether with nitric acid to benzaldehyde in continuous-flow microreactors
Open Access Paper

High-throughput experimentation for the application in oxidation reactions: solid dispensing approach for miniaturised reactions

A SiO2-based solid-dispensing method enables HTS of Cu-catalysed oxidative esterification of benzaldehyde to identify optimal reaction conditions across 96 parallel reactions.

Graphical abstract: High-throughput experimentation for the application in oxidation reactions: solid dispensing approach for miniaturised reactions
Open Access Paper

Model based process optimization for nanoparticle precipitation

This study presents a derivative-based optimization framework for nanoparticle synthesis. PBEs coupled with the exact Method of Moments enable optimal dynamic reactant inflow to minimize size variance while achieving a target mean diameter.

Graphical abstract: Model based process optimization for nanoparticle precipitation
Open Access Paper

Innovative ZSM-5-based catalyst design via 3D printing for methanol dehydration to DME

3D printing was successfully employed to fabricate structured ZSM-5-based catalysts with high catalytic activity in the methanol-to-DME reaction, good resistance to coke formation and high mechanical strength.

Graphical abstract: Innovative ZSM-5-based catalyst design via 3D printing for methanol dehydration to DME
Open Access Paper

Mechanistic insights into the thermal pyrolysis of high-density polyethylene and polypropylene: towards sustainable hydrogen production and carbon valorization

This study systematically investigates how plastic type and reactor temperature determine the gaseous, liquid, and solid products generated during high-temperature pyrolysis of plastic waste for hydrogen and carbon production.

Graphical abstract: Mechanistic insights into the thermal pyrolysis of high-density polyethylene and polypropylene: towards sustainable hydrogen production and carbon valorization
Open Access Paper

Advances in continuous manufacturing of albuterol sulfate: optimization of an amination reaction in flow

Translation of batch amination to continuous manufacturing with on-line reaction monitoring.

Graphical abstract: Advances in continuous manufacturing of albuterol sulfate: optimization of an amination reaction in flow
18 items

About this collection

Browse our 2026 Open Access articles!

All featured articles are published Gold Open Access and are free to read in Reaction Chemistry & Engineering.

Spotlight

Advertisements