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Themed collection Advances in ion spectroscopy - from astrophysics to biology

23 items
Accepted Manuscript - Paper

Probing solvation and reactivity in ionized polycyclic aromatic hydrocarbon-water clusters with photoionization mass spectrometry and electronic structure calculations.

Accepted Manuscript - Paper

Hydration Motifs of Ammonium Bisulfate Clusters of Relevance to Atmospheric New Particle Formation

Accepted Manuscript - Paper

Towards state selective recombination of H3+ ions at astrophysically relevant conditions

Accepted Manuscript - Paper

Photodetachment and Photoreactions of Substituted Naphthalene Anions in a Tandem Ion Mobility Spectrometer

Accepted Manuscript - Paper

Conformational assignment of gas phase peptides and their H-Bonded complexes using far-IR/THz: IR- UV ion dip experiment, DFT-MD spectroscopy, and Graph Theory for modes assignment.

Accepted Manuscript - Paper

Interactions of aggregating peptides probed by IR-UV action spectroscopy

Open Access Accepted Manuscript - Paper

Effect of alkali ions on optical properties of flavins: Vibronic spectra of cryogenic M+lumiflavin ionic complexes (M=Li-Cs)

Open Access Accepted Manuscript - Paper

Combining ultra-high resolution ion-mobility spectrometry with cryogenic IR spectroscopy for the study of biomolecular ions

Accepted Manuscript - Paper

Spectroscopy of Temporary Anion States: Renner-Teller Coupling and Electronic Autodetachment in Copper Difluoride Anion

Open Access Accepted Manuscript - Paper

Spectroscopy of corannulene cations in helium nanodroplets

Accepted Manuscript - Paper

Electronic Spectroscopy of Isolated Nucleic Acid Polyanions

Accepted Manuscript - Paper

Selecting and identifying gas-phase protonation isomers of nicotineH+ using combined laser, ion mobility and mass spectrometry techniques

Accepted Manuscript - Paper

Ion Reactions in Atmospherically-Relevant Clusters: Mechanisms, Dynamics and Spectroscopic Signatures

Accepted Manuscript - Paper

Electronic spectra of ions of astrochemical interest: From fast overview spectra to high resolution

Accepted Manuscript - Paper

State-selective coherent motional excitation as a new approach for the manipulation, spectroscopy and state-to-state chemistry of single molecular ions

Accepted Manuscript - Paper

Investigation of the position of the radical in z3-ions resulting from electron transfer dissociation using infrared ion spectroscopy

Open Access Accepted Manuscript - Paper

Electronic Spectroscopy and Nanocalorimetry of Hydrated Magnesium Ions [Mg(H2O)n]+, n = 20–70: Spontaneous Formation of a Hydrated Electron?

Accepted Manuscript - Paper

Probing the selectivity of Li+ and Na+ cations on noradrenaline at the molecular level

Accepted Manuscript - Paper

Model Potential Study of Non-valence Correlation-bound Anions of (C60)n Clusters: the Role of Electric Field-Induced Charge Transfer

Accepted Manuscript - Paper

Photoelectron spectra of Al2O2- and Al3O3- via slow electron velocity-map imaging

Accepted Manuscript - Paper

EOM-CC guide to Fock-space travel: The C2 edition

Accepted Manuscript - Paper

Electrospray ionization photoelectron spectroscopy of cryogenic [EDTA•M(II)]2− complexes (M = Ca, V−Zn): electronic structures and intrinsic redox properties

Open Access Accepted Manuscript - Paper

Storage time dependent photodissociation action spectroscopy of polycyclic aromatic hydrocarbon cations in the cryogenic electrostatic storage ring DESIREE

23 items

About this collection

We are delighted to share with you a selection of the papers which will be presented at our Faraday Discussion on Advances in ion spectroscopy - from astrophysics to biology taking place in York, UK in April 2019. More information about the event may be found here: http://rsc.li/ionspectroscopy-fd2019. Additional articles will be added to the collection as they are published. The final versions of all the articles presented and a record of the live discussions will be published after the event.

Gaseous ion spectroscopy generally couples mass spectrometry with high-resolution laser spectroscopy to studying the intrinsic chemical and physical properties of isolated ions. The isolation of the molecular ion of interest from its native environment is important to decouple the influence of the surroundings from the intrinsic properties. The effect of the environment can then be incrementally re-introduced through studies of sequentially solvated clusters, which allow the interaction with solvent molecules with the ion to be studied on the molecular level. With the potential to impact a wide range of chemical, physical and biological problems, the field has experienced rapid diversification in the past decade with the application of different ion sources, cryogenic ion traps, and new light sources such that this potential impact is rapidly being realised. The rapid development of experimental techniques has required a concomitant development of theory, which is now being used to model ever larger systems both in terms of structure and dynamics. This Faraday Discussion will bring together experimentalists and theoreticians working on ion spectroscopy in a broad sense to discuss the latest innovations and applications mapping the current status and future challenges of this field.

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