RSC Advances  

Subject area
Main-group chemistry articles published in the last 6 months

11 items
Open Access Paper

Keto–enol equilibrium: stable tautomers of ortho-, meta-, and para-hydroquinones in large aromatics

Keto–enol tautomerism of hydroquinones was studied for fused aromatic compounds. For larger fused aromatic compounds the dione tautomer was the stable form. These experimental results were corroborated by calculations.

Graphical abstract: Keto–enol equilibrium: stable tautomers of ortho-, meta-, and para-hydroquinones in large aromatics
Open Access Paper

Removal of Cr(VI) in wastewater by Fe–Mn oxide loaded sludge biochar

Sludge biochar loaded with Fe–Mn oxides (FMBC) was prepared and employed to remove Cr(VI) from wastewater.

Graphical abstract: Removal of Cr(vi) in wastewater by Fe–Mn oxide loaded sludge biochar
Open Access Paper

High-purity C3N quantum dots for enhancing fluorescence detection of metal ions

High-purity C3N QDs of a sensitive fluorescent response to various metal ions were synthesized by optimized solvothermal treatment with a yield up to 33.1%.

Graphical abstract: High-purity C3N quantum dots for enhancing fluorescence detection of metal ions
Open Access Review Article

Recent advances in the fluorimetric and colorimetric detection of cobalt ions

Cobalt is an essential metal to maintain several functions in the human body and is present in functional materials for numerous applications.

Graphical abstract: Recent advances in the fluorimetric and colorimetric detection of cobalt ions
From the themed collection: 2024 Reviews in RSC Advances
Open Access Paper

Phenothiazine appended thiophene derivative: a trilateral approach to copper ion detection in living cells and aqueous samples

A novel phenothiazine-thiophene acetonitrile compound was synthesised through a Knoevenagel condensation reaction. The compound demonstrated selectivity towards Cu2+ and proved to have low cytotoxicity.

Graphical abstract: Phenothiazine appended thiophene derivative: a trilateral approach to copper ion detection in living cells and aqueous samples
Open Access Paper

Nanoarchitectonics of highly dispersed polythiophene on paper for accurate quantitative detection of metal ions

Paper fibers allow the high dispersion of a fluorescent polythiophene chemosensor for the suppression of aggregation-induced quenching, which is applied to the solid-state fluorescent quantitative sensing of metal ions using imaging analysis and pattern recognition techniques.

Graphical abstract: Nanoarchitectonics of highly dispersed polythiophene on paper for accurate quantitative detection of metal ions
Open Access Paper

Simple potentiometry and cyclic voltammetry techniques for sensing Hg2+ ions in water using a promising flower-shaped WS2-WO3/poly-2-aminobenzene-1-thiol nanocomposite thin film electrode

The WS2-WO3/P2ABT nanocomposite sensor for Hg2+ ions uses both the cyclic voltammetry (three-electrode cell) and the simple potentiometric (two-electrode cell) techniques. The calibration curve yields a Nernstian slope of 33.0 mV decade−1 with a sensitivity of 2.4 μA M−1.

Graphical abstract: Simple potentiometry and cyclic voltammetry techniques for sensing Hg2+ ions in water using a promising flower-shaped WS2-WO3/poly-2-aminobenzene-1-thiol nanocomposite thin film electrode
Open Access Paper

Novel pyrazoline and pyrazole “turn on” fluorescent sensors selective for Zn2+/Cd2+ at λem 480 nm and Fe3+/Fe2+ at λem 465 nm in MeCN

A small series of simple pyrazoline and pyrazole based sensors, all derived from the same chalcone precursors, were synthesised, characterised and screened for their fluorescence “turn on” properties in the presence of multiple metals.

Graphical abstract: Novel pyrazoline and pyrazole “turn on” fluorescent sensors selective for Zn2+/Cd2+ at λem 480 nm and Fe3+/Fe2+ at λem 465 nm in MeCN
Open Access Paper

One-pot synthesis of unsubstituted and methyl substituted-pyrazinyl diselenides and monoselenides: structural, optical property characterization and DFT calculations

A facile synthesis of selenopyrazine compounds is demonstrated at room temperature. The molecular structures are unambiguously determined using SC-XRD. Additionally, the optical properties of these compounds are studied.

Graphical abstract: One-pot synthesis of unsubstituted and methyl substituted-pyrazinyl diselenides and monoselenides: structural, optical property characterization and DFT calculations
Open Access Paper

Electrochemical and X-ray structural evidence of multiple molybdenum precursor candidates from a reported non-aqueous electrodeposition of molybdenum disulfide

Various molybdenum complexes were identified reacting MoO3 and ethylene glycol, and both X-ray crystallography and electrochemistry provide a better understand of this complex, yet crucial reagent used for the 1st reported MoS2 electrodeposition.

Graphical abstract: Electrochemical and X-ray structural evidence of multiple molybdenum precursor candidates from a reported non-aqueous electrodeposition of molybdenum disulfide
Open Access Paper

A colorimetric and fluorescent signaling probe for assaying Pd2+ in practical samples

A colorimetric and fluorescent signaling probe was developed for Pd2+ assay in Pd-containing catalyst and drug candidate, with a rapid response and high selectivity.

Graphical abstract: A colorimetric and fluorescent signaling probe for assaying Pd2+ in practical samples
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