RSC Advances
Organometallic articles published in the last
6 months
Visible-light-induced N-alkylation of anilines with 4-hydroxybutan-2-one
The synthesis of amines through N-alkylation is particularly attractive.
RSC Adv., 2024,14, 14452-14455
https://doi.org/10.1039/D4RA01339E
New multiple-layered 3D polymers showing aggregation-induced emission and polarization
An exceptional achiral and chiral multilayer 3D polymer has been created and controlled by uniform and distinct aromatic chromophore units that are multiply sandwiched by naphthyl berths.
RSC Adv., 2024,14, 13342-13350
https://doi.org/10.1039/D4RA02128B
Syntheses, structural, photophysical and theoretical studies of heteroleptic cycloplatinated guanidinate(1−) complexes bearing acetylacetonate and picolinate ancillary ligands
[Pt(TAG-κC,κN)(acac)] (TAG = triarylguanidinate(1−) ligands) were isolated and fully characterized. These complexes are bluish green light emitters and the origin of absorption/emission in selected complexes were studied by TD-DFT calculations.
RSC Adv., 2024,14, 13291-13305
https://doi.org/10.1039/D4RA00828F
Selenosalicylate; a little-studied heavy-element analogue of the versatile thiosalicylate ligand
Selenosalicylic acid was synthesised by reacting 2-carboxybenzenediazonium chloride with Na2Se2 followed by reduction of the resulting diselenide with zinc and acetic acid. The deprotonated acid reacted with metal precursors to form selenosalicylate complexes.
RSC Adv., 2024,14, 12323-12336
https://doi.org/10.1039/D4RA00926F
Influences of Ru and ZrO2 interaction on the hydroesterification of styrene
Interfacial Lewis acid–base pairs are commonly found in ZrO2-supported metal catalysts due to the facile generation of oxygen vacancies of ZrO2.
RSC Adv., 2024,14, 11914-11920
https://doi.org/10.1039/D4RA00054D
Synthesis, characterization, and biomedical evaluation of ethylene-bridged tetra-NHC Pd(II), Pt(II) and Au(III) complexes, with apoptosis-inducing properties in cisplatin-resistant neuroblastoma cells
New ethylene-bridged N-heterocyclic carbene ligand systems and their respective transition metal complexes are characterized and the electronic properties are discussed.
RSC Adv., 2024,14, 10244-10254
https://doi.org/10.1039/D4RA01195C
In silico modelling of chelate stabilized tetrylene derivatives
The steric and electronic effects of specific ligands can play crucial roles in stabilizing unsaturated tetrylene species.
RSC Adv., 2024,14, 10161-10171
https://doi.org/10.1039/D4RA01515K
Capture of mechanically interlocked molecules by rhodium-mediated terminal alkyne dimerisation
Active metal template synthesis of an enyne-based rotaxane and catenane.
RSC Adv., 2024,14, 7740-7744
https://doi.org/10.1039/D4RA00566J
Tandem manganese catalysis for the chemo-, regio-, and stereoselective hydroboration of terminal alkynes: in situ precatalyst activation as a key to enhanced chemoselectivity
The manganese(II) complex [Mn(iPrPNP)Cl2] (iPrPNP = 2,6-bis(diisopropylphosphinomethyl)pyridine) was found to catalyze the stereo- and regioselective hydroboration of terminal alkynes employing HBPin (pinacolborane).
RSC Adv., 2024,14, 5514-5523
https://doi.org/10.1039/D3RA08747F
Rhodium-catalyzed annulation of hydrazines with vinylene carbonate to synthesize unsubstituted 1-aminoindole derivatives
The step-economical synthesis of C2, C3-unsubstituted 1-aminoindole derivatives through rhodium-catalyzed annulation of hydrazines with vinylene carbonate.
RSC Adv., 2024,14, 4804-4809
https://doi.org/10.1039/D3RA07466H
Salophen chromium(III) complexes functionalized with pyridinium salts as catalysts for carbon dioxide cycloaddition to epoxides
Novel multifunctional one-component catalysts for the cycloaddition of CO2 to epoxides. The selective and effective conversion of substrates to cyclic carbonates possible using 0.01 mol% catalyst and a low CO2 pressure.
RSC Adv., 2024,14, 2466-2480
https://doi.org/10.1039/D3RA07750K
Rational design of galactopyranoside-substituted N-heterocyclic carbene palladium(II) complexes. Stable and efficient catalyst for C–C coupling in aqueous media
Three palladium(II) complexes bearing galactopyranoside-based NHC ligands have been synthesized. Catalytic studies reveal that the complexes are active and reusable.
RSC Adv., 2024,14, 1626-1633
https://doi.org/10.1039/D3RA08031E
Thermodynamic evaluations of the acceptorless dehydrogenation and hydrogenation of pre-aromatic and aromatic N-heterocycles in acetonitrile
This work focuses on two new thermodynamic parameters of pre-aromatic and aromatic N-heterocycles to offer a precise insight into their chemical hydrogen storage and hydrogenation reactions.
RSC Adv., 2024,14, 222-232
https://doi.org/10.1039/D3RA08022F
Reactivity of azido terpyridine Pd(II) and Pt(II) complexes towards 4,4,4-trifluoro-2-butynoic acid: structural insight into the triazolato coordination mode
The binuclear azido terpyridine Pd(II) complex underwent the catalyst-free cycloaddition coupling with alkyne affording triazolate analogues. The coordination mode of the triazolate ring was assigned with the aid of quantum chemical calculations.
RSC Adv., 2023,13, 34826-34835
https://doi.org/10.1039/D3RA06656H
Palladium-anchored donor-flexible pyridylidene amide (PYA) electrocatalysts for CO2 reduction
Pd-PYA complexes as carbon dioxide reduction catalysts.
RSC Adv., 2023,13, 34817-34825
https://doi.org/10.1039/D3RA06477H
Synthesis of P-stereogenic 1-phosphanorbornane-derived phosphine–phosphite ligands and application in asymmetric catalysis
A convenient synthesis of enantiopure mixed donor phosphine–phosphite ligands has been developed incorporating P-stereogenic phosphanorbornane and axially chiral bisnaphthols into one ligand structure.
RSC Adv., 2023,13, 34439-34444
https://doi.org/10.1039/D3RA07630J
Browse by Subject
- All (342 articles)
- Atomic/elemental (14 articles)
- Bioanalytical (66 articles)
- Chemometrics (30 articles)
- Crystallography (165 articles)
- Electroanalytical (54 articles)
- Imaging/microscopy (33 articles)
- Mass spectrometry (22 articles)
- Medical diagnostics (80 articles)
- Microfluidics (18 articles)
- Nanoanalysis (21 articles)
- Separation science (28 articles)
- Spectroscopy (97 articles)
- All (283 articles)
- Bioinorganic chemistry (51 articles)
- Bioorganic chemistry (27 articles)
- Biotechnology (54 articles)
- Cellular chemistry (57 articles)
- Computational (83 articles)
- Drug delivery (81 articles)
- Drug discovery (187 articles)
- Imaging/diagnostics (16 articles)
- Molecular biology (6 articles)
- Nanotechnology (45 articles)
- Natural products (29 articles)
- Pharmacology (89 articles)
- Photobiology (15 articles)
- Polymorphism (pharma) (1 article)
- Structural biology (15 articles)
- Toxicology (5 articles)
- All (567 articles)
- Biomaterials (106 articles)
- Biopolymers (103 articles)
- Carbon materials (102 articles)
- Composites (254 articles)
- Electronic materials (97 articles)
- Encapsulation (1 article)
- Energy applications (87 articles)
- Films/membranes (82 articles)
- Gels & soft matter (35 articles)
- Inorganic materials (50 articles)
- Medical materials (72 articles)
- Nanomaterials (121 articles)
- Optical materials (54 articles)
- Organic materials (62 articles)
- Polymers (140 articles)
- All (356 articles)
- Assembly (13 articles)
- Biotechnology (32 articles)
- Carbon nanomaterials (80 articles)
- Imaging/microscopy (18 articles)
- Nanoanalysis (42 articles)
- Nanocatalysis (32 articles)
- Nanomaterials (217 articles)
- Nanomedicine (46 articles)
- Nanotoxicology (58 articles)
- Optical nanomaterials (38 articles)
- Synthesis (13 articles)
- All (177 articles)
- Bioorganic (17 articles)
- Catalysis (48 articles)
- Fine chemicals (25 articles)
- Natural products (21 articles)
- Physical organic (7 articles)
- Stereochemistry (12 articles)
- Supramolecular (3 articles)
- Sustainable synthesis (35 articles)
- Synthetic methodology (106 articles)
- Total synthesis (12 articles)
- All (321 articles)
- Biophysics (3 articles)
- Charge transfer (31 articles)
- Electrochemistry (12 articles)
- Energy research (18 articles)
- Imaging/microscopy (5 articles)
- Kinetics & dynamics (40 articles)
- Materials (108 articles)
- Mechanics (35 articles)
- Nanoscience (72 articles)
- Photoscience (25 articles)
- Quantum & theoretical (88 articles)
- Simulations (25 articles)
- Single molecules (43 articles)
- Soft matter (5 articles)
- Spectroscopy (7 articles)
- Surfaces & interfaces (69 articles)