Issue 3, 2015

Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant

Abstract

The oxidative olefination of a broad array of arenes and heteroarenes with a variety of activated and unactivated olefins has be achieved via a rhodium(III)-catalyzed C–H activation reaction. The use of an N-pentafluorophenyl benzamide directing group is crucial for achieving catalytic turnovers in the presence of air as the sole oxidant without using a co-oxidant.

Graphical abstract: Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant

Supplementary files

Article information

Article type
Edge Article
Submitted
31 Okt 2014
Accepted
05 Jan 2015
First published
08 Jan 2015
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2015,6, 1923-1927

Author version available

Rh(III)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant

Y. Lu, H. Wang, J. E. Spangler, K. Chen, P. Cui, Y. Zhao, W. Sun and J. Yu, Chem. Sci., 2015, 6, 1923 DOI: 10.1039/C4SC03350G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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