Themed collection Chemical Communications HOT Articles 2024

164 items - Showing page 1 of 3
Highlight

Unveiling the potential of MOF-based single-atom photocatalysts for the production of clean fuel and valuable chemical

Our highlight provides a comprehensive/insightful review on the achievement of combining a MOF and single atoms to generate high-performance photocatalysts for energy-related reactions.

Graphical abstract: Unveiling the potential of MOF-based single-atom photocatalysts for the production of clean fuel and valuable chemical
From the themed collection: Chemical Communications HOT Articles 2024
Highlight

Dual-stimuli responsive theranostic agents based on small molecules

This Highlight summarizes the recent progress of dual-stimuli responsive theranostic agents based on small molecules.

Graphical abstract: Dual-stimuli responsive theranostic agents based on small molecules
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Highlight

Functional implications of unusual NOS and SONOS covalent linkages found in proteins

Novel NOS linkages stabilize protein tertiary and quaternary structures and may be as prevalent as disulfide bonds. They regulate enzyme activity and have other important roles.

Graphical abstract: Functional implications of unusual NOS and SONOS covalent linkages found in proteins
From the themed collection: ChemComm 60th Anniversary Collection
Highlight

Value addition of MXenes as photo-/electrocatalysts in water splitting for sustainable hydrogen production

Recent advances in the use of MXenes for (photo)electrocatalytic water splitting applications are reviewed.

Graphical abstract: Value addition of MXenes as photo-/electrocatalysts in water splitting for sustainable hydrogen production
From the themed collection: Chemical Communications HOT Articles 2024
Highlight

Electrocatalytic water-to-oxygenates conversion: redox-mediated versus direct oxygen transfer

Elucidating the oxygen transfer route can facilitate the development of electro-catalytic oxygenation reactions. Herein, we introduce oxygen transfer routes including the redox-mediated pathway and the direct oxygen transfer (DOT) method.

Graphical abstract: Electrocatalytic water-to-oxygenates conversion: redox-mediated versus direct oxygen transfer
From the themed collection: 2024 Pioneering Investigators
Highlight

Electrifying oxidation of ethylene and propylene

This highlight discusses the advantages of various oxidation methods for improved performance of the electrochemical oxidation of ethylene and propylene, and provides an overview of current challenges and problems requiring further efforts.

Graphical abstract: Electrifying oxidation of ethylene and propylene
From the themed collection: ChemComm 60th Anniversary Collection
Open Access Highlight

Mechanism-based and data-driven modeling in cell-free synthetic biology

This highlight discusses state-of-the-art mechanism-based modeling and machine-learning approaches in cell-free synthetic biology and their potential for designing and optimizing novel genetic circuits.

Graphical abstract: Mechanism-based and data-driven modeling in cell-free synthetic biology
From the themed collection: 2024 Pioneering Investigators
Highlight

Recent advances in C(sp3)–N bond formation via metallaphoto-redox catalysis

In this review, the state-of-the-art advances in radical-involved C(sp3)–N bond formation via metallaphotoredox catalysis have been highlighted, which are organized according to different catalytic modes, reaction types, and substrate classes.

Graphical abstract: Recent advances in C(sp3)–N bond formation via metallaphoto-redox catalysis
From the themed collection: Chemical Communications HOT Articles 2024
Highlight

Recent developments in photocatalytic production of hydrogen peroxide

This highlight article summarizes the recent developments and challenges in photocatalytic production of hydrogen peroxide and looks forward to the development direction of this field.

Graphical abstract: Recent developments in photocatalytic production of hydrogen peroxide
From the themed collection: ChemComm 60th Anniversary Collection
Open Access Highlight

Recent advances in electrosynthesis of H2O2via two-electron oxygen reduction reaction

This review provides an electrosynthesis strategy of H2O2via the 2e ORR, covering aspects of reaction mechanisms, performance assessment, catalyst engineering, and setups for scaling up H2O2 production.

Graphical abstract: Recent advances in electrosynthesis of H2O2via two-electron oxygen reduction reaction
From the themed collection: ChemComm 60th Anniversary Collection
Highlight

Enantioselective merged gold/organocatalysis

This highlight demonstrates the state of the art in the field of the enantioselective merged gold/organocatalysis by leveraging the unique reactivity of each catalyst.

Graphical abstract: Enantioselective merged gold/organocatalysis
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Highlight

Visual monitoring of biocatalytic processes using small molecular fluorescent probes: strategies-mechanisms-applications

Real-time monitoring of biocatalytic-based processes is significantly improved and simplified when they can be visualized.

Graphical abstract: Visual monitoring of biocatalytic processes using small molecular fluorescent probes: strategies-mechanisms-applications
From the themed collection: Chemical Communications HOT Articles 2024
Highlight

Catalysts and electrolyzers for the electrochemical CO2 reduction reaction: from laboratory to industrial applications

To cope with the environmental pollution and energy shortage, reducing carbon dioxide molecules and producing fuels and chemicals via electrocatalytic methods, is one of the effective pathways to achieve carbon neutrality.

Graphical abstract: Catalysts and electrolyzers for the electrochemical CO2 reduction reaction: from laboratory to industrial applications
From the themed collection: Chemical Communications HOT Articles 2024
Accepted Manuscript - Feature Article

Upcycling of waste polyester for the development of circular economy

From the themed collection: Chemical Communications HOT Articles 2024
Open Access Accepted Manuscript - Feature Article

Exploiting hydrogenases for biocatalytic hydrogenations

From the themed collection: ChemComm 60th Anniversary Collection
Feature Article

Biomimetic light-harvesting antennas via the self-assembly of chemically programmed chlorophylls

This feature article describes strategies for constructing supramolecular aggregates of (semi)synthetic dyes, particularly chlorophyll derivatives to mimic the photosynthetic light-harvesting antennas.

Graphical abstract: Biomimetic light-harvesting antennas via the self-assembly of chemically programmed chlorophylls
From the themed collection: 2024 Emerging Investigators
Feature Article

Multiphase coacervates: mimicking complex cellular structures through liquid–liquid phase separation

This review summarizes recent advancements in the study of multiphase coacervates, focusing on design strategies, underlying mechanisms, structural control, and their applications in biomimetics.

Graphical abstract: Multiphase coacervates: mimicking complex cellular structures through liquid–liquid phase separation
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Recent advances in catalytic enantioselective construction of monofluoromethyl-substituted stereocenters

This feature article comprehensively summarizes the recent advances in catalytic enantioselective construction of monofluoromethyl-substituted stereocenters.

Graphical abstract: Recent advances in catalytic enantioselective construction of monofluoromethyl-substituted stereocenters
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Feature Article

Spot the difference in reactivity: a comprehensive review of site-selective multicomponent conjugation exploiting multi-azide compounds

This review outlines methods and strategies to exploit specific azide positions for molecular conjugation in the presence of multiple azido groups. Illustrative examples spanning di-, tri- and tetraazide click scaffolds are included.

Graphical abstract: Spot the difference in reactivity: a comprehensive review of site-selective multicomponent conjugation exploiting multi-azide compounds
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Common ground and divergence: OLED emitters as photocatalysts

Many photocatalysts were initially developed or used as emitters for organic light emitting diodes (OLEDs). Requirements for photocatalysts and OLED emitters overlap in many aspects but diverge in some.

Graphical abstract: Common ground and divergence: OLED emitters as photocatalysts
From the themed collection: ChemComm 60th Anniversary Collection
Feature Article

1,3-Bishomocubane: a kinetic rock, a thermodynamic powerhouse and a compelling chiral synthetic scaffold

Over the last several decades, saturated polycyclic cage compounds have remained a point of interest for organic chemists because of their unique characteristics and reactivity.

Graphical abstract: 1,3-Bishomocubane: a kinetic rock, a thermodynamic powerhouse and a compelling chiral synthetic scaffold
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Development of chemiluminescent systems and devices for analytical applications

Chemiluminescent luminophores, coreactants, catalysts and sonochemiluminescence devices are highlighted.

Graphical abstract: Development of chemiluminescent systems and devices for analytical applications
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Metal-free small molecule-based piezoelectric energy harvesters

The recent progress in the design of metal-free small-molecule derived piezoelectric materials and their utilization as all-organic piezoelectric energy harvesters has been discussed in this feature article.

Graphical abstract: Metal-free small molecule-based piezoelectric energy harvesters
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Advances in designing efficient electrocatalysts for nitrate reduction from a theoretical perspective

The electrochemical nitrate reduction reaction to ammonia (eNO3RR) is a potential way for harmonizing the nitrogen cycle. This feature article summarizes the recent advances in electrocatalyst design for the eNO3RR from a theoretical perspective.

Graphical abstract: Advances in designing efficient electrocatalysts for nitrate reduction from a theoretical perspective
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Advances in the self-organized total synthesis of natural products

In this review, we account for the definition, delimitation, and categorization of self-organized total synthesis and then elucidate a comprehensive understanding of this synthetic strategy based on our intensive explorations.

Graphical abstract: Advances in the self-organized total synthesis of natural products
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Heterogeneous catalysis of methane hydroxylation with nearly total selectivity under mild conditions

Recent advancements in methane hydroxylation catalysis have achieved nearly total selectivity. A deeper understanding of catalyst design, reaction mechanism, and parameter optimization is crucial for minimizing CO2 and boosting oxygenate yield.

Graphical abstract: Heterogeneous catalysis of methane hydroxylation with nearly total selectivity under mild conditions
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Supramolecular light-harvesting systems utilizing tetraphenylethylene chromophores as antennas

This comprehensive Feature Article summarizes the recent progress of supramolecular light-harvesting systems utilizing tetraphenylethylene (TPE) chromophores as antennas.

Graphical abstract: Supramolecular light-harvesting systems utilizing tetraphenylethylene chromophores as antennas
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Cationic ligands – from monodentate to pincer systems

Incorporation of cationic ligands within pincer frameworks allowed to develop them from obscure peculiarities into a diverse class of ancillary ligands.

Graphical abstract: Cationic ligands – from monodentate to pincer systems
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Glycosylation with sulfoxide-based glycosyl donors

This feature article elucidates the development and notable progress of glycosyl sulfoxide-based glycosylation reactions, with a specific emphasis on cases where sulfinyl groups are situated either directly at the anomeric position or more distally.

Graphical abstract: Glycosylation with sulfoxide-based glycosyl donors
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Mechanistic insights into facilitating reductive elimination from Ni(II) species

The possible modes have been summarized to disclose the reductive elimination from Ni(II) species.

Graphical abstract: Mechanistic insights into facilitating reductive elimination from Ni(ii) species
From the themed collection: 2024 Pioneering Investigators
Feature Article

Ru(0)-catalysed synthesis of borylated polyene building blocks by cross-dimerisation toward cross-coupling

A series of borylated polyenes is synthesised by cross-dimerisation as a synthetic building block for cross-coupling reactions.

Graphical abstract: Ru(0)-catalysed synthesis of borylated polyene building blocks by cross-dimerisation toward cross-coupling
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Recent advances in circularly polarized luminescence of planar chiral organic compounds

This review overviews recent research on circularly polarized luminescence from planar chiral organic compounds, focusing on their synthetic strategies, properties and applications.

Graphical abstract: Recent advances in circularly polarized luminescence of planar chiral organic compounds
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Metal–organic framework (MOF)-based materials for pyroptosis-mediated cancer therapy

This manuscript summarized the recent progress of MOF-based pyroptosis inducers in immunotherapy.

Graphical abstract: Metal–organic framework (MOF)-based materials for pyroptosis-mediated cancer therapy
From the themed collection: Emerging Trends in MOFs
Open Access Feature Article

Hydrogen bond types which do not fit accepted definitions

There are various interactions that either partially fit or do not fit the currently accepted definitions of the hydrogen bond.

Graphical abstract: Hydrogen bond types which do not fit accepted definitions
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Feature Article

All-atom molecular dynamics simulations of polymer and polyelectrolyte brushes

New discoveries on polymer and polyelectrolyte brush systems and the corresponding brush-supported ions and water, arising from employing all-atom molecular dynamics simulations, have been thoroughly reviewed.

Graphical abstract: All-atom molecular dynamics simulations of polymer and polyelectrolyte brushes
From the themed collection: 2024 Pioneering Investigators
Feature Article

Molecule engineering strategy of toll-like receptor 7/8 agonists designed for potentiating immune stimuli activation

We highlighted the recent research progress concerning the molecule engineering strategy of toll-like receptor 7/8 agonists for enhancing immunotherapy, including our research work and some related emerging works.

Graphical abstract: Molecule engineering strategy of toll-like receptor 7/8 agonists designed for potentiating immune stimuli activation
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Feature Article

Cascade ring expansion reactions for the synthesis of medium-sized rings and macrocycles

Recent advances in the development of cascade ring expansion reactions for the synthesis of medium-sized rings and macrocycles are described.

Graphical abstract: Cascade ring expansion reactions for the synthesis of medium-sized rings and macrocycles
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Feature Article

Cooperative small molecule activation by apolar and weakly polar bonds through the lens of a suitable computational protocol

Through the magnifying glass of a suitable computational protocol, both support and guidance of experimental advances in small molecules activation mediated by apolar and weakly polar bonds are made possible.

Graphical abstract: Cooperative small molecule activation by apolar and weakly polar bonds through the lens of a suitable computational protocol
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Artificial transmembrane potassium transporters: designs, functions, mechanisms and applications

In this review, we provide the very first comprehensive exposition of artificial potassium transporters developed mostly over the past ten years.

Graphical abstract: Artificial transmembrane potassium transporters: designs, functions, mechanisms and applications
From the themed collection: Chemical Communications HOT Articles 2024
Feature Article

Emerging sensing platforms based on Cucurbit[n]uril functionalized gold nanoparticles and electrodes

Cucurbit[n]uril functionalized gold nanoparticles and electrodes facilitate the development of sensing platforms based on recognition tunneling, surface-enhanced Raman spectroscopy, single molecule force spectroscopy, and electrochemical methods.

Graphical abstract: Emerging sensing platforms based on Cucurbit[n]uril functionalized gold nanoparticles and electrodes
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Feature Article

Sample transformation in online separations: how chemical conversion advances analytical technology

Sample transformation can be used to provide insights into the properties of complex samples.

Graphical abstract: Sample transformation in online separations: how chemical conversion advances analytical technology
From the themed collection: Chemical Communications HOT Articles 2024
Accepted Manuscript - Communication

Ni-Catalyzed Reductive Cyanation of Alkenyl Tosylates and Triflates

From the themed collection: ChemComm 60th Anniversary Collection
Accepted Manuscript - Communication

Chemical oxidation of a double-twisted nanographene

From the themed collection: Chemical Communications HOT Articles 2024
Open Access Accepted Manuscript - Communication

Detecting Single-Point Isomeric Differences in Polymer Chains by MOF Column Chromatography

From the themed collection: ChemComm 60th Anniversary Collection
Communication

A ternary composite nanofiber-derived thin membrane electrolyte for solid-state Li metal batteries

We develop a novel membrane electrolyte comprising h-BN-doped PEO modified PVDF-HFP-nanofibers with high ionic conductivity (3.3 × 10−4 S cm−1) and Li+ transference number (0.74), endowing solid LiFePO4//Li batteries with excellent cyclability.

Graphical abstract: A ternary composite nanofiber-derived thin membrane electrolyte for solid-state Li metal batteries
From the themed collection: Chemical Communications HOT Articles 2024
Communication

Diamidocarbene-derived palladium and nickel–sulfur clusters

Tetranuclear palladium and nickel–sulfur clusters were synthesized using a diamidocarbene-derived, redox-active carbon disulfide ligand.

Graphical abstract: Diamidocarbene-derived palladium and nickel–sulfur clusters
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Communication

Asymmetric cyclopropanation via an electro-organocatalytic cascade

The work demonstrates the successful merger of electrochemistry with asymmetric iminium ion organocatalysis.

Graphical abstract: Asymmetric cyclopropanation via an electro-organocatalytic cascade
From the themed collection: Chemical Communications HOT Articles 2024
Accepted Manuscript - Communication

Giant Macrocycle Overcomes the Post-Treatment Phototoxicity of Photofrin through Host-Guest Complexation

From the themed collection: ChemComm 60th Anniversary Collection
Communication

Cobalt-catalyzed dithiolation of unactivated alkenes with thiols: facile access to diverse vicinal dithioethers

A simple cobalt-catalytic aerobic approach for the direct dithiolation of unactivated alkenes with thiols has been established, enabling efficient access to symmetric and unsymmetric vicinal dithioethers under mild reaction conditions.

Graphical abstract: Cobalt-catalyzed dithiolation of unactivated alkenes with thiols: facile access to diverse vicinal dithioethers
Communication

Copper-catalyzed perfluoroalkylation of propargyl gem-dichlorides

We developed a method for the copper-catalyzed coupling of propargyl gem-dichlorides with (DMPU)2Zn(Rf)2 to assemble chloro-substituted fluoroalkylated allenes. The reaction proceeds under mild conditions with good functional group tolerance.

Graphical abstract: Copper-catalyzed perfluoroalkylation of propargyl gem-dichlorides
From the themed collection: Chemical Communications HOT Articles 2024
Communication

Inhibition of Acinetobacter nosocomialis twitching motility by quinolones produced by Pseudomonas aeruginosa

Quinolones from P. aeruginosa inhibit the twitching motility of A. nosocomialis without interfering with its growth. This finding suggests an intriguing quinolone-based mechanism that enables P. aeruginosa to limit encroachment of other microbes.

Graphical abstract: Inhibition of Acinetobacter nosocomialis twitching motility by quinolones produced by Pseudomonas aeruginosa
From the themed collection: ChemComm 60th Anniversary Collection
Open Access Communication

Developing non-radioactive, radical methods to screen for radiolytic stability

A non-radioactive, radical method is reported as a screening tool for radiolytic degradation. Similar degradation products and trends are observed between this newly developed, higher-throughput assay and traditional gamma radiolysis.

Graphical abstract: Developing non-radioactive, radical methods to screen for radiolytic stability
From the themed collection: Chemical Communications HOT Articles 2024
Communication

Blue photoluminescence of wide-bandgap polystyrenesulfonate materials

Blue photoluminescence (PL) was observed in polystyrene sulfonic acid solution (PSS) for the first time. And the diversity and tunability of its PL properties were revealed.

Graphical abstract: Blue photoluminescence of wide-bandgap polystyrenesulfonate materials
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Communication

Reversible CO2 insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane

The reversible insertion of carbon dioxide into the silicon–nitrogen bond of an N-heterocyclic iminosilane is reported.

Graphical abstract: Reversible CO2 insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane
From the themed collection: Chemical Communications HOT Articles 2024
Communication

Iminobispyrazole (IBP) photoswitches: two pyrazole rings can be better than one

Sometimes, two pyrazoles are better than one: exploring the photoswitching properties of synthetically accessible iminobispyrazoles.

Graphical abstract: Iminobispyrazole (IBP) photoswitches: two pyrazole rings can be better than one
From the themed collection: Chemical Communications HOT Articles 2024
Communication

Selective 17O-labeling of silica

Silanol groups on the surface of silica are labile and spontaneously exchange their oxygen atoms with water. This enables the synthesis of silica materials that are selectively labeled in 17O at either the silanol or siloxane positions.

Graphical abstract: Selective 17O-labeling of silica
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Communication

Isolation of a chloride-capped cerium polyoxo nanocluster built from 52 metal ions

A chloride/water terminated Ce–oxo cluster built from 52 metal ions, with the longest Ce–Ce distance measuring roughly 1.6 nm, was isolated from acidic aqueous solution using pyridinium counterions.

Graphical abstract: Isolation of a chloride-capped cerium polyoxo nanocluster built from 52 metal ions
From the themed collection: Chemical Communications HOT Articles 2024
Communication

Diastereoselective dearomative cycloaddition of bicyclobutanes with pyridinium ylides: a modular approach to multisubstituted azabicyclo[3.1.1]heptanes

Structurally-dense and stereochemically-defined tricyclic heterocycles are easily accessed by (3+3) cycloaddition, leading to versatile Csp3-rich scaffolds.

Graphical abstract: Diastereoselective dearomative cycloaddition of bicyclobutanes with pyridinium ylides: a modular approach to multisubstituted azabicyclo[3.1.1]heptanes
From the themed collection: Chemical Communications HOT Articles 2024
Communication

Ligand effects on gas adsorption in nanoporous phthalocyanine crystals

Sorption of CO and NO in phthalocyanine nanoporous crystals with 4,4′ bipyridine or 4,4′ bipyrimidine trans coordinated to open Co2+ sites has been studied, demonstrating how the ligands influence gas sorption properties and structures.

Graphical abstract: Ligand effects on gas adsorption in nanoporous phthalocyanine crystals
From the themed collection: ChemComm 60th Anniversary Collection
Communication

Unravelling the prebiotic origins of the simplest α-ketoacids in cometary ices: a computational investigation

Extra-terrestrial origins of the simplest α-ketoacids, central to many prebiotic metabolic cycles, have been revealed by simulating the soft impact-induced compression of cometary ices.

Graphical abstract: Unravelling the prebiotic origins of the simplest α-ketoacids in cometary ices: a computational investigation
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Communication

Polyoxometalate-incorporated NiFe-based oxyhydroxides for enhanced oxygen evolution reaction in alkaline media

NiFe–PMA/CNTs homogeneous/heterogeneous hybrid catalyst exhibits low overpotential and a high TOF for the oxygen evolution reaction.

Graphical abstract: Polyoxometalate-incorporated NiFe-based oxyhydroxides for enhanced oxygen evolution reaction in alkaline media
From the themed collection: ChemComm 60th Anniversary Collection
Open Access Communication

Nitrogen fixation by alkali and alkaline earth metal hydrides assisted by plasma

The chemical behaviors of alkali and alkaline earth metal hydrides under nitrogen plasma differ significantly from one another, exhibiting an ammonia production trend that contrasts with that observed under thermal conditions.

Graphical abstract: Nitrogen fixation by alkali and alkaline earth metal hydrides assisted by plasma
From the themed collection: ChemComm 60th Anniversary Collection
Communication

Molten-salt-induced structural heterogeneity of carbon nitride for efficient photocatalytic H2O2 production

In the prepared molecular heterostructured carbon nitride, the intimately connected heptazine and triazine units effectively accelerate charge transport, leading to a remarkably enhanced photocatalytic H2O2 production.

Graphical abstract: Molten-salt-induced structural heterogeneity of carbon nitride for efficient photocatalytic H2O2 production
From the themed collection: Chemical Communications HOT Articles 2024
Communication

Covalently grafting a covalent organic framework onto carbon nanotubes as a bifunctional electrocatalyst for overall water splitting

A combined nanoscale and molecular-level strategy was developed to coat Ni(II) modified bipyridine-based COF on amino-functionalized CNTs through covalent bonding as a bifunctional electrocatalyst for water splitting in alkaline solution.

Graphical abstract: Covalently grafting a covalent organic framework onto carbon nanotubes as a bifunctional electrocatalyst for overall water splitting
From the themed collection: ChemComm 60th Anniversary Collection
Open Access Communication

A povarov-type reaction to access tetrahydroquinolines from N-benzylhydroxylamines and alkenes in HFIP

Here, we report the synthesis of tetrahydroquinolines between newly developed N-benzylhydroxylamine reagents and alkenes using HFIP as a solvent.

Graphical abstract: A povarov-type reaction to access tetrahydroquinolines from N-benzylhydroxylamines and alkenes in HFIP
From the themed collection: ChemComm 60th Anniversary Collection
Communication

Low-temperature de-alloying and unique self-filling interface optimization mechanism of layered silicon for enhanced lithium storage

The safe synthesis and unique self-filling interface optimization mechanism of high-purity layered silicon for lithium storage.

Graphical abstract: Low-temperature de-alloying and unique self-filling interface optimization mechanism of layered silicon for enhanced lithium storage
From the themed collection: Chemical Communications HOT Articles 2024
Communication

An isolable stannaimine and its cycloaddition/metathesis reactions with carbon dioxide

An isolable stannaimine deoxygenates carbon dioxide to form a dimeric stannaoxane and a new isocyanate.

Graphical abstract: An isolable stannaimine and its cycloaddition/metathesis reactions with carbon dioxide
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Communication

Photochemical α-amination of carbonyl groups with iodinanes

We report on a photochemical reaction of silyl enol ethers with iminoiodinanes.

Graphical abstract: Photochemical α-amination of carbonyl groups with iodinanes
From the themed collection: Chemical Communications HOT Articles 2024
Open Access Communication

One-, two- and three-dimensional interlocked polymers based on hybrid inorganic–organic rotaxanes

We report three new polymers, based on mechanically interlocked inorganic–organic rotaxanes.

Graphical abstract: One-, two- and three-dimensional interlocked polymers based on hybrid inorganic–organic rotaxanes
From the themed collection: Chemical Communications HOT Articles 2024
Communication

Thiophene assisted cellular uptake enhancement for highly efficient NIR-II cancer phototheranostics

We proposed a strategy of thiophene assisted cellular uptake enhancement for achieving highly efficient NIR-II cancer phototheranostics.

Graphical abstract: Thiophene assisted cellular uptake enhancement for highly efficient NIR-II cancer phototheranostics
From the themed collection: Chemical Communications HOT Articles 2024
164 items - Showing page 1 of 3

About this collection

This ongoing web-collection features the articles published in ChemComm in 2024 that have been marked as HOT by our Editors and trusted Reviewers. Many Congratulations to all those featured!


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