Issue 8, 2010
From the journal:

CrystEngComm

Control over the nucleation process determines the framework topology of porous coordination polymers†

Mio Kondo,a   Yohei Takashima,b   Joobeom Seo,c   Susumu Kitagawa*abc  and  Shuhei Furukawa*ac  

* Corresponding authors

a Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

b Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: kitagawa@sbchem.kyoto-u.ac.jp

c ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815, Japan
E-mail: shuhei.furukawa@kip.jst.go.jp

Abstract

In this contribution, we present a method to selectively synthesize crystal polymorphs of [Zn2(bdc)2(dabco)]n (1) and [Zn2(bdc)2(bpy)]n (2), either the pillared 2D square-grid nets (1sql or 2sql) or the pillared 2D Kagomé nets (1kgm or 2kgm) by simply changing the crystallization temperature.

Graphical abstract: Control over the nucleation process determines the framework topology of porous coordination polymers

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Article information

DOI
https://doi.org/10.1039/C004066E
Article type
Communication
Submitted
10 Mar 2010
Accepted
22 Jun 2010
First published
05 Jul 2010

CrystEngComm, 2010,12, 2350-2353

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Control over the nucleation process determines the framework topology of porous coordination polymers

M. Kondo, Y. Takashima, J. Seo, S. Kitagawa and S. Furukawa, CrystEngComm, 2010, 12, 2350 DOI: 10.1039/C004066E

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