Issue 8, 2010
From the journal:

CrystEngComm

A metal–organic framework with coordinatively unsaturated metal centers and microporous structure†

Bin Mu,a   Yougui Huanga  and  Krista S. Walton*a  

* Corresponding authors

a School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia, USA
E-mail: krista.walton@chbe.gatech.edu
Fax: +1-404-894-2866
Tel: +1-404-894-5254

Abstract

A novel two dimensional porous framework [Cd3(BTB)2(DEF)4]n·2nDEF (1) based on {Cd3} building blocks with bilayer honeycomb structure constructed from cadmium ion bridged honeycomb layers exhibits promising adsorption for N2 after activation to obtain coordinatively unsaturated Cd centers, and SEM characterization demonstrates interesting microporous structure inside of the compound.

Graphical abstract: A metal–organic framework with coordinatively unsaturated metal centers and microporous structure

  • This article is part of the themed collection: New Talent
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Article information

DOI
https://doi.org/10.1039/C001485K
Article type
Communication
Submitted
22 Jan 2010
Accepted
26 May 2010
First published
10 Jun 2010

CrystEngComm, 2010,12, 2347-2349

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A metal–organic framework with coordinatively unsaturated metal centers and microporous structure

B. Mu, Y. Huang and K. S. Walton, CrystEngComm, 2010, 12, 2347 DOI: 10.1039/C001485K

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