Issue 73, 2018

Dramatic enhancement of spin–spin coupling and quenching of magnetic dimensionality in compressed silver difluoride

Abstract

Meta-GGA calculations of the ambient and high-pressure polymorphs of silver difluoride indicate that the compression-induced structural changes lead to a 3.5-fold increase in the strength of antiferromagnetic spin–spin interactions resulting in coupling constant values higher than those found for record-holding oxocuprates(II).

Graphical abstract: Dramatic enhancement of spin–spin coupling and quenching of magnetic dimensionality in compressed silver difluoride

Supplementary files

Article information

Article type
Communication
Submitted
22 јун. 2018
Accepted
16 јул. 2018
First published
24 јул. 2018

Chem. Commun., 2018,54, 10252-10255

Dramatic enhancement of spin–spin coupling and quenching of magnetic dimensionality in compressed silver difluoride

D. Kurzydłowski, M. Derzsi, P. Barone, A. Grzelak, V. Struzhkin, J. Lorenzana and W. Grochala, Chem. Commun., 2018, 54, 10252 DOI: 10.1039/C8CC05002C

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