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Issue 73, 2018
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Building a 22-ring nanographene by combining in-solution and on-surface syntheses

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Abstract

A nanographene formed by the fusion of 22 benzene rings has been prepared by combining an in-solution Pd-catalyzed cycloaddition reaction and on-surface Au-promoted cyclodehydrogenation. The structure and electronic properties of the resulting three-fold symmetric C66H24 molecule have been characterized by scanning probe microscopy with atomic resolution and corroborated by theoretical modelling.

Graphical abstract: Building a 22-ring nanographene by combining in-solution and on-surface syntheses

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Publication details

The article was received on 03 Jul 2018, accepted on 17 Aug 2018 and first published on 17 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC05353G
Citation: Chem. Commun., 2018,54, 10256-10259

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    Building a 22-ring nanographene by combining in-solution and on-surface syntheses

    R. Zuzak, J. Castro-Esteban, P. Brandimarte, M. Engelund, A. Cobas, P. Piątkowski, M. Kolmer, D. Pérez, E. Guitián, M. Szymonski, D. Sánchez-Portal, S. Godlewski and D. Peña, Chem. Commun., 2018, 54, 10256
    DOI: 10.1039/C8CC05353G

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