Themed collection Catalysis Science & Technology Most Popular 2025 Articles

22 items
Perspective

Advancements in transition metal iron-based catalysts: enhancing catalytic activity through electron transfer

In this perspective, we aim to explore the latest advancements in a range of design improvements in iron-based catalysts, with a particular focus on electron transfer during catalytic processes.

Graphical abstract: Advancements in transition metal iron-based catalysts: enhancing catalytic activity through electron transfer
Review Article

Synthesis strategies of supported bimetallic catalysts for hydrogenation reactions: review and outlook

In this review, we focus on the synthesis strategies of supported bimetallic catalysts for hydrogenation reactions. We also discuss nano-catalysts, single-atom catalysts, and the role of catalyst support in enhancing bimetallic systems.

Graphical abstract: Synthesis strategies of supported bimetallic catalysts for hydrogenation reactions: review and outlook
From the themed collection: Emerging Investigator Series
Open Access Review Article

From CO2 to DME: catalytic advances, challenges, and alternatives to conventional gas-phase routes

This work reviews advances in CO2-to-DME synthesis under mild conditions, emphasizing gas and liquid-phase routes, catalyst design, and a novel methyl formate pathway, highlighting both its potential and current limitations.

Graphical abstract: From CO2 to DME: catalytic advances, challenges, and alternatives to conventional gas-phase routes
Review Article

A review of reversible hydrogenation and dehydrogenation catalysts for liquid organic hydrogen carriers

Recent advancements in the catalytic hydrogenation and dehydrogenation of LOHCs are introduced, particularly focusing on the role of metal catalysts in enhancing the reversible hydrogenation and release of hydrogen.

Graphical abstract: A review of reversible hydrogenation and dehydrogenation catalysts for liquid organic hydrogen carriers
Review Article

Recent progress and perspective of electrocatalysts for the hydrogen evolution reaction

The article explores an in-depth exploration of the diverse range of catalysts that are commonly employed in the field of electrocatalytic HER, such as metals, oxides, sulfides, selenides, carbides, phosphides, nitrides, borides, single-atom catalysts, and carbon-supported catalysts.

Graphical abstract: Recent progress and perspective of electrocatalysts for the hydrogen evolution reaction
Review Article

Recent progress in understanding the role of graphene oxide, TiO2 and graphene oxide–TiO2 nanocomposites as multidisciplinary photocatalysts in energy and environmental applications

A review on graphene oxide (GO)–TiO2 nanocomposites with emphasis on the role of GO as a co-catalyst and photocatalyst, providing a synergistic effect as well as multidisciplinary photocatalytic activities in the fields of energy and the environment.

Graphical abstract: Recent progress in understanding the role of graphene oxide, TiO2 and graphene oxide–TiO2 nanocomposites as multidisciplinary photocatalysts in energy and environmental applications
Review Article

Recent progress in gel catalysts: boosting efficiency for sustainable energy applications

Achieving carbon neutrality and mitigating global warming necessitate a shift from fossil fuels to renewable energy sources.

Graphical abstract: Recent progress in gel catalysts: boosting efficiency for sustainable energy applications
Open Access Review Article

A mini review on photocatalytic lignin conversion into monomeric aromatic compounds

This review systematically outlines the development of photocatalytic lignin conversion, critically reviews the advantages and limitations of photocatalytic systems from the key studies, highlights key challenges and future perspectives.

Graphical abstract: A mini review on photocatalytic lignin conversion into monomeric aromatic compounds
Open Access Paper

A kinetic model for Pd-based hydrogenation of acetylene-rich streams typical of post-plasma applications

The advancement of electrified chemical processes prompts interest in novel technologies such as plasma-based methane (CH4) conversion into high-demand chemicals.

Graphical abstract: A kinetic model for Pd-based hydrogenation of acetylene-rich streams typical of post-plasma applications
Open Access Paper

Microwave-assisted synthesis of a sulfonated carbon-based catalyst for efficient esterification of oleic acid into biodiesel

A sulfonated carbon catalyst was rapidly synthesized via a one-pot microwave method, achieving >90% biodiesel conversion under mild conditions.

Graphical abstract: Microwave-assisted synthesis of a sulfonated carbon-based catalyst for efficient esterification of oleic acid into biodiesel
From the themed collection: Celebrating Latin American Chemistry
Open Access Paper

Heterometallic Li/Zn, Li/Al and Li/In catalysts for rac-lactide ring-opening polymerisation: “ate” or “non-ate” pathways?

Heterometallic cooperativity can improve catalyst performance in lactide polymerisation, yet some heterocombinations do not cooperate. This work shows how the metal roles change with different heterocombinations, affecting polymerisation efficiency.

Graphical abstract: Heterometallic Li/Zn, Li/Al and Li/In catalysts for rac-lactide ring-opening polymerisation: “ate” or “non-ate” pathways?
Paper

Highly efficient catalytic conversion of 2,5-dimethylfuran and acrylic acid to para-xylene over MCM-22 zeolites

The MCM-22 zeolites were demonstrated to show superior catalytic performance in the Diels–Alder cycloaddition of 2,5-dimethylfuran and acrylic acid, and the active site was mainly from the easily accessible acid sites at the pocket structure.

Graphical abstract: Highly efficient catalytic conversion of 2,5-dimethylfuran and acrylic acid to para-xylene over MCM-22 zeolites
Open Access Paper

Correlating electronic properties of a nickel polymerisation catalyst with the branching density of a polyethylene

Electronic tuning of the para-R group of the Ni precatalyst allows a means to regulate the branching density and the Mw of the PE. The E1/2 value of the precatalyst has been used as a quantitative descriptor of this electronic effect.

Graphical abstract: Correlating electronic properties of a nickel polymerisation catalyst with the branching density of a polyethylene
Open Access Paper

Tuning oxidative propane dehydrogenation while co-converting CO2 over vanadium containing CHA zeolites

Propane oxidative dehydrogenation with CO2 is key for on-purpose propene production. V/CHA zeolites emerge as candidates. Insights into catalytic performance using box-and-whisker plots support data representation for catalyst design.

Graphical abstract: Tuning oxidative propane dehydrogenation while co-converting CO2 over vanadium containing CHA zeolites
Open Access Paper

Activation strategies for rice husk biochar: enhancing porosity and performance as a support for Pd catalysts in hydrogenation reactions

Different activation methods were applied to rice husk biochar from slow pyrolysis for use as sustainable catalyst support. Results show activation method greatly affects performance, with KOH activation yielding especially strong results.

Graphical abstract: Activation strategies for rice husk biochar: enhancing porosity and performance as a support for Pd catalysts in hydrogenation reactions
From the themed collection: Carbon for Catalysis
Open Access Paper

Modelling hydrogen peroxide adsorption on cerium dioxide: the effect of surface strain

Cerium oxide nanoparticles possess inherent strain, which facilitates the stabilization of various reactive oxygen species, such as hydrogen peroxide and its dissociation products, on their surfaces, thereby altering their surface activity.

Graphical abstract: Modelling hydrogen peroxide adsorption on cerium dioxide: the effect of surface strain
Paper

Electrooxidation of ethylene glycol coupled with hydrogen production on porous NiO/Ni@NF nanosheet electrocatalysts

Construction of NiO/Nix@NF nanosheets has been demonstrated to be an effective way to facilitate electrooxidation of ethylene glycol and hydrogen production.

Graphical abstract: Electrooxidation of ethylene glycol coupled with hydrogen production on porous NiO/Ni@NF nanosheet electrocatalysts
Open Access Paper

The effects of SO2 impurities on CO2 electroreduction on bare silver and SiO2 coated silver in different cell geometries

Electrochemical CO2 reduction presents an opportunity to transform waste flue gas with water and renewable electricity into chemicals or fuels.

Graphical abstract: The effects of SO2 impurities on CO2 electroreduction on bare silver and SiO2 coated silver in different cell geometries
Paper

Optimized Ru catalysts for the selective cleavage of CAr–OCH3 bonds in guaiacol under mild conditions

The structure sensitivity of γ-Al2O3 supported Ru catalysts with varying Ru particle sizes (0.6–7.5 nm) is utilized for the hydrodeoxygenation of lignin-derived guaiacol to cyclohexanol under relatively mild conditions of 190 °C and 5 bar H2.

Graphical abstract: Optimized Ru catalysts for the selective cleavage of CAr–OCH3 bonds in guaiacol under mild conditions
From the themed collection: Emerging Investigator Series
Open Access Paper

Photocatalytic norfloxacin degradation enabled by a dual S-scheme nanocellulose-based Ag2WO4/NiO/MoO3 tertiary heterojunction

The escalating presence of antibiotic contaminants, such as norfloxacin (NFX), in water resources poses a pressing environmental challenge, demanding the development of innovative and sustainable remediation technologies.

Graphical abstract: Photocatalytic norfloxacin degradation enabled by a dual S-scheme nanocellulose-based Ag2WO4/NiO/MoO3 tertiary heterojunction
Paper

Transition metal atoms embedded in monolayer C13N3 as OER/ORR bifunctional electrocatalysts

Developing bifunctional electrocatalysts for efficiently catalyzing the oxygen evolution/reduction reaction (OER/ORR) is essential for water electrolysis and other processes.

Graphical abstract: Transition metal atoms embedded in monolayer C13N3 as OER/ORR bifunctional electrocatalysts
Open Access Paper

Genesys-Cat: automatic microkinetic model generation for heterogeneous catalysis with improved Bayesian optimization

Genesys-Cat facilitates automated microkinetic model development for catalytic reactions based on a rule-based reaction network generator and enhanced Bayesian optimization.

Graphical abstract: Genesys-Cat: automatic microkinetic model generation for heterogeneous catalysis with improved Bayesian optimization
22 items

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Showcasing some of the most cited and most accessed articles published in Catalysis Science & Technology during 2025.

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