Issue 4, 2022

Chirality inversion in hydrogen-bonded rhodanine–oligothiophene derivatives by solvent and temperature

Abstract

The self-assembly process of hydrogen-bonded quinquethiophenerhodanine derivatives has been explored as a function of solvent and temperature. We demonstrate the divergent supramolecular chirality emerging from a single enantiomer by subtle changes in solvent mixtures and sample preparation protocol. Spectroscopic techniques have proved the presence of aggregates where H-bonding interactions play a crucial role.

Graphical abstract: Chirality inversion in hydrogen-bonded rhodanine–oligothiophene derivatives by solvent and temperature

Supplementary files

Article information

Article type
Communication
Submitted
21 10 2021
Accepted
07 12 2021
First published
08 12 2021

Chem. Commun., 2022,58, 529-532

Chirality inversion in hydrogen-bonded rhodanine–oligothiophene derivatives by solvent and temperature

A. M. Garcia and A. Ruiz-Carretero, Chem. Commun., 2022, 58, 529 DOI: 10.1039/D1CC05945A

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