Issue 4, 2022

Electron transitions in a Ce(iii)-catecholate metal–organic framework

Abstract

A rare three-dimensional catecholate-based Ce(III) metal–organic framework (MOF), denoted as NU-1701, has been synthesized and crystallographically characterized. Density functional theory calculations highlight various possible electronic transitions that may present in NU-1701. These transitions are competitive and indicate increased lanthanide character of Ce(III).

Graphical abstract: Electron transitions in a Ce(iii)-catecholate metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
15 Nov 2021
Accepted
08 Dec 2021
First published
15 Dec 2021

Chem. Commun., 2022,58, 525-528

Electron transitions in a Ce(III)-catecholate metal–organic framework

J. G. Knapp, D. Ray, P. B. Calio, M. C. Wasson, T. R. Scott, L. Gagliardi and O. K. Farha, Chem. Commun., 2022, 58, 525 DOI: 10.1039/D1CC06440A

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