Ab initio molecular orbital calculations on the reactions of the trifluoromethyl radical, which can be easily released from perfluoroalkylamine by dissociation of C–N bonds, with hydroxyl or hydrogen radicals revealed the fire extinguishing mechanism of non-bromine-containing halon replacements such as perfluoroalkylamines.
H. Fukaya, T. Ono and T. Abe, J. Chem. Soc., Chem. Commun., 1995, 1207 DOI: 10.1039/C39950001207
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