In the presence of water the unsaturated iridium(III) metallacyclopentadiene halide complex [graphic omitted]R)(PPh3)2Cl (1, R = CO2Me) undergoes reaction with prop-2-ynyl alcohol, or methyl prop-2-ynyl ether at room temperature to give the η1-ethenyl complex [graphic omitted]R)(PPh3)2(CO)(η1-CH![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CH2)(3, R = CO2Me) in quantitative yield.
J. M. O'Connor and K. Hiibner, J. Chem. Soc., Chem. Commun., 1995, 1209 DOI: 10.1039/C39950001209
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