Hydrogenation of cage-opened C60 derivatives mediated by frustrated Lewis pairs

Yoshifumi Hashikawa; Yasujiro Murata

doi:10.1039/D1OB02316K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Hydrogenation of cage-opened C₆₀ derivatives mediated by frustrated Lewis pairs†

Yoshifumi Hashikawa

^a and Yasujiro Murata

*^a

Author affiliations

* Corresponding authors

^a Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan

Abstract

Multiply-carbonylated fullerene derivatives were found to work as one component in frustrated Lewis pairs which caused an Si–H bond activation in the presence of B(C₆F₅)₃, leading to the carbonyl hydrogenation in up to 99% yield. The Lewis acid-mediated reductive arylation also took place to furnish a corresponding ketal derivative.

This article is part of the themed collection: Supramolecular chemistry in OBC

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D1OB02316K
Article type: Communication
Submitted: 04 déc. 2021
Accepted: 10 janv. 2022
First published: 14 janv. 2022

Download Citation

Org. Biomol. Chem., 2022,20, 1000-1003

Permissions

Request permissions

Hydrogenation of cage-opened C₆₀ derivatives mediated by frustrated Lewis pairs

Y. Hashikawa and Y. Murata, Org. Biomol. Chem., 2022, 20, 1000 DOI: 10.1039/D1OB02316K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Organic & Biomolecular Chemistry