Issue 5, 2022
From the journal:

Organic & Biomolecular Chemistry

Alkynedicobalt mediated vinylogous Nazarov reactions†

Somaiah Almubayedh ORCID logo a  and  James R. Green ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, Canada
E-mail: jgreen@uwindsor.ca

Abstract

The SnCl4 mediated reactions of cross conjugated aryl enynone-Co2(CO)6 and dienynone-Co2(CO)6 complexes afford benzocycloheptynone complexes or cycloheptenynone complexes in a thermal vinylogous Nazarov process. The rate of ring closure is strongly dependent on the ketone α-substituent.

Graphical abstract: Alkynedicobalt mediated vinylogous Nazarov reactions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D1OB02256C
Article type
Communication
Submitted
18 Nov 2021
Accepted
17 Dec 2021
First published
22 Dec 2021

Org. Biomol. Chem., 2022,20, 1004-1007

Permissions

Request permissions

Alkynedicobalt mediated vinylogous Nazarov reactions

S. Almubayedh and J. R. Green, Org. Biomol. Chem., 2022, 20, 1004 DOI: 10.1039/D1OB02256C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements