Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(iii) phosphoramidate complex†
Marcus W.
Drover, 
a
Laurel L.
Schafer
*a
and
a
Laurel L.
Schafer
*a
and
Abstract
The reaction of a Cp*Ir(III) phosphoramidate complex with secondary amines gives amine, imine-bound Cp*Ir(III) hydride complexes resulting from amine dehydrogenation. These well-characterized species could serve as models of relevant intermediates that have been proposed in catalytic amine dehydrogenation using related N,O-chelated Cp*Ir(III) pyridonate complexes.
- This article is part of the themed collections: Celebrating Excellence in Research: 100 Women of Chemistry and CSC100: Celebrating Canadian Chemistry
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