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Issue 26, 2017
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The first ReI organometallic complex with an organoimido-polyoxometalate ligand

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Abstract

The spectroscopic, electrochemical and photophysical properties of the first ReI organometallic organoimido-polyoxometalate complex [n-Bu4N][Mo6O18NC6H4-CH2-N3C2H2-Re-phen(CO)3] compared with all fragments are reported. The UV–Vis spectra are analysed using experimental and theoretical tools. In contrast to the reported studies in the literature, our results show that a new more intense band is present in the spectra of the hybrid ligand obscuring the intra-polyanion charge transfer. The electrochemical results show that the strong acceptor character of the polyoxometalate fragment is quenched by the condensation of the phenyl-triazole molecule.

Graphical abstract: The first ReI organometallic complex with an organoimido-polyoxometalate ligand

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Supplementary files

Article information


Submitted
05 May 2017
Accepted
08 Jun 2017
First published
08 Jun 2017

Dalton Trans., 2017,46, 8611-8620
Article type
Paper

The first ReI organometallic complex with an organoimido-polyoxometalate ligand

P. Hermosilla-Ibáñez, K. Wrighton-Araneda, G. Prado, V. Paredes-García, N. Pizarro, A. Vega and D. Venegas-Yazigi, Dalton Trans., 2017, 46, 8611
DOI: 10.1039/C7DT01633F

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