Issue 5, 2016
From the journal:

Dalton Transactions

Iron-catalyzed cross coupling of P–H/C–O bonds: efficient synthesis of α-alkoxyphosphorus compounds†

Xue Li,a   Tieqiao Chen,*a   Yuta Sagab  and  Li-Biao Han*c  

* Corresponding authors

a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
E-mail: chentieqiao@hnu.edu.cn

b Katayama Chemical Industries Co., Ltd, 26-22, 3-Chome, Higasinaniwa-cho, Amagasaki, Hyogo 660-0892, Japan

c National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan
E-mail: libiao-han@aist.go.jp

Abstract

An efficient P–C bond-formation through iron-catalyzed cross coupling of P–H/C–O bonds is developed for the first time. This reaction proceeds efficiently to produce the corresponding valuable α-alkoxyphosphorus compounds under mild conditions with a wide generality.

Graphical abstract: Iron-catalyzed cross coupling of P–H/C–O bonds: efficient synthesis of α-alkoxyphosphorus compounds

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Article information

DOI
https://doi.org/10.1039/C5DT02454D
Article type
Communication
Submitted
29 juin 2015
Accepted
19 août 2015
First published
19 août 2015

Dalton Trans., 2016,45, 1877-1880

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Iron-catalyzed cross coupling of P–H/C–O bonds: efficient synthesis of α-alkoxyphosphorus compounds

X. Li, T. Chen, Y. Saga and L. Han, Dalton Trans., 2016, 45, 1877 DOI: 10.1039/C5DT02454D

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