Issue 21, 2011

Linking [FeIII3] triangles with “double-headed”phenolic oximes

Abstract

The use of “double-headed” phenolic oximes produces a trigonal antiprismatic [FeIII3]2 cluster with an “internal cavity” filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.

Graphical abstract: Linking [FeIII3] triangles with “double-headed”phenolic oximes

Supplementary files

Article information

Article type
Communication
Submitted
25 févr. 2011
Accepted
24 mars 2011
First published
11 avr. 2011

Chem. Commun., 2011,47, 6018-6020

Linking [FeIII3] triangles with “double-headed”phenolic oximes

K. Mason, J. Chang, E. Garlatti, A. Prescimone, S. Yoshii, H. Nojiri, J. Schnack, P. A. Tasker, S. Carretta and E. K. Brechin, Chem. Commun., 2011, 47, 6018 DOI: 10.1039/C1CC11146A

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