RSC Advances  

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Redox articles published in the last 6 months

28 items - Showing page 1 of 2
Open Access Paper

Ag/AgBr-oxygen enriched g-C3N4 for efficient photocatalytic degradation of trimethylamine

In this study, Ag/AgBr–O-gCN samples with ternary Z-type heterojunctions were prepared by in situ photoreduction using water as the reducing agent for generating Ag/AgBr active species and oxygen doping.

Graphical abstract: Ag/AgBr-oxygen enriched g-C3N4 for efficient photocatalytic degradation of trimethylamine
Open Access Paper

High performance electrochemical CO2 reduction over Pd decorated cobalt containing nitrogen doped carbon

Efficient electrocatalytic CO2 reduction reaction (eCO2RR) to various products, such as carbon monoxide (CO), is crucial for mitigating greenhouse gas emissions and enabling renewable energy storage.

Graphical abstract: High performance electrochemical CO2 reduction over Pd decorated cobalt containing nitrogen doped carbon
Open Access Paper

Investigation into the impact of CeO2 morphology regulation on the oxidation process of dichloromethane

Four distinct CeO2 catalysts featuring varied morphologies (nanorods, nanocubes, nanoparticles, and nano spindle-shaped) were synthesized through a hydrothermal process and subsequently employed in the oxidation of dichloromethane (DCM).

Graphical abstract: Investigation into the impact of CeO2 morphology regulation on the oxidation process of dichloromethane
Open Access Paper

Boosting oxygen evolution reaction rates with mesoporous Fe-doped MoCo-phosphide nanosheets

In this study, we explord the catalytic activity of MoCoFephosphide nanosheets as highly active and stable catalysts for OER. Electrochemical analysis exhibits a low overpotential of 250 mV in (1 M KOH), achieving a current density of 10 mA cm−2 with a low Tafel slope of 43.38 mV dec−2.

Graphical abstract: Boosting oxygen evolution reaction rates with mesoporous Fe-doped MoCo-phosphide nanosheets
Open Access Paper

Selective electrooxidation of 5-hydroxymethylfurfural at low working potentials promoted by 3D hierarchical Cu(OH)2@Ni3Co1-layered double hydroxide architecture with oxygen vacancies

An effective and stable catalyst with 3D hierarchical architecture was synthesized by electrodepositing Ni3Co1-LDH nanosheets on copper foam-supported Cu(OH)2 nanorods. The catalyst can be used to prepare FDCA continuously, showing great potential in the electrochemical conversion of biomass.

Graphical abstract: Selective electrooxidation of 5-hydroxymethylfurfural at low working potentials promoted by 3D hierarchical Cu(OH)2@Ni3Co1-layered double hydroxide architecture with oxygen vacancies
Open Access Expression of Concern

Expression of concern: Highly porous copper-supported magnetic nanocatalysts: made of volcanic pumice textured by cellulose and applied for the reduction of nitrobenzene derivatives

Open Access Paper

Modified photoanode by in situ growth of covalent organic frameworks on BiVO4 for oxygen evolution reaction

COF-Azo and COF-Ben are grown in situ on a modified BiVO4 photoanode, which exhibit better catalytic performance in OER.

Graphical abstract: Modified photoanode by in situ growth of covalent organic frameworks on BiVO4 for oxygen evolution reaction
Open Access Paper

Functionalisation of alkali-resistant nanoporous glass via Au nanoparticle decoration using alkaline impregnation: catalytic activity for CO removal

This study demonstrates that a nanoporous glass can be decorated with Au nanoparticles using an alkali impregnation method. The resulting composite exhibits high catalytic activity in CO oxidation.

Graphical abstract: Functionalisation of alkali-resistant nanoporous glass via Au nanoparticle decoration using alkaline impregnation: catalytic activity for CO removal
Open Access Paper

The discrepancy of NH3 oxidation mechanism between SAPO-34 and Cu/SAPO-34

The difference of NH3 oxidation mechanism over SAPO-34 and Cu–SAPO-34 was studied.

Graphical abstract: The discrepancy of NH3 oxidation mechanism between SAPO-34 and Cu/SAPO-34
Open Access Paper

Magnetic MnFe2O4/ZIF-67 nanocomposites with high activation of peroxymonosulfate for the degradation of tetracycline hydrochloride in wastewater

Schematic illustration of the reaction mechanisms in the MnFe2O4/ZIF-67/PMS system.

Graphical abstract: Magnetic MnFe2O4/ZIF-67 nanocomposites with high activation of peroxymonosulfate for the degradation of tetracycline hydrochloride in wastewater
Open Access Paper

A comparative study of α-Ni(OH)2 and Ni nanoparticle supported ZIF-8@reduced graphene oxide-derived nitrogen doped carbon for electrocatalytic ethanol oxidation

Ethanol electrooxidation is an important reaction for fuel cells, however, the major obstacle to ethanol electrocatalysis is the splitting of the carbon–carbon bond to CO2 at lower overpotentials.

Graphical abstract: A comparative study of α-Ni(OH)2 and Ni nanoparticle supported ZIF-8@reduced graphene oxide-derived nitrogen doped carbon for electrocatalytic ethanol oxidation
Open Access Paper

Sustainable production of catechol derivatives from waste tung nutshell C/G-type lignin via heterogeneous Cu–NC catalytic oxidation

A heterogeneous oxidative process is reported towards sustainable production of valuable catechol derivatives from the depolymerization of Tung nutshell C/G lignin by Cu–NC catalytic process. The CuO and Cu2O might be active species for oxidation.

Graphical abstract: Sustainable production of catechol derivatives from waste tung nutshell C/G-type lignin via heterogeneous Cu–NC catalytic oxidation
From the themed collection: Chemistry in Biorefineries
Open Access Paper

Microalgae-derived Co3O4 nanomaterials for catalytic CO oxidation

Sustainable nanosized Co3O4 catalysts, derived from microalgae extracts and post-synthesis treatments, were employed for oxidative CO removal.

Graphical abstract: Microalgae-derived Co3O4 nanomaterials for catalytic CO oxidation
Open Access Paper

Manganese-oxide-supported gold catalyst derived from metal–organic frameworks for trace PCl3 oxidation in an organic system

An Au/Mn3O4 catalyst derived from Mn-MIL-100 exhibits a high catalytic performance for trace PCl3 oxidation with oxygen in an organic system through an MvK-style supply of oxygen.

Graphical abstract: Manganese-oxide-supported gold catalyst derived from metal–organic frameworks for trace PCl3 oxidation in an organic system
Open Access Review Article

Recent advances in single-atom alloys: preparation methods and applications in heterogeneous catalysis

Single-atom alloys (SAAs) are a different type of alloy where a guest metal, usually a noble metal (e.g., Pt, Pd, and Ru), is atomically dispersed on a relatively more inert (e.g., Ag and Cu) host metal.

Graphical abstract: Recent advances in single-atom alloys: preparation methods and applications in heterogeneous catalysis
From the themed collection: 2024 Reviews in RSC Advances
Open Access Paper

Efficient catalytic activity of NiO and CeO2 films in benzoic acid removal using ozone

(1) CeO2 films increases TOC removal in comparison with NiO films in benzoic acid elimination. (2) Both CeO2 and NiO films can be easily recovered from the ozonation system.

Graphical abstract: Efficient catalytic activity of NiO and CeO2 films in benzoic acid removal using ozone
Open Access Paper

Self-assembled copper nanoclusters used to mimic peroxidase for glucose detection

A sensing system for glucose derived from a self-assembled copper nanoclusters-based nano-enzyme and glucose oxidase.

Graphical abstract: Self-assembled copper nanoclusters used to mimic peroxidase for glucose detection
Open Access Paper

Catalytic hydrolysis of carbonyl sulfide in blast furnace gas over Sm-Ce-Ox@ZrO2 catalyst

Carbonyl sulfur (COS) is a prominent organic sulfur pollutant commonly found in the by-product gas generated by the steel industry.

Graphical abstract: Catalytic hydrolysis of carbonyl sulfide in blast furnace gas over Sm-Ce-Ox@ZrO2 catalyst
Open Access Paper

Ni–Fe bimetallic catalysts with high dispersion supported by SBA-15 evaluated for the selective oxidation of benzyl alcohol to benzaldehyde

A wetness impregnation method was used to impregnate the substrate with a substantial quantity of oleic acid together with a metal precursor, leading to significantly dispersed Ni–Fe bimetallic catalysts based on mesoporous SBA-15.

Graphical abstract: Ni–Fe bimetallic catalysts with high dispersion supported by SBA-15 evaluated for the selective oxidation of benzyl alcohol to benzaldehyde
Open Access Retraction

Retraction: Robust, highly active, and stable supported Co(II) nanoparticles on magnetic cellulose nanofiber-functionalized for the multi-component reactions of piperidines and alcohol oxidation

Open Access Paper

A novel concept and design for highly efficient photoelectrocatalytic materials with high performance, stability, and charge transport properties: development of an innovative next-generation green technology

In semiconductors, generating charges via catalysis is a highly challenging task and characteristic of heterojunction photoanodes.

Graphical abstract: A novel concept and design for highly efficient photoelectrocatalytic materials with high performance, stability, and charge transport properties: development of an innovative next-generation green technology
Open Access Paper

Component-controlled synthesis of PdxSny nanocrystals on carbon nanotubes as advanced electrocatalysts for oxygen reduction reaction

A series of PdxSny nanocrystals loaded on carbon nanotubes (CNTs) nanohybrids have been synthesized. Due to the proper alloy constituent and the strong interplay between the two components, the resultant Pd3Sn/CNTs exhibit excellent ORR activity.

Graphical abstract: Component-controlled synthesis of PdxSny nanocrystals on carbon nanotubes as advanced electrocatalysts for oxygen reduction reaction
Open Access Paper

Anderson-type polyoxometalate-based metal–organic framework as an efficient heterogeneous catalyst for selective oxidation of benzylic C–H bonds

Self-assembly of Anderson-type polyoxometalate {CrMo6} with Cu2+ and bistriazole L affords POMOF-1 that works cooperatively with NPHI for oxidative transformation of benzylic C–H bonds into carbonyl compounds.

Graphical abstract: Anderson-type polyoxometalate-based metal–organic framework as an efficient heterogeneous catalyst for selective oxidation of benzylic C–H bonds
Open Access Paper

Advancing nitrate reduction to ammonia: insights into mechanism, activity control, and catalyst design over Pt nanoparticle-based ZrO2

Tailoring nitrate reduction: unraveling mechanisms, modulating activity, and designing Pt nanoparticle-based ZrO2 catalysts for enhanced ammonia production.

Graphical abstract: Advancing nitrate reduction to ammonia: insights into mechanism, activity control, and catalyst design over Pt nanoparticle-based ZrO2
Open Access Paper

Exploring the source of ammonia generation in electrochemical nitrogen reduction using niobium nitride

A NbN catalyst is prepared by the urea-glass route for NRR, with the produced NH3 originating from the leaching of NbN, rather than from an electrochemical reaction.

Graphical abstract: Exploring the source of ammonia generation in electrochemical nitrogen reduction using niobium nitride
28 items - Showing page 1 of 2

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