Themed collection 2023 Frontier and Perspective articles

78 items - Showing page 1 of 2
Perspective

Systematics of stable copper and silver clusters protected by small bite chelating bidentate sulfur and selenium ligands related to their polyhedral cavities: analogies to aliphatic compounds and three-dimensional spherical aromatic systems

Silver clusters composed exclusively of fused tetrahedra are analogous to simple saturated organic compounds. Copper clusters with central cuboctahedra and silver clusters with central icosahedra having interstitial metal atoms provide examples of metal superatoms.

Graphical abstract: Systematics of stable copper and silver clusters protected by small bite chelating bidentate sulfur and selenium ligands related to their polyhedral cavities: analogies to aliphatic compounds and three-dimensional spherical aromatic systems
From the themed collection: 2024 Frontier and Perspective articles
Open Access Perspective

Chemical Chartographisis: a contemporary perspective in molecular design and synthesis

We introduce a contemporary perspective in molecular design and synthesis, named "Chemical Chartographisis".

Graphical abstract: Chemical Chartographisis: a contemporary perspective in molecular design and synthesis
Perspective

Recent advances and prospects of metal–organic frameworks in cancer therapies

This paper presents the latest applications of MOFs in chemodynamic therapy (CDT), sonodynamic therapy (SDT), photodynamic therapy (PDT), photothermal therapy (PTT), immunotherapy (IT), and combination therapy for breast cancer.

Graphical abstract: Recent advances and prospects of metal–organic frameworks in cancer therapies
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Thiol and thioether-based metal–organic frameworks: synthesis, structure, and multifaceted applications

Overview of thiol and thioether-based metal–organic frameworks.

Graphical abstract: Thiol and thioether-based metal–organic frameworks: synthesis, structure, and multifaceted applications
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Decoding the puzzle: recent breakthroughs in understanding degradation mechanisms of Li-ion batteries

This review examines Li-ion battery degradation, with a focus on the cathode-electrolyte interphase (CEI), modification, modeling, and novel characterization tools for improved battery performance.

Graphical abstract: Decoding the puzzle: recent breakthroughs in understanding degradation mechanisms of Li-ion batteries
From the themed collection: Dalton Transactions HOT Articles
Perspective

Advances in the research of carbon electrodes for perovskite solar cells

Perovskite solar cells (PSCs) were first proposed in 2009.

Graphical abstract: Advances in the research of carbon electrodes for perovskite solar cells
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Recent advances in the nanoarchitectonics of metal–organic frameworks for light-activated tumor therapy

The application of nMOFs to antitumor therapy, including drug delivery strategies, photodynamic therapy (PDT), photothermal therapy (PTT), and combination therapy, is presented.

Graphical abstract: Recent advances in the nanoarchitectonics of metal–organic frameworks for light-activated tumor therapy
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Electron transfer catalysis mediated by 3d complexes of redox non-innocent ligands possessing an azo function: a perspective

The catalytic aspects of metal complexes of redox non-innocent azo ligands in achieving important and useful chemicals by a hassle-free and economical technique have been presented with in-depth mechanistic explications.

Graphical abstract: Electron transfer catalysis mediated by 3d complexes of redox non-innocent ligands possessing an azo function: a perspective
From the themed collection: 2023 Frontier and Perspective articles
Open Access Perspective

Elucidation of the electronic structures of thiolate-protected gold nanoclusters by electrochemical measurements

Electrochemical measurements can elucidate the electronic structures of metal nanoclusters and give deep insight into the electronic structure between the molecule and the metal.

Graphical abstract: Elucidation of the electronic structures of thiolate-protected gold nanoclusters by electrochemical measurements
From the themed collection: New Talent: Asia Pacific
Perspective

Copper trafficking systems in cells: insights into coordination chemistry and toxicity

This review describes the coordination chemistry of a copper trafficking system and the toxicity mechanisms arising from impaired copper homeostasis.

Graphical abstract: Copper trafficking systems in cells: insights into coordination chemistry and toxicity
From the themed collection: New Talent: Asia Pacific
Perspective

A roadmap to enhance gas permselectivity in metal–organic framework-based mixed-matrix membranes

Metal–organic framework-based mixed-matrix membranes design strategies have been discussed with a focus on the challanges related to membrane fabrication, interface design, and gas diffusion pathways.

Graphical abstract: A roadmap to enhance gas permselectivity in metal–organic framework-based mixed-matrix membranes
From the themed collection: New Talent: Asia Pacific
Perspective

Stepwise construction of multi-component metal–organic frameworks

This review outlines stepwise synthesis strategies for multi-component metal–organic frameworks, emphasizing their distinct advantages for gas adsorption, water remediation, heterogeneous catalysis, luminescence, and chemical sensing.

Graphical abstract: Stepwise construction of multi-component metal–organic frameworks
From the themed collection: New Talent: Asia Pacific
Perspective

Recent advances on the construction of long-wavelength emissive supramolecular coordination complexes for photo-diagnosis and therapy

Schematic diagram of the diagnosis and treatment of NIR-II emissive SCCs.

Graphical abstract: Recent advances on the construction of long-wavelength emissive supramolecular coordination complexes for photo-diagnosis and therapy
From the themed collection: New Talent: Asia Pacific
Perspective

Recent advances in porous molecular cages for photocatalytic organic conversions

Photocatalytic organic conversion is considered an efficient, environmentally friendly, and energy-saving strategy for organic synthesis. Porous molecular cages exhibit significant potential in the realm of photocatalytic organic conversion.

Graphical abstract: Recent advances in porous molecular cages for photocatalytic organic conversions
From the themed collection: New Talent: Asia Pacific
Perspective

Emerging enzyme-based nanocomposites for catalytic biomedicine

In this review, we discuss key aspects of enzyme-based catalytic biomedicine. We also highlighted the field's challenges and provided a prospect for the rational design and application of the enzyme-based nanocomposites.

Graphical abstract: Emerging enzyme-based nanocomposites for catalytic biomedicine
From the themed collection: New Talent: Asia Pacific
Perspective

Olefin-linked covalent organic frameworks: synthesis and applications

In this review, we highlight the design principles, synthesis strategies, and impactful applications of olefin-linked covalent organic frameworks. Besides, the challenges and perspectives in this research field have been provided.

Graphical abstract: Olefin-linked covalent organic frameworks: synthesis and applications
From the themed collection: New Talent: Asia Pacific
Perspective

Insights into the self-assembly of giant polyoxomolybdates from building blocks to supramolecular structures

Gaining an in-depth understanding of the self-assembly mechanism of giant polyoxomolybdates is the key for the designable clusters synthesis. This will in turn promote related supramolecular self-assembly and application research.

Graphical abstract: Insights into the self-assembly of giant polyoxomolybdates from building blocks to supramolecular structures
From the themed collection: New Talent: Asia Pacific
Perspective

Fluorescent and chromogenic organic probes to detect group 10 metal ions: design strategies and sensing applications

This study highlights various fluorescent and colorimetric organic sensors for detection of group 10 metal ions. Existing receptor design issues, challenges and promising development prospects are presented.

Graphical abstract: Fluorescent and chromogenic organic probes to detect group 10 metal ions: design strategies and sensing applications
From the themed collection: 2023 Frontier and Perspective articles
Open Access Perspective

Cooperation towards nobility: equipping first-row transition metals with an aluminium sword

This perspective offers an overview of the state-of-the-art regarding heterobimetallic complexes featuring a bond between aluminium and a first-row transition metal. Their synthesis, reactivity and prospective catalytic applications are discussed.

Graphical abstract: Cooperation towards nobility: equipping first-row transition metals with an aluminium sword
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Room-temperature chemiresistive ammonia sensors based on 2D MXenes and their hybrids: recent developments and future prospects

This article offers a thorough overview of current advancements, potential applications and future improvement approaches for room-temperature ammonia sensors based on 2D MXene-based gas sensing technology.

Graphical abstract: Room-temperature chemiresistive ammonia sensors based on 2D MXenes and their hybrids: recent developments and future prospects
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Recent advances of H-intercalated Pd-based nanocatalysts for electrocatalytic reactions

A comprehensive review in terms of the engineering and applications of Pd hydrides is summarized.

Graphical abstract: Recent advances of H-intercalated Pd-based nanocatalysts for electrocatalytic reactions
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Recent progress in trivalent europium (Eu3+)-based inorganic phosphors for solid-state lighting: an overview

Narrow band red-emitting phosphors are significant constituents but still a bottleneck for next-generation smart displays and high-performance lighting (solid-state lighting based white light-emitting diodes (WLEDs)) technology.

Graphical abstract: Recent progress in trivalent europium (Eu3+)-based inorganic phosphors for solid-state lighting: an overview
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Recent advances in oxidative catalytic applications of polyoxovanadate-based inorganic–organic hybrids

The oxidative catalytic applications of polyoxovanadate-based inorganic–organic hybrid (POVH) materials have been summarized for the transformation of organic compounds in this perspective article.

Graphical abstract: Recent advances in oxidative catalytic applications of polyoxovanadate-based inorganic–organic hybrids
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Management of typical VOCs in air with adsorbents: status and challenges

The primary adsorption materials including activated carbon, zeolites and metal organic frameworks, and their modification methods are reviewed. The key factors controlling VOCs adsorption and the removal mechanisms are discussed.

Graphical abstract: Management of typical VOCs in air with adsorbents: status and challenges
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Recent progress in the stabilization of low band-gap black-phase iodide perovskite solar cells

This perspective presents a summary of diverse approaches used to stabilize the black phase of iodide perovskites, along with their practical implementation in photovoltaic devices.

Graphical abstract: Recent progress in the stabilization of low band-gap black-phase iodide perovskite solar cells
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Engineering metallenes for boosting electrocatalytic biomass-oxidation-assisted hydrogen evolution reaction

A systematic review regarding the engineering of metallenes toward biomass-oxidation-assisted hydrogen evolution is presented.

Graphical abstract: Engineering metallenes for boosting electrocatalytic biomass-oxidation-assisted hydrogen evolution reaction
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Interactions of Mn complexes with DNA: the relevance of therapeutic applications towards cancer treatment

Design of manganese-based drug conjugates for selective targeting of cancer cells will be a major breakthrough in the field of cancer research.

Graphical abstract: Interactions of Mn complexes with DNA: the relevance of therapeutic applications towards cancer treatment
From the themed collection: 2023 Frontier and Perspective articles
Open Access Perspective

Atmospheric-pressure atomic layer deposition: recent applications and new emerging applications in high-porosity/3D materials

Atmospheric-pressure atomic layer deposition (ALD) is an upcoming technology poised to revolutionize the commercial production of large-area substrates and unlock new applications in high-porosity/3D materials.

Graphical abstract: Atmospheric-pressure atomic layer deposition: recent applications and new emerging applications in high-porosity/3D materials
From the themed collection: 2023 Frontier and Perspective articles
Perspective

How does chemistry contribute to circular economy in nuclear energy systems to make them more sustainable and ecological?

Nuclear fuel recycling basically follows a concept of circular economy, while it actually suffers from several problems. This perspective discusses how chemistry works for resolving them as well as what task academic scientists should take on.

Graphical abstract: How does chemistry contribute to circular economy in nuclear energy systems to make them more sustainable and ecological?
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Recent trends in phenol synthesis by photocatalytic oxidation of benzene

This perspective introduces current homogeneous and heterogeneous photocatalytic systems for phenol synthesis and outlines several strategies to enhance phenol selectivity.

Graphical abstract: Recent trends in phenol synthesis by photocatalytic oxidation of benzene
From the themed collection: 2023 Frontier and Perspective articles
Open Access Perspective

Amidoboronates: bringing together the synthesis of BN-heterocycles via a reductive coupling and dynamic covalent chemistry

This Perspective discusses the synthesis of amidoboronates and the dynamic covalent chemistry of the C–C, B–N and B–O bonds.

Graphical abstract: Amidoboronates: bringing together the synthesis of BN-heterocycles via a reductive coupling and dynamic covalent chemistry
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Stabilization of transition metal heterojunctions inside porous materials for high-performance catalysis

The developed strategies for stabilizing heterojunctions in different porous materials with improved synergistic effect, catalytic properties and stability are summarized and discussed.

Graphical abstract: Stabilization of transition metal heterojunctions inside porous materials for high-performance catalysis
From the themed collection: 2023 Frontier and Perspective articles
Perspective

The enhanced sensing properties of MOS-based resistive gas sensors by Au functionalization: a review

Au-functionalized MOS-based gas sensing materials.

Graphical abstract: The enhanced sensing properties of MOS-based resistive gas sensors by Au functionalization: a review
From the themed collection: 2023 Frontier and Perspective articles
Open Access Perspective

The quest for organo-alkali metal monomers: unscrambling the structure–reactivity relationship

This perspective explores the strategies that have been employed to isolate low aggregate and, in particular, monomeric complexes of the most common alkali metal alkyls and the relationship between aggregation, structure and reactivity.

Graphical abstract: The quest for organo-alkali metal monomers: unscrambling the structure–reactivity relationship
From the themed collection: 2023 Frontier and Perspective articles
Open Access Perspective

Oligozwitterions in coordination polymers and frameworks – a structural view

Uranyl ion cluster formation about a trizwitterion.

Graphical abstract: Oligozwitterions in coordination polymers and frameworks – a structural view
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Engineering of metal–organic frameworks (MOFs) for thermometry

The construction of luminescent MOF and its thermometry application.

Graphical abstract: Engineering of metal–organic frameworks (MOFs) for thermometry
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Progress and prospects of dealloying methods for energy-conversion electrocatalysis

Developing hydrogen production and utilization technologies is a promising way to achieve large-scale applications of renewable energy.

Graphical abstract: Progress and prospects of dealloying methods for energy-conversion electrocatalysis
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Transition metal complexes as self-activating chemical nucleases: proficient DNA cleavage without any exogenous redox agents

This perspective presents DNA cleavage via self-activation based on transition metal complexes employing copper, zinc and iron with their mechanistic investigation.

Graphical abstract: Transition metal complexes as self-activating chemical nucleases: proficient DNA cleavage without any exogenous redox agents
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Noncovalent tailoring of coordination complexes by resorcin[4]arene-based supramolecular hosts

Resorcin[4]arene-based molecular hosts can accommodate coordination complexes in a noncovalent manner to afford a unique host–guest systems, in which the chemical and physical properties of the guests are altered by encapsulation.

Graphical abstract: Noncovalent tailoring of coordination complexes by resorcin[4]arene-based supramolecular hosts
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Current status and prospects of MOFs in controlled delivery of Pt anticancer drugs

This review focuses on the application of platinum as an anticancer drug and the MOF materials loading platinum species; the prospect for its future development is also discussed.

Graphical abstract: Current status and prospects of MOFs in controlled delivery of Pt anticancer drugs
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Light hydrocarbon conversion to acrylonitrile and acetonitrile – a review

Acrylonitrile can be produced by (i) propylene using a bismuth molybdate catalyst and (ii) propane using a MoVTeNb mixed oxide catalyst. Acetonitrile can be synthesized either from C2 (ethylene and ethane) using Co/HZSM-5 or C1 (methane) using solid-state-pyrolysis-made GaN.

Graphical abstract: Light hydrocarbon conversion to acrylonitrile and acetonitrile – a review
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Addressing the gaps in homeostatic mechanisms of copper and copper dithiocarbamate complexes in cancer therapy: a shift from classical platinum-drug mechanisms

This review will focus on copper homeostasis in mammalian cells and on our current understanding of copper dysregulation in cancer and recent therapeutic breakthroughs using copper coordination complexes as anticancer drugs.

Graphical abstract: Addressing the gaps in homeostatic mechanisms of copper and copper dithiocarbamate complexes in cancer therapy: a shift from classical platinum-drug mechanisms
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Single-atom catalysts for catalytic benzene oxidation to phenol: recent progress and future perspectives

A comprehensive review with a particular focus on the significant roles of single atom sites and supports played in the substantial improvement of catalytic activity and selectivity towards the oxidation of benzene to phenol, is organized.

Graphical abstract: Single-atom catalysts for catalytic benzene oxidation to phenol: recent progress and future perspectives
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Sn(IV)-porphyrinoids for photodynamic anticancer and antimicrobial chemotherapy

Research on recently reported Sn(IV) porphyrinoids, including corroles, chlorins and N-confused porphyrins, focusing primarily on their photodynamic therapy (PDT) and photodynamic antimicrobial chemotherapy (PACT) activity properties is reviewed.

Graphical abstract: Sn(iv)-porphyrinoids for photodynamic anticancer and antimicrobial chemotherapy
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Polyoxotantalate chemistry: from synthetic strategies to structural diversity and applications

In this review, complexes including isopolyoxotantalates (IPOTas), organic–inorganic hybrid POTas, Ta/W mixed polyoxometalates and heteropolyoxotantalates (HPOTas) are introduced, in order to provide guidance for further exploration of intriguing POTas.

Graphical abstract: Polyoxotantalate chemistry: from synthetic strategies to structural diversity and applications
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Metal complexes with valuable biomolecules produced by Pseudomonas aeruginosa: a review of the coordination properties of pyocyanin, pyochelin and pyoverdines

A survey of the results achieved in the field of metal complexes with the natural products derived from Pseudomonas aeruginosa, namely pyocyanin, pyochelin, and pyoverdines, has been presented.

Graphical abstract: Metal complexes with valuable biomolecules produced by Pseudomonas aeruginosa: a review of the coordination properties of pyocyanin, pyochelin and pyoverdines
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Challenges and developments for the blue perovskite nanocrystal light-emitting diodes

The above figure is the thermal diagram of blue-light PeLEDs. From this diagram, it can be seen that the main research direction of blue-light LED is still efficiency and stability.

Graphical abstract: Challenges and developments for the blue perovskite nanocrystal light-emitting diodes
From the themed collection: 2023 Frontier and Perspective articles
Open Access Perspective

The effect of size, shape, coating and functionalization on nuclear relaxation properties in iron oxide core–shell nanoparticles: a brief review of the situation

Intrinsic parameters (magnetic core composition, size, shape, coating, and surface functionalization) and extrinsic parameters (solvent, magnetic field, and temperature) relevant for describing the nuclear relaxation in MNP core–shell nanoparticles are discussed.

Graphical abstract: The effect of size, shape, coating and functionalization on nuclear relaxation properties in iron oxide core–shell nanoparticles: a brief review of the situation
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Precision syntheses of molecular necklaces based on coordination interactions

Precision syntheses and potential applications of molecular necklaces based on coordination interactions.

Graphical abstract: Precision syntheses of molecular necklaces based on coordination interactions
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Strategies to mitigate the shuttle effect in room temperature sodium–sulfur batteries: improving cathode materials

Challenges and insights into high-performance sulfur electrodes for optimizing RT-Na/S batteries are discussed.

Graphical abstract: Strategies to mitigate the shuttle effect in room temperature sodium–sulfur batteries: improving cathode materials
From the themed collection: 2023 Frontier and Perspective articles
Open Access Perspective

Thermodynamics-based rules of thumb to evaluate the interaction of chelators and kinetically-labile metal ions in blood serum and plasma

Chelators and metal-ligand complexes can be stable or evolve in a biological system depending on thermodynamics and kinetics. For thermodynamic consideration the inclusion of all essential metals and metal-binding proteins is crucial.

Graphical abstract: Thermodynamics-based rules of thumb to evaluate the interaction of chelators and kinetically-labile metal ions in blood serum and plasma
From the themed collection: 2023 Frontier and Perspective articles
Open Access Perspective

Low-concentration CO2 capture using metal–organic frameworks – current status and future perspectives

Metal–organic frameworks with tailored pore sizes, structures and surface chemistry are promising sorbents for CO2 capture from low concentration CO2 sources.

Graphical abstract: Low-concentration CO2 capture using metal–organic frameworks – current status and future perspectives
From the themed collection: 2023 Frontier and Perspective articles
Open Access Perspective

Ferrocene-triazole conjugates: do we know why they are biologically active?

Using the click-chemistry approach, ferrocene has been linked to different organic structures of medicinal importance. Biologically active ferrocene-triazole conjugates, reported since 2012, are reviewed according to the type of their effect.

Graphical abstract: Ferrocene-triazole conjugates: do we know why they are biologically active?
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Four-membered C^N chelation in main-group organometallic chemistry

This perspective deals with the synthesis, structure and applications of main-group organometallic compounds containing four-membered C^N chelation.

Graphical abstract: Four-membered C^N chelation in main-group organometallic chemistry
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Aiming for dynamic behaviours of molecular metal chains

This paper focuses on dynamic behaviors of the Pd chains supported by linear tetraphosphines, and current development on fine-tuning of metal chains by introducing heterometal atoms, which are considered promising dynamic components.

Graphical abstract: Aiming for dynamic behaviours of molecular metal chains
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Nanostructured mixed transition metal oxide spinels for supercapacitor applications

Illustration of the transition metal oxides considered and their supercapacitor studies.

Graphical abstract: Nanostructured mixed transition metal oxide spinels for supercapacitor applications
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Pentagonal-bipyramidal 4d and 5d complexes with unquenched orbital angular momentum as a unique platform for advanced single-molecule magnets: current state and perspectives

Pentagonal-bipyramidal 4d3/5d3 complexes with unquenched orbital angular momentum are a unique platform for advanced single-molecule magnets due to anisotropic Ising-type exchange interactions, H = −Jxy(Sx5dSx3d + Sy5dSy3d) − JzSz5dSz3d.

Graphical abstract: Pentagonal-bipyramidal 4d and 5d complexes with unquenched orbital angular momentum as a unique platform for advanced single-molecule magnets: current state and perspectives
From the themed collection: 2023 Frontier and Perspective articles
Perspective

Introducing Te for boosting electrocatalytic reactions

Te-based nanocatalysts with multiple structures have been summarized for boosting electrocatalytic reactions.

Graphical abstract: Introducing Te for boosting electrocatalytic reactions
From the themed collection: 2023 Frontier and Perspective articles
Frontier

Anderson-type polyoxometalates for catalytic applications

Anderson-type polyoxometalates shown exceptional catalytic abilities. The unique combination of heteroatoms, organic grafting, and network immobilization gives a distinct advantage in catalytic performance.

Graphical abstract: Anderson-type polyoxometalates for catalytic applications
From the themed collection: Dalton Transactions HOT Articles
Open Access Frontier

Redox-active ligands – a viable route to reactive main group metal compounds

This article highlights studies that probe the oxidation/reduction of main group metal compounds possessing redox-active ligands and comments on the prospects for this relatively untapped avenue of research.

Graphical abstract: Redox-active ligands – a viable route to reactive main group metal compounds
From the themed collection: 2023 Frontier and Perspective articles
Frontier

Utility of all-pyrazole heteroscorpionates in f-element chemistry

A new generation of heteroscorpionates, known as all-pyrazole heteroscorpionates is dicussed as a platform for the generation of f-element compounds with robust structural diversity, desirable photoluminescent and molecular magnetism properties.

Graphical abstract: Utility of all-pyrazole heteroscorpionates in f-element chemistry
From the themed collection: 2023 Frontier and Perspective articles
Frontier

Coordination polymers: a promising candidate for photo-responsive electronic device application

This study emphasizes recent advances in the designing of coordination polymers for photo-responsive electronic device applications in regard to crystal engineering aspects and structure–property relationship.

Graphical abstract: Coordination polymers: a promising candidate for photo-responsive electronic device application
Frontier

Multivariate metal–organic frameworks generated through post-synthetic modification: impact and future directions

Reticular chemistry has proven to be invaluable over time, thanks to the structural versatility, and tailored porosity observed in structures like metal–organic frameworks (MOFs), covalent–organic frameworks (COFs), and metal–organic polyhedra (MOPs).

Graphical abstract: Multivariate metal–organic frameworks generated through post-synthetic modification: impact and future directions
From the themed collection: 2023 Frontier and Perspective articles
Frontier

Zeolite encapsulated organometallic complexes as model catalysts

Encapsulated complexes have potential as model heterogeneous catalysts for gap-phase reactions.

Graphical abstract: Zeolite encapsulated organometallic complexes as model catalysts
From the themed collection: 2023 Frontier and Perspective articles
Frontier

The fascinating story of axial ligand dependent spectroscopy and redox-properties in iron(II) phthalocyanines

Iron phthalocyanines play crucial fundamental and applied roles ranging from bulk colorants to components of advanced materials. In this mini-review, we discuss the influence of axial ligand identity on spectroscopic and redox properties of iron(II) phthalocyanines.

Graphical abstract: The fascinating story of axial ligand dependent spectroscopy and redox-properties in iron(ii) phthalocyanines
From the themed collection: 2023 Frontier and Perspective articles
Frontier

Cage-based sensors for circular dichroism analysis

Three-dimensional cages are promising platforms for chiral CD due to their stereochemical flexibility and cavity. In this minireview, we discuss recent advances, future challenges, and opportunities in the quantitative sensing of small molecules.

Graphical abstract: Cage-based sensors for circular dichroism analysis
From the themed collection: New Talent: Asia Pacific
Frontier

Chemical bottom-up approach for inorganic single-atomic layers aiming beyond graphene

A chemical bottom-up approach for single-atomic-layered materials like graphene is attractive due to the possibility of introducing or tuning functions. This article focuses on the synthesis and properties of the inorganic layers.

Graphical abstract: Chemical bottom-up approach for inorganic single-atomic layers aiming beyond graphene
From the themed collection: New Talent: Asia Pacific
Frontier

Hydrogen peroxide photo-fuel cells

H2O2-photofuel cell (PFC) is an important photoelectrochemical device contributing to the realization of a solar-driven clean energy cycle named the “hydrogen peroxide-keyed energy cycle” through combination with the photocatalytic H2O2 synthesis.

Graphical abstract: Hydrogen peroxide photo-fuel cells
From the themed collection: 2023 Frontier and Perspective articles
Frontier

Advances and opportunities in Group 15 porphyrin chemistry

The article summarizes recent advances in Group 15 porphyrin chemistry and attempts to unravel the tremendous opportunities of these remarkable porphyrins.

Graphical abstract: Advances and opportunities in Group 15 porphyrin chemistry
From the themed collection: 2023 Frontier and Perspective articles
Frontier

Metal-ion doping in metal–organic-frameworks: modulating the electronic structure and local coordination for enhanced oxygen evolution reaction activity

Metal-ion doping modulates electronic structure and coordination environment in MOFs, leading to partial exposure of metal nodes, thus enhancing the active sites, and accelerating the OER.

Graphical abstract: Metal-ion doping in metal–organic-frameworks: modulating the electronic structure and local coordination for enhanced oxygen evolution reaction activity
From the themed collection: 2023 Frontier and Perspective articles
78 items - Showing page 1 of 2

About this collection

This web collection contains the Frontier and Perspective articles published in Dalton Transactions in 2023.

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