Issue 20, 1977
From the journal:

Journal of the Chemical Society, Chemical Communications

Tris[triphenylphosphinehexachloronaphthalene-1,8-dithiolatonickel(II)], [Ni3(PPh3)3(S2C10Cl6)3], a Ni3S6 metal–sulphur cluster compound; preparation and crystal and molecular structure

Wil P. Bosman  and  Hans G. M. van der Linden  

Abstract

The trinuclear nickel complex [Ni3(PPh3)3(S2C10Cl6)3] has been prepared by the reaction of equimolar amounts of [Ni(cyclo-octa-1,5-diene)2], PPh3, and hexachloronaphtho[1,8-cd]-1,2-dithiole; an X-ray study shows that the six sulphur atoms are situated in a trigonal prismatic arrangement with the nickel atom situated 0·60 Å above the prism faces, thus forming a unique Ni3S6 cluster.

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Article information

DOI
https://doi.org/10.1039/C39770000714
Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 714-715

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Tris[triphenylphosphinehexachloronaphthalene-1,8-dithiolatonickel(II)], [Ni3(PPh3)3(S2C10Cl6)3], a Ni3S6 metal–sulphur cluster compound; preparation and crystal and molecular structure

W. P. Bosman and H. G. M. van der Linden, J. Chem. Soc., Chem. Commun., 1977, 714 DOI: 10.1039/C39770000714

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