Rate data for sulphur dioxide extrusions from thiiren 1,1-dioxides correlate best with the sum of the σp+ substituent constants and are consistent with a stepwise cleavage of the two carbon–sulphur bonds.
J. C. Philips and O. Morales, J. Chem. Soc., Chem. Commun., 1977, 713 DOI: 10.1039/C39770000713
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