Issue 33, 2022
From the journal:

Chemical Communications

The hangman effect boosts hydrogen production by a manganese terpyridine complex†

Qianqian Wu,a   Minghong Li,a   Shuanglin He,a   Ying Xiong,a   Ping Zhang,a   Heyan Huang,a   Lin Chen, ORCID logo *a   Fang Huang ORCID logo *b  and  Fei Li ORCID logo *c  

* Corresponding authors

a State Key Laboratory of Environment-Friendly Energy Materials, School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, P. R. China
E-mail: chenlin101101@aliyun.com

b College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, P. R. China

c State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. China

Abstract

The manganese terpyridine complex 1 with a coordinated carboxylate in the axial position was obtained in situ. By virtue of a hangman effect, complex 1 catalyzes electrochemical hydrogen evolution from phenol in acetonitrile solution with a turnover frequency of 525 s−1 at a low overpotential of ca. 230 mV.

Graphical abstract: The hangman effect boosts hydrogen production by a manganese terpyridine complex

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Article information

DOI
https://doi.org/10.1039/D2CC00757F
Article type
Communication
Submitted
07 Feb 2022
Accepted
28 Mar 2022
First published
30 Mar 2022

Chem. Commun., 2022,58, 5128-5131

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The hangman effect boosts hydrogen production by a manganese terpyridine complex

Q. Wu, M. Li, S. He, Y. Xiong, P. Zhang, H. Huang, L. Chen, F. Huang and F. Li, Chem. Commun., 2022, 58, 5128 DOI: 10.1039/D2CC00757F

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