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Mn-Catalyzed azidation–peroxidation of alkenes

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Abstract

Mn-Catalyzed azidation–peroxidation of alkenes with TMSN3 and TBHP has been developed. With this method, a variety of β-peroxyl azides have been synthesized from simple and readily available starting materials. Furthermore, the obtained β-peroxyl azides could be converted to α-azido carbonyl products, aldehydes or ketones, and triazole products under mild reaction conditions.

Graphical abstract: Mn-Catalyzed azidation–peroxidation of alkenes

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Publication details

The article was received on 13 Nov 2018, accepted on 15 Jan 2019 and first published on 16 Jan 2019


Article type: Research Article
DOI: 10.1039/C8QO01231H
Citation: Org. Chem. Front., 2019, Advance Article

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    Mn-Catalyzed azidation–peroxidation of alkenes

    Y. Chen, T. Tian and Z. Li, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C8QO01231H

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