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Issue 73, 2018
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Dramatic enhancement of spin–spin coupling and quenching of magnetic dimensionality in compressed silver difluoride

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Abstract

Meta-GGA calculations of the ambient and high-pressure polymorphs of silver difluoride indicate that the compression-induced structural changes lead to a 3.5-fold increase in the strength of antiferromagnetic spin–spin interactions resulting in coupling constant values higher than those found for record-holding oxocuprates(II).

Graphical abstract: Dramatic enhancement of spin–spin coupling and quenching of magnetic dimensionality in compressed silver difluoride

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Publication details

The article was received on 22 Jun 2018, accepted on 16 Jul 2018 and first published on 24 Jul 2018


Article type: Communication
DOI: 10.1039/C8CC05002C
Chem. Commun., 2018,54, 10252-10255

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    Dramatic enhancement of spin–spin coupling and quenching of magnetic dimensionality in compressed silver difluoride

    D. Kurzydłowski, M. Derzsi, P. Barone, A. Grzelak, V. Struzhkin, J. Lorenzana and W. Grochala, Chem. Commun., 2018, 54, 10252
    DOI: 10.1039/C8CC05002C

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