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Issue 3, 2015
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Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant

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Abstract

The oxidative olefination of a broad array of arenes and heteroarenes with a variety of activated and unactivated olefins has be achieved via a rhodium(III)-catalyzed C–H activation reaction. The use of an N-pentafluorophenyl benzamide directing group is crucial for achieving catalytic turnovers in the presence of air as the sole oxidant without using a co-oxidant.

Graphical abstract: Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant

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Article information


Submitted
31 Oct 2014
Accepted
05 Jan 2015
First published
08 Jan 2015

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2015,6, 1923-1927
Article type
Edge Article
Author version available

Rh(III)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant

Y. Lu, H. Wang, J. E. Spangler, K. Chen, P. Cui, Y. Zhao, W. Sun and J. Yu, Chem. Sci., 2015, 6, 1923
DOI: 10.1039/C4SC03350G

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