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Issue 40, 2015
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Pd2Au36(SR)24 cluster: structure studies

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Abstract

The location of the Pd atoms in Pd2Au36(SC2H4Ph)24, is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd–S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.

Graphical abstract: Pd2Au36(SR)24 cluster: structure studies

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Article information


Submitted
29 Jun 2015
Accepted
14 Sep 2015
First published
22 Sep 2015

Nanoscale, 2015,7, 17012-17019
Article type
Paper
Author version available

Pd2Au36(SR)24 cluster: structure studies

B. Zhang, S. Kaziz, H. Li, D. Wodka, S. Malola, O. Safonova, M. Nachtegaal, C. Mazet, I. Dolamic, J. Llorca, E. Kalenius, L. M. Lawson Daku, H. Hakkinen, T. Bürgi and N. Barrabés, Nanoscale, 2015, 7, 17012
DOI: 10.1039/C5NR04324G

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