Issue 93, 2015
From the journal:

Chemical Communications

Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes†

Julio Fernandez-Cestau,a   Benoît Bertrand,a   Maria Blaya,a   Garth A. Jones,a   Thomas J. Penfold*b  and  Manfred Bochmann*a  

* Corresponding authors

a School of Chemistry, University of East Anglia, Norwich, UK
E-mail: m.bochmann@uea.ac.uk

b Department of Chemistry, Newcastle University, Newcastle upon Tyne, UK
E-mail: Tom.Penfold@newcastle.ac.uk

Abstract

The first examples of pyrazine-based gold(III) pincer complexes are reported; their intense photoemissions can be modified by protonation, N-alkylation or metal ions, without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF).

Graphical abstract: Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes

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Article information

DOI
https://doi.org/10.1039/C5CC07523H
Article type
Communication
Submitted
08 Sep 2015
Accepted
25 Sep 2015
First published
25 Sep 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 16629-16632

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Synthesis and luminescence modulation of pyrazine-based gold(III) pincer complexes

J. Fernandez-Cestau, B. Bertrand, M. Blaya, G. A. Jones, T. J. Penfold and M. Bochmann, Chem. Commun., 2015, 51, 16629 DOI: 10.1039/C5CC07523H

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