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Issue 93, 2015
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Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes

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Abstract

The first examples of pyrazine-based gold(III) pincer complexes are reported; their intense photoemissions can be modified by protonation, N-alkylation or metal ions, without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF).

Graphical abstract: Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes

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Article information


Submitted
08 Sep 2015
Accepted
25 Sep 2015
First published
25 Sep 2015

This article is Open Access

Chem. Commun., 2015,51, 16629-16632
Article type
Communication
Author version available

Synthesis and luminescence modulation of pyrazine-based gold(III) pincer complexes

J. Fernandez-Cestau, B. Bertrand, M. Blaya, G. A. Jones, T. J. Penfold and M. Bochmann, Chem. Commun., 2015, 51, 16629
DOI: 10.1039/C5CC07523H

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