Issue 56, 2015
From the journal:

Chemical Communications

The crystalline sponge method: MOF terminal ligand effects†

Timothy R. Ramadhar,a   Shao-Liang Zheng,b   Yu-Sheng Chenc  and  Jon Clardy*a  

* Corresponding authors

a Department of Biological Chemistry and Molecular Pharmacology, Harvard Medical School, 240 Longwood Avenue, Boston, Massachusetts, USA
E-mail: jon_clardy@hms.harvard.edu
Fax: +1-617-432-3790

b Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts, USA

c ChemMatCARS, Center for Advanced Radiation Sources, The University of Chicago c/o Advanced Photon Source, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois, USA

Abstract

Bromide and chloride analogs of the commonly used zinc iodide-based metal organic framework for the crystalline sponge method were synthesized and evaluated. Inclusion of (1R)-(−)-menthyl acetate into these MOFs was analysed using third-generation synchrotron radiation, and the effects and potential benefits of varying the MOF terminal ligand are discussed.

Graphical abstract: The crystalline sponge method: MOF terminal ligand effects

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Article information

DOI
https://doi.org/10.1039/C5CC03840E
Article type
Communication
Submitted
08 May 2015
Accepted
29 May 2015
First published
02 Jun 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 11252-11255

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The crystalline sponge method: MOF terminal ligand effects

T. R. Ramadhar, S. Zheng, Y. Chen and J. Clardy, Chem. Commun., 2015, 51, 11252 DOI: 10.1039/C5CC03840E

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