Issue 56, 2015
From the journal:

Chemical Communications

The singlet excited state of BODIPY promoted aerobic cross-dehydrogenative-coupling reactions under visible light†

Xu-Zhe Wang,a   Qing-Yuan Meng,*a   Jian-Ji Zhong,a   Xue-Wang Gao,a   Tao Lei,a   Lei-Min Zhao,a   Zhi-Jun Li,a   Bin Chen,a   Chen-Ho Tunga  and  Li-Zhu Wu*a  

* Corresponding authors

a Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of Chinese Academy of Sciences, the Chinese Academy of Sciences, Beijing, P. R. China
E-mail: mqy@mail.ipc.ac.cn, lzwu@mail.ipc.ac.cn

Abstract

In contrast to previous studies, we disclose for the first time that the singlet excited state (1PS*) of BODIPY rather than the triplet excited state (3PS*) can drive C–H bond activation to form C–C and C–P bonds smoothly, which offers new methods to promote organic transformation under visible light irradiation.

Graphical abstract: The singlet excited state of BODIPY promoted aerobic cross-dehydrogenative-coupling reactions under visible light

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Article information

DOI
https://doi.org/10.1039/C5CC03421C
Article type
Communication
Submitted
24 Apr 2015
Accepted
05 Jun 2015
First published
09 Jun 2015

Chem. Commun., 2015,51, 11256-11259

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The singlet excited state of BODIPY promoted aerobic cross-dehydrogenative-coupling reactions under visible light

X. Wang, Q. Meng, J. Zhong, X. Gao, T. Lei, L. Zhao, Z. Li, B. Chen, C. Tung and L. Wu, Chem. Commun., 2015, 51, 11256 DOI: 10.1039/C5CC03421C

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