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Issue 30, 2014
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Hydrodynamic interactions slow down crystallization of soft colloids

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Abstract

Colloidal suspensions are often argued to be an ideal model for studying phase transitions such as crystallization, as they have the advantage of tunable interactions and experimentally tractable time and length scales. Because crystallization is assumed to be unaffected by details of particle transport other than the bulk diffusion coefficient, findings are frequently argued to be transferable to pure melts without solvent. In this article, we present molecular dynamics simulations of crystallization in a suspension of colloids with Yukawa interactions which challenge this assumption. In order to investigate the role of hydrodynamic interactions mediated by the solvent, we model the solvent both implicitly and explicitly, using Langevin dynamics and the fluctuating lattice Boltzmann method, respectively. Our simulations show a significant reduction of the crystal growth velocity due to hydrodynamic interactions even at moderate hydrodynamic coupling. This slowdown is accompanied by a reduction of the width of the layering region in front of the growing crystal. Thus the dynamics of a colloidal suspension differ strongly from that of a melt, making it less useful as a model for solvent-free melts than previously thought.

Graphical abstract: Hydrodynamic interactions slow down crystallization of soft colloids

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Article information


Submitted
28 Mar 2014
Accepted
22 May 2014
First published
23 May 2014

Soft Matter, 2014,10, 5503-5509
Article type
Paper
Author version available

Hydrodynamic interactions slow down crystallization of soft colloids

D. Roehm, S. Kesselheim and A. Arnold, Soft Matter, 2014, 10, 5503
DOI: 10.1039/C4SM00686K

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