Jump to main content
Jump to site search

Issue 16, 2013
Previous Article Next Article

A face-capped [Fe4L4]8+ spin crossover tetrahedral cage

Author affiliations

Abstract

Reported here is a face-capped Fe(II) molecular tetrahedron, [Fe4L4](BF4)8, 1. Single crystal X-ray diffraction at 153 and 293 K suggest spin crossover (SCO) and variable temperature magnetic susceptibility measurements confirm 1 displays thermally driven SCO behaviour in the solid state and in dilute acetone solution centred around 284–288 K.

Graphical abstract: A face-capped [Fe4L4]8+ spin crossover tetrahedral cage

Back to tab navigation

Supplementary files

Article information


Submitted
26 Oct 2012
Accepted
08 Jan 2013
First published
08 Jan 2013

This article is Open Access

Chem. Commun., 2013,49, 1597-1599
Article type
Communication

A face-capped [Fe4L4]8+ spin crossover tetrahedral cage

A. Ferguson, M. A. Squire, D. Siretanu, D. Mitcov, C. Mathonière, R. Clérac and P. E. Kruger, Chem. Commun., 2013, 49, 1597
DOI: 10.1039/C3CC00012E

Social activity

Search articles by author

Spotlight

Advertisements