CO2 superabsorption in a paddlewheel-type Ru dimer chain compound: gate-open performance dependent on inter-chain interactions

Wataru Kosaka; Kayo Yamagishi; Hiroki Yoshida; Ryotaro Matsuda; Susumu Kitagawa; Masaki Takata; Hitoshi Miyasaka

doi:10.1039/C2CC36153A

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CO₂ superabsorption in a paddlewheel-type Ru dimer chain compound: gate-open performance dependent on inter-chain interactions†

Wataru Kosaka,^a Kayo Yamagishi,^a Hiroki Yoshida,^b Ryotaro Matsuda,^cde Susumu Kitagawa,^cdef Masaki Takata^eg and Hitoshi Miyasaka*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan
E-mail: miyasaka@se.kanazawa-u.ac.jp
Fax: +81-76-264-5742
Tel: +81-76-264-5697

^b Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan

^c ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST), Kyoto Research Park Bldg #3-405, Shimogyo-ku, Kyoto 600-8815, Japan

^d Institute for Integrated Cell-Materials Science (iCeMS), Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

^e RIKEN SPring-8 Center, Sayo-gun, Hyogo 679-5148, Japan

^f Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

^g Japan Synchrotron Radiation Research Institute/SPring-8, Sayo-gun, Hyogo 679-5198, Japan

Abstract

A porous one-dimensional coordination chain compound, [Ru₂(p-F-PhCO₂)₄(phz)] (1′; p-F-PhCO₂⁻ = para-fluorobenzoate; phz = phenazine) derived by drying its nitrobenzene-solvated compound, specifically adsorbs CO₂ at 195 K in a stepwise sorption manner.

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Article information

DOI: https://doi.org/10.1039/C2CC36153A
Article type: Communication
Submitted: 24 Aug 2012
Accepted: 08 Nov 2012
First published: 08 Nov 2012

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Chem. Commun., 2013,49, 1594-1596

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CO₂ superabsorption in a paddlewheel-type Ru dimer chain compound: gate-open performance dependent on inter-chain interactions

W. Kosaka, K. Yamagishi, H. Yoshida, R. Matsuda, S. Kitagawa, M. Takata and H. Miyasaka, Chem. Commun., 2013, 49, 1594 DOI: 10.1039/C2CC36153A

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Chemical Communications