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Issue 18, 2012
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Assembly of robust two-dimensional sheet structures from crystalline ring-fused malonamidesvia cooperative hydrogen bonding of amide groups

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Abstract

Ring-fused malonamides assemble into well-defined 2D-sheet structures based on the formation of 6 to 8 hydrogen bonds per molecule. The stacking manner and the interlayer distances of these sheets in the crystal can be manipulated by varying the size of the fused ring to form either interdigitated or segregated structures.

Graphical abstract: Assembly of robust two-dimensional sheet structures from crystalline ring-fused malonamides via cooperative hydrogen bonding of amide groups

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Article information


Submitted
24 Apr 2012
Accepted
28 Jun 2012
First published
28 Jun 2012

CrystEngComm, 2012,14, 5717-5719
Article type
Communication

Assembly of robust two-dimensional sheet structures from crystalline ring-fused malonamides via cooperative hydrogen bonding of amide groups

H. Kawai and D. Hosoda, CrystEngComm, 2012, 14, 5717
DOI: 10.1039/C2CE26003D

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