Issue 18, 2012
From the journal:

CrystEngComm

An unprecedented 3D/3D hetero-interpenetrated MOF built from two different nodes, chemical composition, and topology of networks†

Heng Xu,a   Weiwei Bao,a   Yan Xu,a   Xiaolan Liu,a   Xuan Shena  and  Dunru Zhu*ab  

* Corresponding authors

a State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China
E-mail: zhudr@njut.edu.cn

b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China

Abstract

An exceptional acentric MOF material with two-fold hetero-interpenetrated nets consisting of a 3D diamond network (mononuclear Cd(CO2)4 node) and a 3D CsCl framework (trinuclear Cd3(CO2)8 node) has been constructed, which contains 6-, 7-, 8-coordinated Cd2+ ions and shows a high thermal stability (>420 °C) and SHG activity.

Graphical abstract: An unprecedented 3D/3D hetero-interpenetrated MOF built from two different nodes, chemical composition, and topology of networks

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Article information

DOI
https://doi.org/10.1039/C2CE25739D
Article type
Communication
Submitted
11 May 2012
Accepted
21 Jun 2012
First published
21 Jun 2012

CrystEngComm, 2012,14, 5720-5722

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An unprecedented 3D/3D hetero-interpenetrated MOF built from two different nodes, chemical composition, and topology of networks

H. Xu, W. Bao, Y. Xu, X. Liu, X. Shen and D. Zhu, CrystEngComm, 2012, 14, 5720 DOI: 10.1039/C2CE25739D

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